Skip to main content
Erschienen in: Clean Technologies and Environmental Policy 1/2015

01.01.2015 | Original Paper

True boiling point distillation and product quality assessment of biocrude obtained from Mesua ferrea L. seed oil via hydroprocessing

verfasst von: Mohammad Aslam, N. C. Kothiyal, A. K. Sarma

Erschienen in: Clean Technologies and Environmental Policy | Ausgabe 1/2015

Einloggen

Aktivieren Sie unsere intelligente Suche um passende Fachinhalte oder Patente zu finden.

search-config
loading …

Abstract

In this article, hydroprocessing of non-edible Mesua ferrea L. (MFL) seed oil has been described for the first time with a perspective for the production of liquid biofuels identical to petroleum products. MFL seed oil was hydroprocessed at the constant temperature of 400 °C under 7.5 MPa initial H2 pressure in a 2L capacity batch reactor for 4 h using 0.1 % Na2CO3 as catalyst. About 90 wt% biocrude could be obtained after hydroprocessing while the balance 7 % escapes as non-condensable gases and 2–3 % water at the bottom of the collecting flask. The resultant biocrude was characterized with regard to appropriate standards and distilled as per ASTM D2892 and ASTM D5236 using the TBP distillation unit. The distillate fractions obtained were characterized and it was found that the petroleum fraction within the boiling range of 35–140 °C was 15 wt%, kerosene and aviation fuel within the boiling range of 140–300 °C were 22 wt%, while the diesel fraction in the range of 300–370 °C was 14 wt%. About 11 wt% slightly yellowish coloured paraffin wax could also be recovered from the biocrude. Thus, the total recoverable distillates are 62 wt% of the original biocrude. The fuel properties of the different fractions were determined as per ASTM standard and were found to be in conformity to petroleum distillates. The economic analysis of the process and product unveil that the cost of biocrude and distillate is primarily dependent upon the cost of raw MFL seed oil. If the MFL can be availed @ INR 15/L then the prevailing costs of petroleum distillates and biocrude distillates have no difference at all.

