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Journal of Sol-Gel Science and Technology
Erschienen in: Journal of Sol-Gel Science and Technology 3/2017

27.03.2017 | Original Paper: Sol-gel and hybrid materials with surface modification for applications

The interaction of cellulose and montmorillonite in a hydrothermal process

verfasst von: Guangyu Yang, Yinshan Jiang, Xiaodong Yang, Yuanjun Xu, Shiding Miao, Fangfei Li

Erschienen in: Journal of Sol-Gel Science and Technology | Ausgabe 3/2017

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Abstract

In this paper, the interaction of cellulose and montmorillonite in a hydrothermal process was discussed. The preparation of the composite was performed at 230 °C for different periods of time from 0.5 to 16 h. The hydroxypropyl methyl cellulose was set to 50 wt.% in the composite and multiple sets of data were compared. The samples were characterized by X-ray diffraction, Fourier transform infrared spectroscopy, scanning electron microscopy, thermogravimetry-differential thermal analysis, specific surface area and electric potential for evaluation of interactions. Hydrochar is a solid carbon-rich mixture produced from the hydrothermal carbonization of the cellulose. The cellulose can be adsorbed at the surface of montmorillonite. The pores of montmorillonite are partially blocked by the hydrochar. The state of the hydrochar has a significant effect on the order of montmorillonite. The zeta potential of the composite is mainly affected by hydrochar. In turn, the Fourier transform infrared spectroscopy results indicate that montmorillonite affects the hydrochar structure, and the thermal stability of hydrochar is improved. The experimental results show that the presence of hydrochar in the composite causes significant changes in surface properties and the interlayer structure. Meanwhile, montmorillonite plays a protective role on the hydrochar.

Graphical Abstract

https://static-content.springer.com/image/art%3A10.1007%2Fs10971-017-4365-4/MediaObjects/10971_2017_4365_Figa_HTML.gif
Vorheriger Artikel Application of chalcone-based dithiocarbamate derivative incorporated sol–gel for the removal of Hg (II) ion from water
Nächster Artikel A systematic study of the hydration and drying process of silica xerogels using Cu(II) EPR spectroscopy

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Metadaten
Titel
The interaction of cellulose and montmorillonite in a hydrothermal process
verfasst von
Guangyu Yang
Yinshan Jiang
Xiaodong Yang
Yuanjun Xu
Shiding Miao
Fangfei Li
Publikationsdatum
27.03.2017
Verlag
Springer US
Erschienen in
Journal of Sol-Gel Science and Technology / Ausgabe 3/2017
Print ISSN: 0928-0707
Elektronische ISSN: 1573-4846
DOI
https://doi.org/10.1007/s10971-017-4365-4

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