Skip to main content

Tipp

Weitere Artikel dieser Ausgabe durch Wischen aufrufen

Erschienen in: Physics of Metals and Metallography 9/2022

01.09.2022 | ELECTRICAL AND MAGNETIC PROPERTIES

The Magnetocaloric Effect of Nonstoichiometric ErM2Mnx Compounds (with M = Ni, Co, and Fe)

verfasst von: A. A. Inishev, E. G. Gerasimov, P. B. Terent’ev, V. S. Gaviko, N. V. Mushnikov

Erschienen in: Physics of Metals and Metallography | Ausgabe 9/2022

Einloggen, um Zugang zu erhalten
share
TEILEN

Abstract

The structure and magnetic and magnetocaloric properties of nonstoichiometric ErM2Mnx alloys with M = Ni, Co, and Fe have been studied. ErNi2Mnx alloys with x ≤ 1.25, ErCo2Mnx alloys with x ≤ 0.8, and ErFe2Mnx alloys with x ≤ 0.4 are shown to solidify with the formation of the cubic MgCu2-type structure. The magnetocaloric effect of the ErM2Mnx compounds is estimated based on magnetic measurements and using the thermodynamic Maxwell’s relation. The ErFe2Mn0.4 compound is found to demonstrate a plateau-like temperature dependence of the magnetic entropy change over the wide temperature range from 77 to 300 K.

Sie möchten Zugang zu diesem Inhalt erhalten? Dann informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 69.000 Bücher
  • über 500 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt 90 Tage mit der neuen Mini-Lizenz testen!

Springer Professional "Wirtschaft"

Online-Abonnement

Mit Springer Professional "Wirtschaft" erhalten Sie Zugriff auf:

  • über 58.000 Bücher
  • über 300 Zeitschriften

aus folgenden Fachgebieten:

  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Versicherung + Risiko





Jetzt 90 Tage mit der neuen Mini-Lizenz testen!

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 50.000 Bücher
  • über 380 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe



 


Jetzt 90 Tage mit der neuen Mini-Lizenz testen!

