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2013 | OriginalPaper | Buchkapitel

18. Tracers for Biogenic Secondary Organic Aerosol from α-Pinene and Related Monoterpenes: An Overview

verfasst von : Magda Claeys, Rafal Szmigielski, Reinhilde Vermeylen, Wu Wang, Mohammad Safi Shalamzari, Willy Maenhaut

Erschienen in: Disposal of Dangerous Chemicals in Urban Areas and Mega Cities

Verlag: Springer Netherlands

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Abstract

In this review, we first address the terpenoid composition of ambient fine rural aerosol to give a report on the current state of knowledge in regard to the molecular characterisation of biogenic secondary organic aerosol tracers. The major known, recently elucidated, and still unknown tracers, which can be detected at a significant relative abundance, are listed and briefly discussed. In a second part, we provide a historic account on the discovery of 3-methyl-1,2,3-butanetricarboxylic acid, which involved a long search with several failures and a final success, and propose a revised formation pathway. Finally, we present some brief conclusions and perspectives.

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Literatur
1.
Zurück zum Zitat Christoffersen TS, Hjorth J, Horie O, Jensen NR, Kotzias D, Molander L, Neeb P, Ruppert L, Winterhalter R, Virkkula A, Wirtz K, Larsen BR (1998) cis-Pinic acid, a possible precursor for organic aerosol formation from ozonolysis of α-pinene. Atmos Environ 32:1657–1661CrossRef Christoffersen TS, Hjorth J, Horie O, Jensen NR, Kotzias D, Molander L, Neeb P, Ruppert L, Winterhalter R, Virkkula A, Wirtz K, Larsen BR (1998) cis-Pinic acid, a possible precursor for organic aerosol formation from ozonolysis of α-pinene. Atmos Environ 32:1657–1661CrossRef
2.
Zurück zum Zitat Claeys M, Szmigielski R, Kourtchev I, Van der Veken P, Vermeylen R, Maenhaut W, Jaoui M, Kleindienst TE, Lewandowski M, Offenberg JH, Edney EO (2007) Hydroxydicarboxylic acids: novel markers for secondary organic aerosol from the photooxidation of α-pinene. Environ Sci Technol 41:1628–1634CrossRef Claeys M, Szmigielski R, Kourtchev I, Van der Veken P, Vermeylen R, Maenhaut W, Jaoui M, Kleindienst TE, Lewandowski M, Offenberg JH, Edney EO (2007) Hydroxydicarboxylic acids: novel markers for secondary organic aerosol from the photooxidation of α-pinene. Environ Sci Technol 41:1628–1634CrossRef
3.
Zurück zum Zitat Claeys M, Iinuma Y, Szmigielski R, Surratt JD, Blockhuys F, Van Alsenoy C, Böge O, Sierau B, Gómez-González Y, Vermeylen R, Van der Veken P, Shahgholi M, Chan AWH, Herrmann H, Seinfeld JH, Maenhaut W (2009) Terpenylic acid and related compounds from the oxidation of α-pinene: implications for new particle formation and growth above forest. Environ Sci Technol 43:6976–6982CrossRef Claeys M, Iinuma Y, Szmigielski R, Surratt JD, Blockhuys F, Van Alsenoy C, Böge O, Sierau B, Gómez-González Y, Vermeylen R, Van der Veken P, Shahgholi M, Chan AWH, Herrmann H, Seinfeld JH, Maenhaut W (2009) Terpenylic acid and related compounds from the oxidation of α-pinene: implications for new particle formation and growth above forest. Environ Sci Technol 43:6976–6982CrossRef
4.
Zurück zum Zitat Gao Y, Hall WA IV, Johnston MV (2010) Molecular composition of monoterpene secondary organic aerosol at low mass loading. Environ Sci Technol 44:7897–7902CrossRef Gao Y, Hall WA IV, Johnston MV (2010) Molecular composition of monoterpene secondary organic aerosol at low mass loading. Environ Sci Technol 44:7897–7902CrossRef
5.
Zurück zum Zitat George IJ, Abbatt JPD (2010) Chemical evolution of secondary organic aerosol from OH-initiated heterogeneous oxidation. Atmos Chem Phys 10:5551–5563CrossRef George IJ, Abbatt JPD (2010) Chemical evolution of secondary organic aerosol from OH-initiated heterogeneous oxidation. Atmos Chem Phys 10:5551–5563CrossRef
6.
