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Metallurgical and Materials Transactions B

Erschienen in:

26.02.2016

Thermodynamic Assessment of Chrome-Spinel Formation in Laser-Sintered Coatings with Cr₂O₃ Particles

verfasst von: Mikhail Krivilyov, Evgeny Kharanzhevskiy, Sergey Reshetnikov, Lesley J. Beyers

Erschienen in: Metallurgical and Materials Transactions B | Ausgabe 3/2016

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Abstract

Formation of a thin passive layer has been performed using short pulse laser dispersion of Cr₂O₃ particles in a C22 steel substrate. As a result, the coating’s corrosion resistance is substantially improved compared to unprocessed samples. Microstructure analysis by TEM, XPS, and XRD showed that laser processing leads to dissolution of Cr₂O₃ with formation of Cr and Fe oxides, chrome-spinel, and metallic Cr dispersed in alpha and gamma Fe. Thermodynamic assessment revealed that the formation of pure chromium is caused by reduction of Cr₂O₃ and oxidation of iron. This reaction is promoted by shifting of chemical equilibrium at elevated temperatures in the molten zone under short pulse laser processing.

Vorheriger Artikel Analysis of Mold Friction in a Continuous Casting Using Wavelet Entropy

Nächster Artikel Mass Transfer Behavior of Phosphorus from the Liquid Slag Phase to Solid 2CaO·SiO2 in the Multiphase Dephosphorization Slag

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Titel: Thermodynamic Assessment of Chrome-Spinel Formation in Laser-Sintered Coatings with Cr2O3 Particles
verfasst von: Mikhail Krivilyov
Evgeny Kharanzhevskiy
Sergey Reshetnikov
Lesley J. Beyers
Publikationsdatum: 26.02.2016
Verlag: Springer US
Erschienen in: Metallurgical and Materials Transactions B / Ausgabe 3/2016
Print ISSN: 1073-5615
Elektronische ISSN: 1543-1916
DOI: https://doi.org/10.1007/s11663-016-0616-y

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