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29.07.2017 | Original Paper

Thermoresponsive poly(poly(ethylene glycol) methylacrylate)s grafted cellulose nanocrystals through SI-ATRP polymerization

verfasst von: Xiuqiang Zhang, Jinlong Zhang, Lili Dong, Suxia Ren, Qinglin Wu, Tingzhou Lei

Erschienen in: Cellulose | Ausgabe 10/2017

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Abstract

We report a series of thermoresponsive cellulose nanocrystals (CNCs) decorated with poly(poly(ethylene glycol) methylacrylate) copolymers (poly(PEGMA)-g-CNCs) synthesized by surface initiated-atom transfer radical polymerization (SI-ATRP). The chemical structures and surface morphologies were subsequently confirmed by FT-IR, XPS, and AFM measurements. With regard to thermally responsive behavior, poly(PEGMA)-g-CNCs show tunable lower critical solution temperature (LCST) values in the range of 34–66 °C by varying the feeding ratios of comonomers. The reversible morphological transformation from individual nano-rod structures to larger globule aggregates was further verified by AFM during the LCST transition. These functionalized CNCs have potential as smart film filters and biosensors.

Vorheriger Artikel Mechanical fabrication of high-strength and redispersible wood nanofibers from unbleached groundwood pulp

Nächster Artikel Effect of fiber drying on properties of lignin containing cellulose nanocrystals and nanofibrils produced through maleic acid hydrolysis

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Titel: Thermoresponsive poly(poly(ethylene glycol) methylacrylate)s grafted cellulose nanocrystals through SI-ATRP polymerization
verfasst von: Xiuqiang Zhang
Jinlong Zhang
Lili Dong
Suxia Ren
Qinglin Wu
Tingzhou Lei
Publikationsdatum: 29.07.2017
Verlag: Springer Netherlands
Erschienen in: Cellulose / Ausgabe 10/2017
Print ISSN: 0969-0239
Elektronische ISSN: 1572-882X
DOI: https://doi.org/10.1007/s10570-017-1414-7

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