Zurück zum Zitat Glasius M, Duane M, Larsen BR (1999) Determination of polar terpene oxidation products in aerosols by liquid chromatography-ion trap mass spectrometry. J Chromatogr A 833:121–135CrossRef Glasius M, Duane M, Larsen BR (1999) Determination of polar terpene oxidation products in aerosols by liquid chromatography-ion trap mass spectrometry. J Chromatogr A 833:121–135CrossRef
7.
Zurück zum Zitat Glasius M, Lahaniati M, Calogirou A, Di Bella D, Jensen NR, Hjorth J, Duane M, Kotzias D, Larsen BR (2000) Carboxylic acids in secondary aerosols from oxidation of cyclic monoterpenes by ozone. Environ Sci Technol 34:1001–1010CrossRef Glasius M, Lahaniati M, Calogirou A, Di Bella D, Jensen NR, Hjorth J, Duane M, Kotzias D, Larsen BR (2000) Carboxylic acids in secondary aerosols from oxidation of cyclic monoterpenes by ozone. Environ Sci Technol 34:1001–1010CrossRef
8.
Zurück zum Zitat Gómez-González Y, Surratt JD, Cuyckens F, Szmigielski R, Vermeylen R, Jaoui M, Lewandowski M, Offenberg JH, Kleindienst TE, Edney EO, Blockhuys F, Van Alsenoy C, Maenhaut W, Claeys M (2008) Characterization of organosulfates from the photooxidation of isoprene and unsaturated fatty acids in ambient aerosol using liquid chromatography/(-)electrospray ionization mass spectrometry. J Mass Spectrom 43:371–382CrossRef Gómez-González Y, Surratt JD, Cuyckens F, Szmigielski R, Vermeylen R, Jaoui M, Lewandowski M, Offenberg JH, Kleindienst TE, Edney EO, Blockhuys F, Van Alsenoy C, Maenhaut W, Claeys M (2008) Characterization of organosulfates from the photooxidation of isoprene and unsaturated fatty acids in ambient aerosol using liquid chromatography/(-)electrospray ionization mass spectrometry. J Mass Spectrom 43:371–382CrossRef
9.
Zurück zum Zitat Gómez-González Y, Wang W, Vermeylen R, Chi X, Neirynck J, Janssens IA, Maenhaut W, Claeys M (2012) Chemical characterization of atmospheric aerosols during a 2007 summer field campaign at Brasschaat, Belgium: sources and source processes of biogenic secondary organic aerosol. Atmos Chem Phys 12:125–138CrossRef Gómez-González Y, Wang W, Vermeylen R, Chi X, Neirynck J, Janssens IA, Maenhaut W, Claeys M (2012) Chemical characterization of atmospheric aerosols during a 2007 summer field campaign at Brasschaat, Belgium: sources and source processes of biogenic secondary organic aerosol. Atmos Chem Phys 12:125–138CrossRef
10.
Zurück zum Zitat Hallquist M, Wenger JC, Baltensperger U, Rudich Y, Simpson D, Claeys M, Dommen J, Donahue NM, George C, Goldstein AH, Hamilton JF, Herrmann H, Hoffmann T, Iinuma Y, Jang M, Jenkin ME, Jimenez JL, Kiendler-Scharr A, Maenhaut W, McFiggans G, Mentel TF, Monod A, Prévôt ASH, Seinfeld JH, Surratt JD, Szmigielski R, Wildt J (2009) The formation, properties and impact of secondary organic aerosol: current and emerging issues. Atmos Chem Phys 9:5155–5236CrossRef Hallquist M, Wenger JC, Baltensperger U, Rudich Y, Simpson D, Claeys M, Dommen J, Donahue NM, George C, Goldstein AH, Hamilton JF, Herrmann H, Hoffmann T, Iinuma Y, Jang M, Jenkin ME, Jimenez JL, Kiendler-Scharr A, Maenhaut W, McFiggans G, Mentel TF, Monod A, Prévôt ASH, Seinfeld JH, Surratt JD, Szmigielski R, Wildt J (2009) The formation, properties and impact of secondary organic aerosol: current and emerging issues. Atmos Chem Phys 9:5155–5236CrossRef
11.
