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Journal of Nanoparticle Research

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01.01.2023 | Review

Theoretical studies with B₁₂N₁₂ as a toxic gas sensor: a review

verfasst von: Adilson Luís Pereira Silva, Natanael de Sousa Sousa, Jaldyr de Jesus Gomes Varela Júnior

Erschienen in: Journal of Nanoparticle Research | Ausgabe 1/2023

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Abstract

This systematic review presents an overview, from 2011 to 2022, of how pure B₁₂N₁₂ and B₁₂N₁₂-modified nanocages have been used to detect toxic gases from studies based on density functional theory (DFT). Searches were carried out in the ISI Web of Science, Science Direct, and Scopus databases to identify all studies related to B₁₂N₁₂ nanocages and, with the application of exclusion and inclusion criteria, to select articles involving theoretical studies of pure B₁₂N₁₂ and B₁₂N₁₂-modified nanocages as toxic gas sensors. In addition, from our analysis of these articles, we infer that a pure B₁₂N₁₂ nanocage can selectively detect O₃, HNO, NO, CO, ClCN, and FCN gases. However, it cannot detect N₂O and NH₃. In contrast, metal-modified B₁₂N₁₂ nanocage can detect a wider range of gases such as CO, NH₃, PH₃, AsH₃, SO₂, O₃, COCl₂, NCCN, and ClCN. However, few studies have discussed the interference effects due to the presence of other gases in the atmosphere and/or the incorporation of different structural modifications (decorated, doped, and encapsulated) into the cage. Lastly, this systematic review will guide the development of new applications of nanocages in the selective detection of toxic gases.

Graphical Abstract

Schematic representation of the detection of different toxic gases on a B₁₂N₁₂ nanocage surface.

Vorheriger Artikel Nanotechnology in stem cell research and therapy

Nächster Artikel To cleave or not—disulfide bond of cystine on nanocopper: a computational approach

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Titel: Theoretical studies with B12N12 as a toxic gas sensor: a review
verfasst von: Adilson Luís Pereira Silva
Natanael de Sousa Sousa
Jaldyr de Jesus Gomes Varela Júnior
Publikationsdatum: 01.01.2023
Verlag: Springer Netherlands
Erschienen in: Journal of Nanoparticle Research / Ausgabe 1/2023
Print ISSN: 1388-0764
Elektronische ISSN: 1572-896X
DOI: https://doi.org/10.1007/s11051-023-05667-9

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