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Erschienen in: Wood Science and Technology 1/2018

27.09.2017 | Original

Thermogravimetric analysis of cork and cork components from Quercus variabilis

verfasst von: Weiwei Shangguan, Zhangjing Chen, Jingfeng Zhao, Xiaozhou Song

Erschienen in: Wood Science and Technology | Ausgabe 1/2018

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Abstract

Cork and cork components (suberin, lignin, holocellulose, sclereids, and lenticels) were obtained by manual and chemical methods. Dynamic thermogravimetric analysis was used to investigate the thermal behavior of cork and its components. Thermal decomposition of cork was different from that of natural fibers. Characteristic temperatures of thermal decomposition for cork and impurities (sclereids and lenticels) were related to their chemical components. Cork lignin has the decomposition characteristics of G-type (guaiacyl units) lignin, typical of softwood with high residual solids. The pyrolysis characteristics of Quercus variabilis Blume (Q. variabilis) suberin was close to Quercus cerris L. (Q. cerris) suberin. The decomposition temperature range of cork, lignin, or suberin was wider than that of sclereids, lenticels, or holocellulose. Activation energy of cork was lower than that of natural fibers. The activation energy of cork and the extracted suberin was slightly increased when the conversion rate α was greater than 0.35. Activation energies of sclereids and lenticels were close to each other due to similar composition and proportion in them.