Zurück zum Zitat Hatakeyama S, Izumi K, Fukuyama T, Akimoto H (1989) Reactions of ozone with alpha-pinene and beta-pinene in air – yields of gaseous and particulate products. J Geophys Res Atmos 94:13013–13024CrossRef Hatakeyama S, Izumi K, Fukuyama T, Akimoto H (1989) Reactions of ozone with alpha-pinene and beta-pinene in air – yields of gaseous and particulate products. J Geophys Res Atmos 94:13013–13024CrossRef
12.
Zurück zum Zitat Hoffmann T, Odum JR, Bowman F, Collins D, Klockow D, Flagan RC, Seinfeld JH (1997) Formation of organic aerosols from the oxidation of biogenic hydrocarbons. J Atmos Chem 26:189–222CrossRef Hoffmann T, Odum JR, Bowman F, Collins D, Klockow D, Flagan RC, Seinfeld JH (1997) Formation of organic aerosols from the oxidation of biogenic hydrocarbons. J Atmos Chem 26:189–222CrossRef
13.
Zurück zum Zitat Hoffmann T, Bandur R, Marggraf U, Linscheid M (1998) Molecular composition of organic aerosols formed in the α-pinene/O3 reaction: implications for new particle formation processes. J Geophys Res Atmos 103:25569–25578CrossRef Hoffmann T, Bandur R, Marggraf U, Linscheid M (1998) Molecular composition of organic aerosols formed in the α-pinene/O3 reaction: implications for new particle formation processes. J Geophys Res Atmos 103:25569–25578CrossRef
14.
Zurück zum Zitat Iinuma Y, Müller C, Böge O, Gnauk T, Herrmann H (2007) The formation of organic sulfate esters in the limonene ozonolysis secondary organic aerosol (SOA) under acidic conditions. Atmos Environ 41:5571–5583CrossRef Iinuma Y, Müller C, Böge O, Gnauk T, Herrmann H (2007) The formation of organic sulfate esters in the limonene ozonolysis secondary organic aerosol (SOA) under acidic conditions. Atmos Environ 41:5571–5583CrossRef
15.
Zurück zum Zitat Iinuma Y, Müller C, Berndt T, Böge O, Claeys M, Herrmann H (2007) Evidence for the existence of organosulfates from beta-pinene ozonolysis in ambient secondary organic aerosol. Environ Sci Technol 41:6678–6683CrossRef Iinuma Y, Müller C, Berndt T, Böge O, Claeys M, Herrmann H (2007) Evidence for the existence of organosulfates from beta-pinene ozonolysis in ambient secondary organic aerosol. Environ Sci Technol 41:6678–6683CrossRef
16.
Zurück zum Zitat Iinuma Y, Böge O, Keywood M, Gnauk T, Herrmann H (2009) Diaterebic acid acetate and diaterpenylic acid acetate: atmospheric tracers for secondary organic aerosol formation from 1,8-cineole oxidation. Environ Sci Technol 43:280–285CrossRef Iinuma Y, Böge O, Keywood M, Gnauk T, Herrmann H (2009) Diaterebic acid acetate and diaterpenylic acid acetate: atmospheric tracers for secondary organic aerosol formation from 1,8-cineole oxidation. Environ Sci Technol 43:280–285CrossRef
17.
Zurück zum Zitat Jang M, Kamens RM (1999) Newly characterized products and composition of secondary aerosols from the reaction of α-pinene and ozone. Atmos Environ 33:459–474CrossRef Jang M, Kamens RM (1999) Newly characterized products and composition of secondary aerosols from the reaction of α-pinene and ozone. Atmos Environ 33:459–474CrossRef
18.
Zurück zum Zitat Jaoui M, Kleindienst TE, Lewandowski M, Offenberg JH, Edney EO (2005) Identification and quantification of aerosol polar oxygenated compounds bearing carboxylic or hydroxyl groups: 2 organic tracer compounds from monoterpenes. Environ Sci Technol 39:5661–5673CrossRef Jaoui M, Kleindienst TE, Lewandowski M, Offenberg JH, Edney EO (2005) Identification and quantification of aerosol polar oxygenated compounds bearing carboxylic or hydroxyl groups: 2 organic tracer compounds from monoterpenes. Environ Sci Technol 39:5661–5673CrossRef
19.
