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2019 | OriginalPaper | Buchkapitel

The Influence of Temperature and Medium on Corrosion Response of ZE41 and EZ33

verfasst von : M. AbdelGawad, A. U. Chaudhry, B. Mansoor

Erschienen in: Magnesium Technology 2019

Verlag: Springer International Publishing

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Abstract

Mg-based implants offer a promising alternative to commonly used permanent implants due to their biodegradability that eliminates the need for a follow-up surgery, along with the associated medical and economic risks. Several of the commercial Mg alloys for various applications including potential implant applications contain rare earth elements that are known to improve mechanical strength and corrosion resistance. However, it remains a significant challenge to better understand in vitro corrosion behavior of Mg–RE alloys and predict in vivo behavior, which is useful for biomedical applications, since in vitro corrosion rates tend to be significantly higher than those reported in vivo. In this work, we study the mechanical and corrosion behavior of two Mg–RE alloys, ZE41 and EZ33, at physiologically relevant temperature of 37 °C in 3.5 wt% NaCl and Hank’s solution. Tensile and compression tests were used to evaluate mechanical properties while electrochemical techniques were used to investigate the corrosion response. Both alloys demonstrated improved corrosion resistance in Hank’s solution which was attributed to the formation of a more protective surface film. In addition, the increased RE concentration positively impacted the corrosion behavior of EZ33 compared to ZE41 in both mediums.

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Vorheriges Kapitel Microstructures, Corrosion and Mechanical Properties of Mg–Si Alloys as Biodegradable Implant Materials

Nächstes Kapitel Alloy Design Strategies of the Native Anti-corrosion Magnesium Alloy

Song G, Atrens A. (2003) Understanding Magnesium Corrosion—A Framework for Improved Alloy Performance. Adv Eng Mater 5:837–858. https://doi.org/10.1002/adem.200310405CrossRef

Song GL, Atrens A (1999) Corrosion Mechanisms of Magnesium Alloys. Adv Eng Mater 1:11–33. https://doi.org/10.1002/(sici)1527-2648(199909)1:1%3c11::aid-adem11%3e3.0.co;2-nCrossRef

Song G (2005) Recent progress in corrosion and protection of magnesium alloys. Adv Eng Mater 7:563–586. https://doi.org/10.1002/adem.200500013CrossRef

Atrens A, Song GL, Cao F, et al (2013) Advances in Mg corrosion and research suggestions. J Magnes Alloy 1:177–200. https://doi.org/10.1016/j.jma.2013.09.003CrossRef

King AD, Birbilis N, Scully JR (2014) Accurate electrochemical measurement of magnesium corrosion rates: A combined impedance, mass-loss and hydrogen collection study. Electrochim Acta 121:394–406. https://doi.org/10.1016/j.electacta.2013.12.124CrossRef

Gusieva K, Davies CHJ, Scully JR, Birbilis N (2015) Corrosion of magnesium alloys: the role of alloying. Int Mater Rev 60:169–194. https://doi.org/10.1179/1743280414y.0000000046CrossRef

Esmaily M, Svensson JE, Fajardo S, et al (2017) Fundamentals and advances in magnesium alloy corrosion. Prog Mater Sci 89:92–193. https://doi.org/10.1016/j.pmatsci.2017.04.011CrossRef

Zhao D, Witte F, Lu F, et al (2017) Current status on clinical applications of magnesium-based orthopaedic implants: A review from clinical translational perspective. Biomaterials 112:287–302. https://doi.org/10.1016/j.biomaterials.2016.10.017CrossRef

Chen Y, Xu Z, Smith C, Sankar J (2014) Recent advances on the development of magnesium alloys for biodegradable implants. Acta Biomater 10:4561–4573. https://doi.org/10.1016/j.actbio.2014.07.005CrossRef

10.

Agarwal S, Curtin J, Duffy B, Jaiswal S (2016) Biodegradable magnesium alloys for orthopaedic applications: A review on corrosion, biocompatibility and surface modifications. Mater Sci Eng C 68:948–963. https://doi.org/10.1016/j.msec.2016.06.020CrossRef

11.

Ding Y, Wen C, Hodgson P, Li Y (2014) Effects of alloying elements on the corrosion behavior and biocompatibility of biodegradable magnesium alloys: a review. J Mater Chem B 2:1912–1933. https://doi.org/10.1039/c3tb21746aCrossRef

12.

Pourbaix M (1974) Atlas of electrochemical equilibria in aqueous solutions. 2nd Eng. ed. by Marcel Pourbaix; translated from the French by James A. Franklin (except sections I, III 5, and III 6, which were originally written in English). Houston, Tex.: National Association of Corrosion Engineers, 1974

13.

Sanchez AHM, Luthringer BJC, Feyerabend F, Willumeit R (2015) Mg and Mg alloys: How comparable are in vitro and in vivo corrosion rates? A review. Acta Biomater 13:16–31. https://doi.org/10.1016/j.actbio.2014.11.048CrossRef

14.

Tekumalla S, Seetharaman S, Almajid A, et al (2015) Mechanical Properties of Magnesium-Rare Earth Alloy Systems: A Review. Metals (Basel) 5:1–39. https://doi.org/10.3390/met5010001CrossRef

15.

