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Colloid and Polymer Science

Erschienen in:

04.01.2018 | Original Contribution

The property study of sodium dodecyl benzenesulfonate and polyvinylpyrrolidone complexes

verfasst von: Chang Hu, Zhiping Du, Xiumei Tai, Xuebin Mao, Xiaoying Liu

Erschienen in: Colloid and Polymer Science | Ausgabe 2/2018

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Abstract

In this paper, the physicochemical properties between sodium dodecylbenzenesulfonate (SDBS) and polyvinylpyrrolidone (PVP) in aqueous solutions were studied at 25 °C by Ubbelohde viscometer, conductivity analyzer, and fluorescence spectrophotometer. It was found that viscosity, conductivity, steady-state fluorescence, and Rayleigh scattering curve for SDBS-PVP system could be divided into three regions by two characteristic concentrations: the critical aggregation concentration (cac) and the polymer saturation point (psp). The results revealed that interactions between SDBS and PVP molecules in aqueous solutions could be explained by “necklace and bead” model. Micelle-like surfactant aggregates, formed by SDBS-free molecules, associated with PVP chains mainly by hydrophobic interaction.

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Titel: The property study of sodium dodecyl benzenesulfonate and polyvinylpyrrolidone complexes
verfasst von: Chang Hu
Zhiping Du
Xiumei Tai
Xuebin Mao
Xiaoying Liu
Publikationsdatum: 04.01.2018
Verlag: Springer Berlin Heidelberg
Erschienen in: Colloid and Polymer Science / Ausgabe 2/2018
Print ISSN: 0303-402X
Elektronische ISSN: 1435-1536
DOI: https://doi.org/10.1007/s00396-017-4248-9

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