Zurück zum Zitat Jimenez JL, Canagaratna MR, Donahue NM, Prévôt ASH, Zhang Q, Kroll JH, DeCarlo PF, Allan JD, Coe H, Ng NL, Aiken AC, Docherty KS, Ulbrich IM, Grieshop AP, Robinson AL, Duplissy J, Smith JD, Wilson KR, Lanz VA, Hueglin C, Sun YL, Tian J, Laaksonen A, Raatikainen T, Rautiainen J, Vaattovaara P, Ehn M, Kulmala M, Tomlinson JM, Collins DR, Cubison MJ, Dunlea EJ, Huffman JA, Onasch TB, Alfarra MR, Williams PI, Bower K, Kondo Y, Schneider J, Drewnick F, Borrmann S, Weimer S, Demerjian K, Salcedo D, Cottrell L, Griffin R, Takami A, Miyoshi T, Hatakeyama S, Shimono A, Sun JY, Zhang YM, Dzepina K, Kimmel JR, Sueper D, Jayne JT, Herndon SC, Trimborn AM, Williams LR, Wood EC, Middlebrook AM, Kolb CE, Baltensperger U, Worsnop DR (2009) Evolution of organic aerosols in the atmosphere. Science 326:1525–1529CrossRef Jimenez JL, Canagaratna MR, Donahue NM, Prévôt ASH, Zhang Q, Kroll JH, DeCarlo PF, Allan JD, Coe H, Ng NL, Aiken AC, Docherty KS, Ulbrich IM, Grieshop AP, Robinson AL, Duplissy J, Smith JD, Wilson KR, Lanz VA, Hueglin C, Sun YL, Tian J, Laaksonen A, Raatikainen T, Rautiainen J, Vaattovaara P, Ehn M, Kulmala M, Tomlinson JM, Collins DR, Cubison MJ, Dunlea EJ, Huffman JA, Onasch TB, Alfarra MR, Williams PI, Bower K, Kondo Y, Schneider J, Drewnick F, Borrmann S, Weimer S, Demerjian K, Salcedo D, Cottrell L, Griffin R, Takami A, Miyoshi T, Hatakeyama S, Shimono A, Sun JY, Zhang YM, Dzepina K, Kimmel JR, Sueper D, Jayne JT, Herndon SC, Trimborn AM, Williams LR, Wood EC, Middlebrook AM, Kolb CE, Baltensperger U, Worsnop DR (2009) Evolution of organic aerosols in the atmosphere. Science 326:1525–1529CrossRef
20.
Zurück zum Zitat Kourtchev I, Copolovici L, Claeys M, Maenhaut W (2009) Characterization of atmospheric aerosols at a forested site in Central Europe. Environ Sci Technol 43:4665–4671CrossRef Kourtchev I, Copolovici L, Claeys M, Maenhaut W (2009) Characterization of atmospheric aerosols at a forested site in Central Europe. Environ Sci Technol 43:4665–4671CrossRef
21.
Zurück zum Zitat Kristensen K, Glasius M (2011) Organosulfates and oxidation products from biogenic hydrocarbons in fine aerosols from a forest in North West Europe during spring. Atmos Environ 45:4546–4556CrossRef Kristensen K, Glasius M (2011) Organosulfates and oxidation products from biogenic hydrocarbons in fine aerosols from a forest in North West Europe during spring. Atmos Environ 45:4546–4556CrossRef
22.
Zurück zum Zitat Kroll JH, Seinfeld JH (2008) Chemistry of secondary organic aerosol: formation and evolution of low-volatility organics in the atmosphere. Atmos Environ 42:3593–3624CrossRef Kroll JH, Seinfeld JH (2008) Chemistry of secondary organic aerosol: formation and evolution of low-volatility organics in the atmosphere. Atmos Environ 42:3593–3624CrossRef
23.
Zurück zum Zitat Kroll JH, Donahue NM, Jimenez JL, Kessler SH, Canagaratna MR, Wilson KR, Altieri KE, Mazzoleni LR, Wozniak AS, Bluhm H, Mysak ER, Smith JD, Kolb CE, Worsnop DR (2011) Carbon oxidation state as a metric for describing the chemistry of atmospheric organic aerosol. Nat Chem 3:133–139CrossRef Kroll JH, Donahue NM, Jimenez JL, Kessler SH, Canagaratna MR, Wilson KR, Altieri KE, Mazzoleni LR, Wozniak AS, Bluhm H, Mysak ER, Smith JD, Kolb CE, Worsnop DR (2011) Carbon oxidation state as a metric for describing the chemistry of atmospheric organic aerosol. Nat Chem 3:133–139CrossRef
24.