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Literatur
Zurück zum Zitat Antal MJ, Varhegyi G (1995) Cellulose pyrolysis kinetic—the current state knowledge. Ind Eng Chem Res 34:703–717CrossRef Antal MJ, Varhegyi G (1995) Cellulose pyrolysis kinetic—the current state knowledge. Ind Eng Chem Res 34:703–717CrossRef
Zurück zum Zitat Aroso IV, Duarte ARC, Pires RR, Mano JF, Reis RL (2015) Cork processing with supercritical carbon dioxide: impregnation and sorption studies. J Supercrit Fluids 104:251–258CrossRef Aroso IV, Duarte ARC, Pires RR, Mano JF, Reis RL (2015) Cork processing with supercritical carbon dioxide: impregnation and sorption studies. J Supercrit Fluids 104:251–258CrossRef
Zurück zum Zitat Arrhenius S (1889) On the reaction rate of the inversion of non-refined sugar upon souring. Z Phys Chem 4:226–248 Arrhenius S (1889) On the reaction rate of the inversion of non-refined sugar upon souring. Z Phys Chem 4:226–248
Zurück zum Zitat Chevreul M (1807) De l’action de l’acide nitrique sur le liège (The effect of nitric acid on cork). Ann Chim 92:323–333 (in French) Chevreul M (1807) De l’action de l’acide nitrique sur le liège (The effect of nitric acid on cork). Ann Chim 92:323–333 (in French)
Zurück zum Zitat Cordeiro N, Belgacem NM, Gandini A, Neto CP (1998) Cork suberin as a new source of chemicals: 2. Crystallinity, thermal and rheological properties. Bioresour Technol 63:153–158CrossRef Cordeiro N, Belgacem NM, Gandini A, Neto CP (1998) Cork suberin as a new source of chemicals: 2. Crystallinity, thermal and rheological properties. Bioresour Technol 63:153–158CrossRef
Zurück zum Zitat Ferreira R, Garcia H, Sousa AF, Freire CSR, Silvestre AJD, Rebelo LPN, Pereira CS (2013) Isolation of suberin from birch outer bark and cork using ionic liquids: a new source of macromonomers. Ind Crop Prod 44:520–527CrossRef Ferreira R, Garcia H, Sousa AF, Freire CSR, Silvestre AJD, Rebelo LPN, Pereira CS (2013) Isolation of suberin from birch outer bark and cork using ionic liquids: a new source of macromonomers. Ind Crop Prod 44:520–527CrossRef
Zurück zum Zitat Ferreira J, Miranda I, Şen U, Pereira H (2016) Chemical and cellular features of virgin and reproduction cork from Quercus variabilis. Ind Crop Prod 94:638–648CrossRef Ferreira J, Miranda I, Şen U, Pereira H (2016) Chemical and cellular features of virgin and reproduction cork from Quercus variabilis. Ind Crop Prod 94:638–648CrossRef
Zurück zum Zitat Gangil S (2015) Superiority of intrinsic biopolymeric constituents in briquettes of lignocellulosic crop residues over wood: a TG-diagnosis. Renew Energy 76:478–483CrossRef Gangil S (2015) Superiority of intrinsic biopolymeric constituents in briquettes of lignocellulosic crop residues over wood: a TG-diagnosis. Renew Energy 76:478–483CrossRef
Zurück zum Zitat Graça J, Pereira H (2000) Methanolysis of bark suberins: analysis of glycerol and acid monomers. Phytochem Anal 11:45–51CrossRef Graça J, Pereira H (2000) Methanolysis of bark suberins: analysis of glycerol and acid monomers. Phytochem Anal 11:45–51CrossRef
Zurück zum Zitat Grønli MG, Várhegyi G, Blasi CD (2002) Thermogravimetric analysis and devolatilization kinetics of wood. Ind Eng Chem Res 41:4201–4208CrossRef Grønli MG, Várhegyi G, Blasi CD (2002) Thermogravimetric analysis and devolatilization kinetics of wood. Ind Eng Chem Res 41:4201–4208CrossRef
Zurück zum Zitat Hu J, Shen D, Xiao R, Wu S, Zhang H (2012) Free-Radical analysis on thermochemical transformation of lignin to phenolic compounds. Energy Fuels 27:1–12 Hu J, Shen D, Xiao R, Wu S, Zhang H (2012) Free-Radical analysis on thermochemical transformation of lignin to phenolic compounds. Energy Fuels 27:1–12
Zurück zum Zitat Lagorce-Tachon A, Karbowiak T, Champion D, Gougeon RD, Bellat JP (2015) Mechanical properties of cork: effect of hydration. Mater Design 82:148–154CrossRef Lagorce-Tachon A, Karbowiak T, Champion D, Gougeon RD, Bellat JP (2015) Mechanical properties of cork: effect of hydration. Mater Design 82:148–154CrossRef
Zurück zum Zitat Lee MY, Lee TS, Park WH (2001) Effect of side chains on the thermal degradation of poly (3-hydroxyalkanoates). Macromol Chem Phys 202:1257–1261CrossRef Lee MY, Lee TS, Park WH (2001) Effect of side chains on the thermal degradation of poly (3-hydroxyalkanoates). Macromol Chem Phys 202:1257–1261CrossRef
Zurück zum Zitat Liu Z (1991) An introduction to thermal analysis, 1st edn. Chemical Industry Press, Beijing Liu Z (1991) An introduction to thermal analysis, 1st edn. Chemical Industry Press, Beijing
Zurück zum Zitat Liu T, Li B (2012) Kinetic studies on the pyrolysis of a water-soluble chitosan. J Huazhong Norm Univ 46:65–70CrossRef Liu T, Li B (2012) Kinetic studies on the pyrolysis of a water-soluble chitosan. J Huazhong Norm Univ 46:65–70CrossRef