Sediako D, Bichler L, van Hanegam M, Shook S (2013) Compressive Creep Properties of Wrought High Temperature Magnesium Alloys in Axial and Transverse Orientation—A Neutron Diffraction Study. Magnes Technol 2013 3–8. https://doi.org/10.1002/9781118663004

16.

AbdelGawad M, Mansoor B, Chaudhry AU (2018) Corrosion Characteristics of Two Rare Earth Containing Magnesium Alloys BT—Magnesium Technology 2018. In: Orlov D, Joshi V, Solanki KN, Neelameggham NR (eds). Springer International Publishing, Cham, pp 43–53

17.

Zainal Abidin NI, Martin D, Atrens A (2011) Corrosion of high purity Mg, AZ91, ZE41 and Mg2Zn0.2Mn in Hank’s solution at room temperature. Corros Sci 53:862–872. https://doi.org/10.1016/j.corsci.2010.10.008CrossRef

18.

Zainal Abidin NI, Atrens AD, Martin D, Atrens A (2011) Corrosion of high purity Mg, Mg2Zn0.2Mn, ZE41 and AZ91 in Hank’s solution at 37 °C. Corros Sci 53:3542–3556. https://doi.org/10.1016/j.corsci.2011.06.030CrossRef

19.

Taltavull C, Shi Z, Torres B, et al (2014) Influence of the chloride ion concentration on the corrosion of high-purity Mg, ZE41 and AZ91 in buffered Hank’s solution. J Mater Sci Mater Med 25:329–345. https://doi.org/10.1007/s10856-013-5087-y

20.

Johnston S, Shi Z, Atrens A (2015) The influence of pH on the corrosion rate of high-purity Mg, AZ91 and ZE41 in bicarbonate buffered Hanks’ solution. Corros Sci 101:182–192. https://doi.org/10.1016/j.corsci.2015.09.018CrossRef

21.

Zhao MC, Liu M, Song GL, Atrens A (2008) Influence of pH and chloride ion concentration on the corrosion of Mg alloy ZE41. Corros Sci 50:3168–3178. https://doi.org/10.1016/j.corsci.2008.08.023CrossRef

22.

Zhao MC, Liu M, Song GL, Atrens A (2008) Influence of microstructure on corrosion of As-cast ZE41. Adv Eng Mater 10:104–111. https://doi.org/10.1002/adem.200700246CrossRef

23.

Siebert-Timmer A, Fletcher M, Bichler L, Sediako D (2013) Creep performance of wrought AX30 and EZ33 magnesium alloys. Can Metall Q 52:430–438. https://doi.org/10.1179/1879139513y.0000000069CrossRef

24.

Wei LY, Dunlop GL, Westengen H (1997) Solidification behaviour and phase constituents of cast Mg-Zn-misch metal alloys. J Mater Sci 32:3335–3340. https://doi.org/10.1023/a:1018695927717CrossRef

25.

Neil WC, Forsyth M, Howlett PC, et al (2011) Corrosion of heat treated magnesium alloy ZE41. Corros Sci 53:3299–3308. https://doi.org/10.1016/j.corsci.2011.06.005CrossRef

26.

Neil WC, Forsyth M, Howlett PC, et al (2009) Corrosion of magnesium alloy ZE41—The role of microstructural features. Corros Sci 51:387–394. https://doi.org/10.1016/j.corsci.2008.11.005CrossRef

27.

Trojanová Z, Lukáč P (2005) Compressive deformation behaviour of magnesium alloys. J Mater Process Technol 162–163:416–421. https://doi.org/10.1016/j.jmatprotec.2005.02.024CrossRef

28.

Kirkland NT, Birbilis N, Staiger MP (2012) Assessing the corrosion of biodegradable magnesium implants: a critical review of current methodologies and their limitations. Acta Biomater 8:925–936. https://doi.org/10.1016/j.actbio.2011.11.014CrossRef

29.

Wang J, Jang Y, Wan G, et al (2016) Flow-induced corrosion of absorbable magnesium alloy: in-situ and real-time electrochemical study. Corros Sci 104:277–289. https://doi.org/10.1016/j.corsci.2015.12.020CrossRef

30.

Zakiyuddin A, Lee K (2015) Effect of a small addition of zinc and manganese to Mg-Ca based alloys on degradation behavior in physiological media. J Alloys Compd 629:274–283. https://doi.org/10.1016/j.jallcom.2014.12.181CrossRef

31.

Birbilis N, Easton MA, Sudholz AD, et al (2009) On the corrosion of binary magnesium-rare earth alloys. Corros Sci 51:683–689. https://doi.org/10.1016/j.corsci.2008.12.012CrossRef

Titel: The Influence of Temperature and Medium on Corrosion Response of ZE41 and EZ33
verfasst von: M. AbdelGawad
A. U. Chaudhry
B. Mansoor
Verlag: Springer International Publishing
Buch: Magnesium Technology 2019
Print ISBN: 978-3-030-05788-6

Electronic ISBN: 978-3-030-05789-3

Copyright-Jahr: 2019
DOI: https://doi.org/10.1007/978-3-030-05789-3_24

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