Zurück zum Zitat Kubátová A, Vermeylen R, Claeys M, Cafmeyer J, Maenhaut W, Roberts G, Artaxo P (2000) Carbonaceous aerosol characterization in the Amazon basin, Brasil: novel dicarboxylic acids and related compounds. Atmos Environ 34:5037–5051CrossRef Kubátová A, Vermeylen R, Claeys M, Cafmeyer J, Maenhaut W, Roberts G, Artaxo P (2000) Carbonaceous aerosol characterization in the Amazon basin, Brasil: novel dicarboxylic acids and related compounds. Atmos Environ 34:5037–5051CrossRef
25.
Zurück zum Zitat Larsen BR, Lahaniati M, Calogirou A, Kotzias D (1998) Atmospheric oxidation products of terpenes: a new nomenclature. Chemosphere 37:1207–1220CrossRef Larsen BR, Lahaniati M, Calogirou A, Kotzias D (1998) Atmospheric oxidation products of terpenes: a new nomenclature. Chemosphere 37:1207–1220CrossRef
26.
Zurück zum Zitat Larsen BR, Di Bella D, Glasius M, Winterhalter R, Jensen NR, Hjorth J (2001) Gas-phase OH oxidation of monoterpenes: gaseous and particulate products. J Atmos Chem 38:231–276CrossRef Larsen BR, Di Bella D, Glasius M, Winterhalter R, Jensen NR, Hjorth J (2001) Gas-phase OH oxidation of monoterpenes: gaseous and particulate products. J Atmos Chem 38:231–276CrossRef
27.
Zurück zum Zitat Maenhaut W, Wang W, Chi X (2011) Semivolatile behaviour and filter sampling artifacts for dicarboxylic acids during summer campaigns at three forested sites in Europe. Boreal Environ Res 16:273–287 Maenhaut W, Wang W, Chi X (2011) Semivolatile behaviour and filter sampling artifacts for dicarboxylic acids during summer campaigns at three forested sites in Europe. Boreal Environ Res 16:273–287
28.
Zurück zum Zitat Müller L, Reinnig M-C, Warnke J, Hoffmann T (2008) Unambiguous identification of esters as oligomers in secondary organic aerosol formed from cyclohexene and cyclohexene/α-pinene ozonolysis. Atmos Chem Phys 8:1423–1433CrossRef Müller L, Reinnig M-C, Warnke J, Hoffmann T (2008) Unambiguous identification of esters as oligomers in secondary organic aerosol formed from cyclohexene and cyclohexene/α-pinene ozonolysis. Atmos Chem Phys 8:1423–1433CrossRef
29.
Zurück zum Zitat Müller L, Reinnig M-C, Naumann KH, Saathoff H, Mentel TF, Donahue N, Hoffmann T (2011) Formation of 3-methyl-1,2,3-butanetricarboxylic acid via gas phase oxidation of pinonic acid – a mass spectrometric study of SOA aging. Atmos Chem Phys Discuss 11:19443–19476CrossRef Müller L, Reinnig M-C, Naumann KH, Saathoff H, Mentel TF, Donahue N, Hoffmann T (2011) Formation of 3-methyl-1,2,3-butanetricarboxylic acid via gas phase oxidation of pinonic acid – a mass spectrometric study of SOA aging. Atmos Chem Phys Discuss 11:19443–19476CrossRef
30.
Zurück zum Zitat Nizkorodov SA, Laskin J, Laskin A (2011) Molecular chemistry of organic aerosols through the application of high resolution mass spectrometry. Phys Chem Chem Phys 13:3612–3629CrossRef Nizkorodov SA, Laskin J, Laskin A (2011) Molecular chemistry of organic aerosols through the application of high resolution mass spectrometry. Phys Chem Chem Phys 13:3612–3629CrossRef
31.