Zurück zum Zitat Liu Q, Wang S, Zheng Y, Luo Z, Cen K (2008) Mechanism study of wood lignin pyrolysis by using TG–FTIR analysis. J Anal Appl Pyrolysis 82:170–177CrossRef Liu Q, Wang S, Zheng Y, Luo Z, Cen K (2008) Mechanism study of wood lignin pyrolysis by using TG–FTIR analysis. J Anal Appl Pyrolysis 82:170–177CrossRef
Zurück zum Zitat Pereira H (1992) The thermochemical degradation of cork. Wood Sci Technol 26:259–269CrossRef Pereira H (1992) The thermochemical degradation of cork. Wood Sci Technol 26:259–269CrossRef
Zurück zum Zitat Pereira H (2007) Cork: biology, production and uses. Elsevier Science, Amsterdam Pereira H (2007) Cork: biology, production and uses. Elsevier Science, Amsterdam
Zurück zum Zitat Rosa ME, Fortes MA (1987) Temperature-induced alteration of the structure and mechanical properties of cork. Mater Sci Eng 100:69–78CrossRef Rosa ME, Fortes MA (1987) Temperature-induced alteration of the structure and mechanical properties of cork. Mater Sci Eng 100:69–78CrossRef
Zurück zum Zitat Şen A, Miranda I, Santos S, Graça J, Pereira H (2010) The chemical composition of cork and phloem in the rhytidome of Quercus cerris bark. Ind Crops Prod 31:417–422CrossRef Şen A, Miranda I, Santos S, Graça J, Pereira H (2010) The chemical composition of cork and phloem in the rhytidome of Quercus cerris bark. Ind Crops Prod 31:417–422CrossRef
Zurück zum Zitat Şen A, Marques AV, Gominho J, Pereira H (2012) Study of thermochemical treatments of cork in the 150–400 °C range using colour analysis and FTIR spectroscopy. Ind Crops Prod 38:132–138CrossRef Şen A, Marques AV, Gominho J, Pereira H (2012) Study of thermochemical treatments of cork in the 150–400 °C range using colour analysis and FTIR spectroscopy. Ind Crops Prod 38:132–138CrossRef
Zurück zum Zitat Şen A, Bulcke JV, Defoirdt N, Acker JV, Pereira H (2014) Thermal behaviour of cork and cork components. Thermochim Acta 582:94–100CrossRef Şen A, Bulcke JV, Defoirdt N, Acker JV, Pereira H (2014) Thermal behaviour of cork and cork components. Thermochim Acta 582:94–100CrossRef
Zurück zum Zitat Shen D, Zhang L, Xue J, Guan S, Qian L, Xiao R (2015) Thermal degradation of xylan-based hemicellulose under oxidative atmosphere. Carbohydr Polym 12:363–371CrossRef Shen D, Zhang L, Xue J, Guan S, Qian L, Xiao R (2015) Thermal degradation of xylan-based hemicellulose under oxidative atmosphere. Carbohydr Polym 12:363–371CrossRef
Zurück zum Zitat Silva SP, Sabino MA, Fernandes EM, Correlo VN, Boesel LF, Reis RL (2005) Cork: properties, capabilities and applications. Int Mater Rev 50:345–365CrossRef Silva SP, Sabino MA, Fernandes EM, Correlo VN, Boesel LF, Reis RL (2005) Cork: properties, capabilities and applications. Int Mater Rev 50:345–365CrossRef
Zurück zum Zitat Sousa AF, Gandini A, Caetano A, Maria TM, Freire CS, Neto CP, Silvestre AJ (2016) Unravelling the distinct crystallinity and thermal properties of suberin compounds from Quercus suber and Betula pendula outer barks. Int J Biol Macromol 93:686–694CrossRefPubMed Sousa AF, Gandini A, Caetano A, Maria TM, Freire CS, Neto CP, Silvestre AJ (2016) Unravelling the distinct crystallinity and thermal properties of suberin compounds from Quercus suber and Betula pendula outer barks. Int J Biol Macromol 93:686–694CrossRefPubMed
Zurück zum Zitat TAPPI (1975) Holocellulose in wood. Standard Test Method 9 wd-75. Technical association of the pulp and paper industry, Atlanta, GA, USA TAPPI (1975) Holocellulose in wood. Standard Test Method 9 wd-75. Technical association of the pulp and paper industry, Atlanta, GA, USA
Zurück zum Zitat TAPPI (2011) Acid-insoluble lignin in wood and pulp. Standard Test Method 222 om-11. Technical association of the pulp and paper industry, Atlanta, GA, USA TAPPI (2011) Acid-insoluble lignin in wood and pulp. Standard Test Method 222 om-11. Technical association of the pulp and paper industry, Atlanta, GA, USA
Zurück zum Zitat Tian L, Shen B, Xu H, Li F, Wang Y, Singh S (2016) Thermal behavior of waste tea pyrolysis by TG-FTIR analysis. Energy 103:533–542CrossRef Tian L, Shen B, Xu H, Li F, Wang Y, Singh S (2016) Thermal behavior of waste tea pyrolysis by TG-FTIR analysis. Energy 103:533–542CrossRef
Zurück zum Zitat Trockenbrodt M (1995) Calcium oxalate crystals in the bark of Quercus robur, Ulmus glabra, Populus tremula and Betula pendula. Ann Bot 75:281–284CrossRef Trockenbrodt M (1995) Calcium oxalate crystals in the bark of Quercus robur, Ulmus glabra, Populus tremula and Betula pendula. Ann Bot 75:281–284CrossRef
Zurück zum Zitat Tsujiyama S, Miyamori A (2000) Assignment of DSC thermograms of wood and its components. Thermochim Acta 351:177–181CrossRef Tsujiyama S, Miyamori A (2000) Assignment of DSC thermograms of wood and its components. Thermochim Acta 351:177–181CrossRef
