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Erschienen in: Journal of Materials Science: Materials in Electronics 6/2020

08.02.2020

The photoluminescence adjustment of red phosphors ANaWO2F4:Mn4+ (A = Li, Na, K) by suitable tolerance factor designing

verfasst von: Meiqing Hu, Zhifu Liu, Yujuan Xia, Ganghua Zhang, Yongzheng Fang, Yufeng Liu, Guoying Zhao, Jingshan Hou

Erschienen in: Journal of Materials Science: Materials in Electronics | Ausgabe 6/2020

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Abstract

Mn4+-activated perovskite-structured ANaWO2F4 (A = Li, Na, K) red phosphors were successfully prepared by a facile co-precipitation method. By changing the A-site ions, the tolerance factor (t) of host material ANaWO2F4 became adjustable. Red emissions in LiNaWO2F4:Mn4+, Na2WO2F4:Mn4+ and KNaWO2F4:Mn4+ were found to be gradually increased. The relationship between the structure and their photoluminescence properties was discussed. The results suggested that a t-dependent photoluminescence behavior may exist in perovskite-structured phosphors. As the tolerance factor increases, the emission intensity of ANaWO2F4 (A = Li, Na, K) red phosphors increases. This work also provides a reference for the exploration and optimization of Mn4+-activated perovskite-structured red phosphors.

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Metadaten
Titel
The photoluminescence adjustment of red phosphors ANaWO2F4:Mn4+ (A = Li, Na, K) by suitable tolerance factor designing
verfasst von
Meiqing Hu
Zhifu Liu
Yujuan Xia
Ganghua Zhang
Yongzheng Fang
Yufeng Liu
Guoying Zhao
Jingshan Hou
Publikationsdatum
08.02.2020
Verlag
Springer US
Erschienen in
Journal of Materials Science: Materials in Electronics / Ausgabe 6/2020
Print ISSN: 0957-4522
Elektronische ISSN: 1573-482X
DOI
https://doi.org/10.1007/s10854-020-03004-7

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