Zurück zum Zitat Putman AL, Offenberg JH, Fisseha R, Kundu S, Rahn TA, Mazzoleni LR (2012) Ultrahigh-resolution FT-ICR mass spectrometry characterization of α-pinene ozonolysis SOA. Atmos Environ 46:164–172CrossRef Putman AL, Offenberg JH, Fisseha R, Kundu S, Rahn TA, Mazzoleni LR (2012) Ultrahigh-resolution FT-ICR mass spectrometry characterization of α-pinene ozonolysis SOA. Atmos Environ 46:164–172CrossRef
32.
Zurück zum Zitat Reinhardt A, Emmenegger C, Gerrits B, Panse C, Dommen J, Baltensperger U, Zenobi R, Kalberer M (2007) Ultrahigh mass resolution and accurate mass measurements as a tool to characterize oligomers in secondary organic aerosols. Anal Chem 79:4074–4082CrossRef Reinhardt A, Emmenegger C, Gerrits B, Panse C, Dommen J, Baltensperger U, Zenobi R, Kalberer M (2007) Ultrahigh mass resolution and accurate mass measurements as a tool to characterize oligomers in secondary organic aerosols. Anal Chem 79:4074–4082CrossRef
33.
Zurück zum Zitat Surratt JD, Kroll JH, Kleindienst TE, Edney EO, Claeys M, Sorooshian A, Ng NL, Offenberg JH, Lewandowski M, Jaoui M, Flagan RC, Seinfeld JH (2007) Evidence for organosulfates in secondary organic aerosol. Environ Sci Technol 41:517–527CrossRef Surratt JD, Kroll JH, Kleindienst TE, Edney EO, Claeys M, Sorooshian A, Ng NL, Offenberg JH, Lewandowski M, Jaoui M, Flagan RC, Seinfeld JH (2007) Evidence for organosulfates in secondary organic aerosol. Environ Sci Technol 41:517–527CrossRef
34.
Zurück zum Zitat Surratt JD, Gómez-González Y, Chan AWH, Vermeylen R, Shahgholi M, Kleindienst TE, Edney EO, Offenberg JH, Lewandowski M, Jaoui M, Maenhaut W, Claeys M, Flagan RC, Seinfeld JH (2008) Organosulfate formation in biogenic secondary organic aerosol. J Phys Chem A 112:8345–8378CrossRef Surratt JD, Gómez-González Y, Chan AWH, Vermeylen R, Shahgholi M, Kleindienst TE, Edney EO, Offenberg JH, Lewandowski M, Jaoui M, Maenhaut W, Claeys M, Flagan RC, Seinfeld JH (2008) Organosulfate formation in biogenic secondary organic aerosol. J Phys Chem A 112:8345–8378CrossRef
35.
Zurück zum Zitat Surratt JD, Chan AWH, Eddingsaas NC, Chan MN, Loza CL, Kwan AJ, Hersey SP, Flagan RC, Wennberg PO, Seinfeld JH (2010) Reactive intermediates revealed in secondary organic aerosol formation from isoprene. Proc Natl Acad Sci USA 107:6640–6645CrossRef Surratt JD, Chan AWH, Eddingsaas NC, Chan MN, Loza CL, Kwan AJ, Hersey SP, Flagan RC, Wennberg PO, Seinfeld JH (2010) Reactive intermediates revealed in secondary organic aerosol formation from isoprene. Proc Natl Acad Sci USA 107:6640–6645CrossRef
36.
Zurück zum Zitat Szmigielski R, Surratt JD, Gómez-González Y, Van der Veken P, Kourtchev I, Vermeylen R, Blockhuys F, Jaoui M, Kleindienst TE, Lewandowski M, Offenberg JH, Edney EO, Seinfeld JH, Maenhaut W, Claeys M (2007) 3–methyl-1,2,3–butanetricarboxylic acid: an atmospheric tracer for terpene secondary organic aerosol. Geophys Res Lett 34:L24811. doi: 10.1029/2007GL031338 CrossRef Szmigielski R, Surratt JD, Gómez-González Y, Van der Veken P, Kourtchev I, Vermeylen R, Blockhuys F, Jaoui M, Kleindienst TE, Lewandowski M, Offenberg JH, Edney EO, Seinfeld JH, Maenhaut W, Claeys M (2007) 3–methyl-1,2,3–butanetricarboxylic acid: an atmospheric tracer for terpene secondary organic aerosol. Geophys Res Lett 34:L24811. doi: 10.1029/2007GL031338 CrossRef
37.