Zurück zum Zitat Vyazovkin S (2000) Kinetic concepts of thermally stimulated reactions in solids: a view from a historical perspective. Int Rev Phys Chem 19:45–60CrossRef Vyazovkin S (2000) Kinetic concepts of thermally stimulated reactions in solids: a view from a historical perspective. Int Rev Phys Chem 19:45–60CrossRef
Zurück zum Zitat Wang W (2008) Study on thermogravimetric analysis and pyrolysis kinetics of cellulose. Chongqing University, Chongqing Wang W (2008) Study on thermogravimetric analysis and pyrolysis kinetics of cellulose. Chongqing University, Chongqing
Zurück zum Zitat Wang S, Lin H, Ru B, Sun W, Wang Y, Luo Z (2014) Comparison of the pyrolysis behavior of pyrolytic lignin and milled wood lignin by using TG–FTIR analysis. J Anal Appl Pyrolysis 108:78–85CrossRef Wang S, Lin H, Ru B, Sun W, Wang Y, Luo Z (2014) Comparison of the pyrolysis behavior of pyrolytic lignin and milled wood lignin by using TG–FTIR analysis. J Anal Appl Pyrolysis 108:78–85CrossRef
Zurück zum Zitat Yang H, Yan R, Chen H, Dong HL, Zheng C (2007) Characteristics of hemicellulose, cellulose and lignin pyrolysis. Fuel 86:1781–1788CrossRef Yang H, Yan R, Chen H, Dong HL, Zheng C (2007) Characteristics of hemicellulose, cellulose and lignin pyrolysis. Fuel 86:1781–1788CrossRef
Zurück zum Zitat Yao F, Wu Q, Lei Y, Guo W, Xu Y (2008) Thermal decomposition kinetics of natural fibers: activation energy with dynamic thermogravimetric analysis. Polym Degrad Stab 93:90–98CrossRef Yao F, Wu Q, Lei Y, Guo W, Xu Y (2008) Thermal decomposition kinetics of natural fibers: activation energy with dynamic thermogravimetric analysis. Polym Degrad Stab 93:90–98CrossRef
Zurück zum Zitat Yu H, Liu F, Ke M, Zhang X (2015) Thermogravimetric analysis and kinetic study of bamboo waste treated by Echinodontium taxodii using a modified three-parallel-reactions model. Bioresour Technol 185:324–330CrossRefPubMed Yu H, Liu F, Ke M, Zhang X (2015) Thermogravimetric analysis and kinetic study of bamboo waste treated by Echinodontium taxodii using a modified three-parallel-reactions model. Bioresour Technol 185:324–330CrossRefPubMed
Zurück zum Zitat Zhao J (2012) Research in expansion impurities removing technology and mechanisms of Quercus variabilis cork. North west A&F University, Yanling Zhao J (2012) Research in expansion impurities removing technology and mechanisms of Quercus variabilis cork. North west A&F University, Yanling
Zurück zum Zitat Zhao J, Feng D, Lei Y, Zhang W, Zhang Y (2013) Cell structure and chemical components of sclereids and lenticels from Quercus variabilis cork. J Northwest Sci Tech Univ Agric For 41:119–124 Zhao J, Feng D, Lei Y, Zhang W, Zhang Y (2013) Cell structure and chemical components of sclereids and lenticels from Quercus variabilis cork. J Northwest Sci Tech Univ Agric For 41:119–124
Zurück zum Zitat Zhao J, Wang X, Hu J, Liu Q, Shen D, Xiao R (2014) Thermal degradation of softwood lignin and hardwood lignin by TG-FTIR and Py-GC/MS. Polym Degrad Stab 108:133–138CrossRef Zhao J, Wang X, Hu J, Liu Q, Shen D, Xiao R (2014) Thermal degradation of softwood lignin and hardwood lignin by TG-FTIR and Py-GC/MS. Polym Degrad Stab 108:133–138CrossRef
Zurück zum Zitat Zhao J, Song X, Feng D, Lei Y, Zhang Y (2015) Expansion and impurity removal technology for Quercus variabilis cork. J Northwest Sci Tech Univ Agric For 43:87–92 Zhao J, Song X, Feng D, Lei Y, Zhang Y (2015) Expansion and impurity removal technology for Quercus variabilis cork. J Northwest Sci Tech Univ Agric For 43:87–92
Zurück zum Zitat Zhao C, Jiang E, Chen A (2016) Volatile production from pyrolysis of cellulose, hemicellulose and lignin. J Energy Inst 13:1–12 Zhao C, Jiang E, Chen A (2016) Volatile production from pyrolysis of cellulose, hemicellulose and lignin. J Energy Inst 13:1–12
Zurück zum Zitat Zou H, Hu K, Gui L, Cheng L, Lu H (2011) Research on optimal characterization method of CaC2O4·H2O by thermogravimetry-differential thermal analyzer. J Guangxi Acad Sci 27:17–21 Zou H, Hu K, Gui L, Cheng L, Lu H (2011) Research on optimal characterization method of CaC2O4·H2O by thermogravimetry-differential thermal analyzer. J Guangxi Acad Sci 27:17–21
Metadaten
Titel
Thermogravimetric analysis of cork and cork components from Quercus variabilis
verfasst von
Weiwei Shangguan
Zhangjing Chen
Jingfeng Zhao
Xiaozhou Song
Publikationsdatum
27.09.2017
Verlag
Springer Berlin Heidelberg
Erschienen in
Wood Science and Technology / Ausgabe 1/2018
Print ISSN: 0043-7719
Elektronische ISSN: 1432-5225
DOI
https://doi.org/10.1007/s00226-017-0959-9

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