Literatur
1.
Zurück zum Zitat V. Franco, J. S. Blazquez, J. J. Ipus, J. Y. Law, L. M. Moreno-Ramirez, and A. Conde, “Magnetocaloric effect: From materials research to refrigeration devices,” Prog. Mater. Sci. 93, 112–232 (2018). CrossRef V. Franco, J. S. Blazquez, J. J. Ipus, J. Y. Law, L. M. Moreno-Ramirez, and A. Conde, “Magnetocaloric effect: From materials research to refrigeration devices,” Prog. Mater. Sci. 93, 112–232 (2018). CrossRef
2.
Zurück zum Zitat E. J. R. Plaza, V. S. R. de Sousa, M. S. Reis, and P. J. von Ranke, “A comparative study of the magnetocaloric effect in RNi 2 (R = Dy, Ho, Er) intermetallic compounds,” J. Alloys Compd. 505, 357–361 (2010). CrossRef E. J. R. Plaza, V. S. R. de Sousa, M. S. Reis, and P. J. von Ranke, “A comparative study of the magnetocaloric effect in RNi 2 (R = Dy, Ho, Er) intermetallic compounds,” J. Alloys Compd. 505, 357–361 (2010). CrossRef
3.
Zurück zum Zitat M. Anikin, E. Tarasov, N. Kudrevatykh, A. Inishev, M. Semkin, A. Volegov, and A. Zinin, “Features of magnetic and thermal properties of R(Co 1 – xFe x) 2 ( x ≤ 0.16) quasibinary compounds with R = Dy, Ho, Er,” J. Magn. Magn. Mater. 418, 181–187 (2016). CrossRef M. Anikin, E. Tarasov, N. Kudrevatykh, A. Inishev, M. Semkin, A. Volegov, and A. Zinin, “Features of magnetic and thermal properties of R(Co 1 – xFe x) 2 ( x ≤ 0.16) quasibinary compounds with R = Dy, Ho, Er,” J. Magn. Magn. Mater. 418, 181–187 (2016). CrossRef
4.
Zurück zum Zitat G. A. Politova, N. Yu. Pankratov, P. Yu. Vanina, A. V. Filimonov, A. I. Rudskoy, G. S. Burkhanov, A. S. Ilyushin, and I. S. Tereshina, “Magnetocaloric effect and magnetostrictive deformation in Tb–Dy–Gd–Co–Al with Laves phase structure,” J. Magn. Magn. Mater. 470, 50–54 (2019). CrossRef G. A. Politova, N. Yu. Pankratov, P. Yu. Vanina, A. V. Filimonov, A. I. Rudskoy, G. S. Burkhanov, A. S. Ilyushin, and I. S. Tereshina, “Magnetocaloric effect and magnetostrictive deformation in Tb–Dy–Gd–Co–Al with Laves phase structure,” J. Magn. Magn. Mater. 470, 50–54 (2019). CrossRef
5.
Zurück zum Zitat N. V. Mushnikov, V. S. Gaviko, E. G. Gerasimov, P. B. Terentev, and I. A. Tkach, “Magnetic properties and structure of nonstoichiometric rare-earth transition-metal intermetallic compounds TbNi 2Mn x (0 ≤ x ≤ 1.5),” Phys. Met. Metallogr. 110, 210–217 (2010). CrossRef N. V. Mushnikov, V. S. Gaviko, E. G. Gerasimov, P. B. Terentev, and I. A. Tkach, “Magnetic properties and structure of nonstoichiometric rare-earth transition-metal intermetallic compounds TbNi 2Mn x (0 ≤ x ≤ 1.5),” Phys. Met. Metallogr. 110, 210–217 (2010). CrossRef
6.
Zurück zum Zitat C. Fang, J. Wang, F. Hong, W. D. Hutchison, M. F. Md Din, A. J. Studer, J. A. Kimpton, S. Dou, and Z. Cheng, “Tuning the magnetic and structural transitions in TbCo 2Mn x compounds,” Phys. Rev. B 96, 064425 (2017). CrossRef C. Fang, J. Wang, F. Hong, W. D. Hutchison, M. F. Md Din, A. J. Studer, J. A. Kimpton, S. Dou, and Z. Cheng, “Tuning the magnetic and structural transitions in TbCo 2Mn x compounds,” Phys. Rev. B 96, 064425 (2017). CrossRef
7.