Zurück zum Zitat Vereecken L, Peeters J (2002) Enhanced H-atom abstraction from pinonaldehyde, pinonic acid, pinic acid, and related compounds: theoretical study of C–H bond strengths. Phys Chem Chem Phys 4:467–472CrossRef Vereecken L, Peeters J (2002) Enhanced H-atom abstraction from pinonaldehyde, pinonic acid, pinic acid, and related compounds: theoretical study of C–H bond strengths. Phys Chem Chem Phys 4:467–472CrossRef
38.
Zurück zum Zitat Yasmeen F, Vermeylen R, Szmigielski R, Iinuma Y, Böge O, Herrmann H, Maenhaut W, Claeys M (2010) Terpenylic acid and related compounds: precursors for dimers in secondary organic aerosol from the ozonolysis of α- and β-pinene. Atmos Chem Phys 10:9383–9392CrossRef Yasmeen F, Vermeylen R, Szmigielski R, Iinuma Y, Böge O, Herrmann H, Maenhaut W, Claeys M (2010) Terpenylic acid and related compounds: precursors for dimers in secondary organic aerosol from the ozonolysis of α- and β-pinene. Atmos Chem Phys 10:9383–9392CrossRef
39.
Zurück zum Zitat Yasmeen F, Szmigielski R, Vermeylen R, Gómez-González Y, Surratt JD, Chan AWH, Seinfeld JH, Maenhaut W, Claeys M (2011) Mass spectrometric characterization of isomeric terpenoic acids from the oxidation of α-pinene, β-pinene, d-limonene, and Δ3-carene in fine forest aerosol. J Mass Spectrom 46:425–442CrossRef Yasmeen F, Szmigielski R, Vermeylen R, Gómez-González Y, Surratt JD, Chan AWH, Seinfeld JH, Maenhaut W, Claeys M (2011) Mass spectrometric characterization of isomeric terpenoic acids from the oxidation of α-pinene, β-pinene, d-limonene, and Δ3-carene in fine forest aerosol. J Mass Spectrom 46:425–442CrossRef
40.
Zurück zum Zitat Yu JZ, Flagan RC, Seinfeld JH (1998) Identification of products containing –COOH, –OH, and –C=O in atmospheric oxidation of hydrocarbons. Environ Sci Technol 32:2357–2370CrossRef Yu JZ, Flagan RC, Seinfeld JH (1998) Identification of products containing –COOH, –OH, and –C=O in atmospheric oxidation of hydrocarbons. Environ Sci Technol 32:2357–2370CrossRef
41.
Zurück zum Zitat Yu JZ, Cocker DR III, Griffin RJ, Flagan RC, Seinfeld JH (1999) Gas-phase ozone oxidation of monoterpenes: gaseous and particulate products. J Atmos Chem 34:207–258CrossRef Yu JZ, Cocker DR III, Griffin RJ, Flagan RC, Seinfeld JH (1999) Gas-phase ozone oxidation of monoterpenes: gaseous and particulate products. J Atmos Chem 34:207–258CrossRef
42.
Zurück zum Zitat Zhang YY, Müller L, Winterhalter R, Moortgat GK, Hoffmann T, Pöschl U (2010) Seasonal cycle and temperature dependence of pinene oxidation products, dicarboxylic acids and nitrophenols in fine and coarse air particulate matter. Atmos Chem Phys 10:7859–7873CrossRef Zhang YY, Müller L, Winterhalter R, Moortgat GK, Hoffmann T, Pöschl U (2010) Seasonal cycle and temperature dependence of pinene oxidation products, dicarboxylic acids and nitrophenols in fine and coarse air particulate matter. Atmos Chem Phys 10:7859–7873CrossRef
Metadaten
Titel
Tracers for Biogenic Secondary Organic Aerosol from α-Pinene and Related Monoterpenes: An Overview
verfasst von
Magda Claeys
Rafal Szmigielski
Reinhilde Vermeylen
Wu Wang
Mohammad Safi Shalamzari
Willy Maenhaut
Copyright-Jahr
2013
Verlag
Springer Netherlands
DOI
https://doi.org/10.1007/978-94-007-5034-0_18