Zurück zum Zitat A. A. Inishev, E. G. Gerasimov, N. V. Mushnikov, P. B. Terentev, and V. S. Gaviko, “Structure, magnetic and magnetocaloric properties of nonstoichiometric TbCo 2Mn x compounds,” Phys. Met. Metallogr. 119, 1036–1042 (2018). CrossRef A. A. Inishev, E. G. Gerasimov, N. V. Mushnikov, P. B. Terentev, and V. S. Gaviko, “Structure, magnetic and magnetocaloric properties of nonstoichiometric TbCo 2Mn x compounds,” Phys. Met. Metallogr. 119, 1036–1042 (2018). CrossRef
8.
Zurück zum Zitat E. G. Gerasimov, A. A. Inishev, P. B. Terentev, V. A. Kazantsev, and N. V. Mushnikov, “Magnetostriction and thermal expansion of nonstoichiometric TbCo 2Mn x compounds,” J. Magn. Magn. Mater. 523, 167628–167634 (2021). CrossRef E. G. Gerasimov, A. A. Inishev, P. B. Terentev, V. A. Kazantsev, and N. V. Mushnikov, “Magnetostriction and thermal expansion of nonstoichiometric TbCo 2Mn x compounds,” J. Magn. Magn. Mater. 523, 167628–167634 (2021). CrossRef
9.
Zurück zum Zitat E. G. Gerasimov, N. V. Mushnikov, P. B. Terentev, V. S. Gaviko, and A. A. Inishev, “Magnetic properties of the off-stoichiometric GdNi 2Mn x alloys,” J. Alloys Compd. 571, 132–138 (2013). CrossRef E. G. Gerasimov, N. V. Mushnikov, P. B. Terentev, V. S. Gaviko, and A. A. Inishev, “Magnetic properties of the off-stoichiometric GdNi 2Mn x alloys,” J. Alloys Compd. 571, 132–138 (2013). CrossRef
10.
Zurück zum Zitat K. Balinski, T. V. Kuznetsova, E. G. Gerasimov, A. V. Protasov, V. V. Marchenkov, N. V. Mushnikov, V. R. Galakhov, V. V. Mesilov, S. N. Shamin, V. S. Gaviko, B. V. Senkovskiy, M. Fijalkowski, L. Schneider, A. Slebarski, A. Chrobak, and K. Kuepper, “Electrical resistivity, magnetism and electronic structure of the intermetallic 3 d/4 f Laves phase compounds ErNi 2Mn x,” AIP Adv. 8, 105225-1-11 (2018). CrossRef K. Balinski, T. V. Kuznetsova, E. G. Gerasimov, A. V. Protasov, V. V. Marchenkov, N. V. Mushnikov, V. R. Galakhov, V. V. Mesilov, S. N. Shamin, V. S. Gaviko, B. V. Senkovskiy, M. Fijalkowski, L. Schneider, A. Slebarski, A. Chrobak, and K. Kuepper, “Electrical resistivity, magnetism and electronic structure of the intermetallic 3 d/4 f Laves phase compounds ErNi 2Mn x,” AIP Adv. 8, 105225-1-11 (2018). CrossRef
11.
Zurück zum Zitat E. G. Gerasimov, N. V. Mushnikov, A. A. Inishev, P. B. Terentev, and V. S. Gaviko, “Structure, magnetic and magnetothermal properties of the non-stoichiometric ErCo 2Mn x alloys,” J. Alloys Compd. 680, 359–365 (2016). CrossRef E. G. Gerasimov, N. V. Mushnikov, A. A. Inishev, P. B. Terentev, and V. S. Gaviko, “Structure, magnetic and magnetothermal properties of the non-stoichiometric ErCo 2Mn x alloys,” J. Alloys Compd. 680, 359–365 (2016). CrossRef
12.
Zurück zum Zitat G. E. Fish, J. J. Rhyne, S. G. Sankar, and W. E. Wallace, “Effect of hydrogen on sublattice magnetization of Laves-phase rare earth iron compounds,” J. Appl. Phys. 96, 064425-1 (1979). G. E. Fish, J. J. Rhyne, S. G. Sankar, and W. E. Wallace, “Effect of hydrogen on sublattice magnetization of Laves-phase rare earth iron compounds,” J. Appl. Phys. 96, 064425-1 (1979).
13.
Zurück zum Zitat E. Gratz and A. S. Markosyan, “Physical properties of RCo 2 Laves phases,” J. Phys.: Condens. Matter 13, 385–413 (2001). E. Gratz and A. S. Markosyan, “Physical properties of RCo 2 Laves phases,” J. Phys.: Condens. Matter 13, 385–413 (2001).
14.
Zurück zum Zitat H. Yamada, “Electronic structure and magnetic properties of the cubic laves phase transition metal compounds,” Phys. B + C 149, 390–402 (1988). H. Yamada, “Electronic structure and magnetic properties of the cubic laves phase transition metal compounds,” Phys. B + C 149, 390–402 (1988).
15.
Zurück zum Zitat K. H. J. Buschow, “Intermetallic compounds of rare-earth and 3 d transition metals,” Rep. Prog. Phys. 40, 1179–1256 (1977). CrossRef K. H. J. Buschow, “Intermetallic compounds of rare-earth and 3 d transition metals,” Rep. Prog. Phys. 40, 1179–1256 (1977). CrossRef
16.
Zurück zum Zitat J. L. Wang, C. Marquina, M. R. Ibarra, and G. H. Wu, “Structure and magnetic properties of RNi 2Mn compounds ( R = Tb, Dy, Ho and Er),” Phys. Rev. B 73, 094436 (2006). CrossRef J. L. Wang, C. Marquina, M. R. Ibarra, and G. H. Wu, “Structure and magnetic properties of RNi 2Mn compounds ( R = Tb, Dy, Ho and Er),” Phys. Rev. B 73, 094436 (2006). CrossRef
17.
Zurück zum Zitat I. G. de Oliveira, P. J. von Ranke, and E. P. Nóbrega, “Understanding the table-like magnetocaloric effect,” J. Magn. Magn. Mater. 261, 112–117 (2003). CrossRef I. G. de Oliveira, P. J. von Ranke, and E. P. Nóbrega, “Understanding the table-like magnetocaloric effect,” J. Magn. Magn. Mater. 261, 112–117 (2003). CrossRef
18.
Zurück zum Zitat I. Chaaba, S. Othmani, S. Haj-Khlifa, P. de Rango, D. Fruchart, W. Cheikhrouhou-Koubaa, and A. Cheikhrouhou, “Magnetic and magnetocaloric properties of Er(Co 1 – xFe x) 2 intermetallic compounds,” J. Magn. Magn. Mater. 439, 269–276 (2017). CrossRef I. Chaaba, S. Othmani, S. Haj-Khlifa, P. de Rango, D. Fruchart, W. Cheikhrouhou-Koubaa, and A. Cheikhrouhou, “Magnetic and magnetocaloric properties of Er(Co 1 – xFe x) 2 intermetallic compounds,” J. Magn. Magn. Mater. 439, 269–276 (2017). CrossRef
19.
Zurück zum Zitat B. J. Korte, V. K. Pecharsky, and K. A. Gschneidner, “The correlation of the magnetic properties and the magnetocaloric effect in (Gd 1 – xEr x)NiAl alloys,” J. Appl. Phys. 84, 5677–5685 (2017). CrossRef B. J. Korte, V. K. Pecharsky, and K. A. Gschneidner, “The correlation of the magnetic properties and the magnetocaloric effect in (Gd 1 – xEr x)NiAl alloys,” J. Appl. Phys. 84, 5677–5685 (2017). CrossRef
20.
Zurück zum Zitat E. G. Gerasimov, A. A. Inishev, N. V. Mushnikov, P. B. Terentev, V. S. Gaviko, and M. S. Anikin, “Magnetocaloric effect, heat capacity and exchange interactions in nonstoichiometric Er 0.65Gd 0.35Co 2Mn x compounds,” Intermetallics 140, 107386–107394 (2022). CrossRef E. G. Gerasimov, A. A. Inishev, N. V. Mushnikov, P. B. Terentev, V. S. Gaviko, and M. S. Anikin, “Magnetocaloric effect, heat capacity and exchange interactions in nonstoichiometric Er 0.65Gd 0.35Co 2Mn x compounds,” Intermetallics 140, 107386–107394 (2022). CrossRef
Metadaten
Titel
The Magnetocaloric Effect of Nonstoichiometric ErM2Mnx Compounds (with M = Ni, Co, and Fe)
verfasst von
A. A. Inishev
E. G. Gerasimov
P. B. Terent’ev
V. S. Gaviko
N. V. Mushnikov
Publikationsdatum
01.09.2022
Verlag
Pleiades Publishing
Erschienen in
Physics of Metals and Metallography / Ausgabe 9/2022
Print ISSN: 0031-918X
Elektronische ISSN: 1555-6190
DOI
https://doi.org/10.1134/S0031918X22090046

Weitere Artikel der Ausgabe 9/2022

Physics of Metals and Metallography 9/2022 Zur Ausgabe

STRUCTURE, PHASE TRANSFORMATIONS, AND DIFFUSION

The Fine Structure of MgB2 Alloyed with Y and Gd