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Literatur
Zurück zum Zitat Aatola H, Larmi M, Sarjovaara T, Mikkonen S (2008) Hydrotreated vegetable oil (HVO) as a renewable diesel fuel: trade-off between NOx, particulate emission, and fuel consumption of a heavy duty engine. SAE Technical Paper 2008-01-2500:12 Aatola H, Larmi M, Sarjovaara T, Mikkonen S (2008) Hydrotreated vegetable oil (HVO) as a renewable diesel fuel: trade-off between NOx, particulate emission, and fuel consumption of a heavy duty engine. SAE Technical Paper 2008-01-2500:12
Zurück zum Zitat Abbasi S, Diwekar Urmila M (2014) Characterization and stochastic modeling of uncertainties in the biodiesel production. Clean Technol Environ Policy 16:79–94CrossRef Abbasi S, Diwekar Urmila M (2014) Characterization and stochastic modeling of uncertainties in the biodiesel production. Clean Technol Environ Policy 16:79–94CrossRef
Zurück zum Zitat Bezergianni S, Dimitriadis A (2013) Temperature effect on co-hydroprocessing of heavy gas oil—waste cooking oil mixtures for hybrid diesel production. Fuel 103:579–584CrossRef Bezergianni S, Dimitriadis A (2013) Temperature effect on co-hydroprocessing of heavy gas oil—waste cooking oil mixtures for hybrid diesel production. Fuel 103:579–584CrossRef
Zurück zum Zitat Guzman A, Torres JE, Prada LP, Nunez ML (2010) Hydroprocessing of crude palm oil at pilot plant scale. Catal Today 156:38–43CrossRef Guzman A, Torres JE, Prada LP, Nunez ML (2010) Hydroprocessing of crude palm oil at pilot plant scale. Catal Today 156:38–43CrossRef
Zurück zum Zitat Hancsok J, Eller Z, Polczmann G, Varga Z, Hollo A, Varga G (2014) Sustainable production of bioparaffins in a crude oil refinery. Clean Technol Environ Policy. doi:10.1007/s10098-014-0743-6 Hancsok J, Eller Z, Polczmann G, Varga Z, Hollo A, Varga G (2014) Sustainable production of bioparaffins in a crude oil refinery. Clean Technol Environ Policy. doi:10.​1007/​s10098-014-0743-6
Zurück zum Zitat Kubatova A, Luo Y, Stavova J, Sadrameli SM, Aulich T, Kozliak E, Seames W (2011) New path in the thermal cracking of triacylglycerols (canola and soybean oil). Fuel 90(8):2598–2608CrossRef Kubatova A, Luo Y, Stavova J, Sadrameli SM, Aulich T, Kozliak E, Seames W (2011) New path in the thermal cracking of triacylglycerols (canola and soybean oil). Fuel 90(8):2598–2608CrossRef
Zurück zum Zitat Marousek J (2014) Novel technique to enhance the disintegration effect of the pressure waves on oilseeds. Ind Crops Prod 53:1–5CrossRef Marousek J (2014) Novel technique to enhance the disintegration effect of the pressure waves on oilseeds. Ind Crops Prod 53:1–5CrossRef
Zurück zum Zitat Marousek J, Itoh S, Higa O, Kondo Y, Ueno M, Suwa R, Tominaga J, Kawamitsu Y (2013) Enzymatic hydrolysis enhanced by pressure shockwaves opening new possibilities in Jatropha Curcas L. processing. J Chem Technol Biotechnol 88(9):1650–1653CrossRef Marousek J, Itoh S, Higa O, Kondo Y, Ueno M, Suwa R, Tominaga J, Kawamitsu Y (2013) Enzymatic hydrolysis enhanced by pressure shockwaves opening new possibilities in Jatropha Curcas L. processing. J Chem Technol Biotechnol 88(9):1650–1653CrossRef
Zurück zum Zitat No S-Y (2014) Application of hydrotreated vegetable oil from triglyceride based biomass to CI engines—A review. Fuel 115:88–96CrossRef No S-Y (2014) Application of hydrotreated vegetable oil from triglyceride based biomass to CI engines—A review. Fuel 115:88–96CrossRef
Zurück zum Zitat Onyestyak G, Harnos S, Szegedi A, Kallo D (2012) Sunflower oil to green diesel over Raney-type Ni-catalyst. Fuel 102:282–288CrossRef Onyestyak G, Harnos S, Szegedi A, Kallo D (2012) Sunflower oil to green diesel over Raney-type Ni-catalyst. Fuel 102:282–288CrossRef
Zurück zum Zitat Pinto F, Martins S, Gonçalves M, Costa P, Gulyurtlu I, Alves A, Mendes B (2013) Hydrogenation of rapeseed oil for production of liquid bio-chemicals. Appl Energy 102:272–282CrossRef Pinto F, Martins S, Gonçalves M, Costa P, Gulyurtlu I, Alves A, Mendes B (2013) Hydrogenation of rapeseed oil for production of liquid bio-chemicals. Appl Energy 102:272–282CrossRef
Zurück zum Zitat Rong L, Liu J, Fan K, Tian W, Liu C (2012) Hydroprocessing of Jatropha oil over NiMoCe/Al2O3 catalyst. Int J Hydrogen Energy 37(23):17731–17737CrossRef Rong L, Liu J, Fan K, Tian W, Liu C (2012) Hydroprocessing of Jatropha oil over NiMoCe/Al2O3 catalyst. Int J Hydrogen Energy 37(23):17731–17737CrossRef
Zurück zum Zitat Sarma AK, Konwer D (2005) Feasibility studies for conventional refinery distillation with a (1:1) w/w of a biocrude blend with petroleum crude oil. Energy Fuels 66(9):1755–1758CrossRef Sarma AK, Konwer D (2005) Feasibility studies for conventional refinery distillation with a (1:1) w/w of a biocrude blend with petroleum crude oil. Energy Fuels 66(9):1755–1758CrossRef
Zurück zum Zitat Satyarthi JK, Chiranjeevi T, Gokak DT, Viswanathan PS (2013) An overview of catalytic conversion of vegetable oils/fats into middle distillates. Catal Sci Technol 3:70–80CrossRef Satyarthi JK, Chiranjeevi T, Gokak DT, Viswanathan PS (2013) An overview of catalytic conversion of vegetable oils/fats into middle distillates. Catal Sci Technol 3:70–80CrossRef
Zurück zum Zitat Schneider RCS, Lara LRS, Ceolin MM, Kaercher JA, Schneider M (2013) Environmental impact of castor oil catalytic transfer hydrogenation. Clean Technol Environ Policy 15:977–985CrossRef Schneider RCS, Lara LRS, Ceolin MM, Kaercher JA, Schneider M (2013) Environmental impact of castor oil catalytic transfer hydrogenation. Clean Technol Environ Policy 15:977–985CrossRef
Zurück zum Zitat Sebos I, Matsoukas A, Apostolopoulos V, Papayannakos N (2009) Catalytic hydroprocessing of cottonseed oil in petroleum diesel mixtures for production of renewable diesel. Fuel 88(1):145–149CrossRef Sebos I, Matsoukas A, Apostolopoulos V, Papayannakos N (2009) Catalytic hydroprocessing of cottonseed oil in petroleum diesel mixtures for production of renewable diesel. Fuel 88(1):145–149CrossRef
Zurück zum Zitat Sharma RK, Anand M, Rana BS, Kumar R, Farooqui SA, Sibi MG, Sinha AK (2012) Jatropha-oil conversion to liquid hydrocarbon fuels using mesoporous titanosilicate supported sulfide catalysts. Catal Today 198(1):314–320CrossRef Sharma RK, Anand M, Rana BS, Kumar R, Farooqui SA, Sibi MG, Sinha AK (2012) Jatropha-oil conversion to liquid hydrocarbon fuels using mesoporous titanosilicate supported sulfide catalysts. Catal Today 198(1):314–320CrossRef
Zurück zum Zitat Simacek P, Kubicka D, Sebor G, Pospisil M (2010) Fuel properties of hydroprocessed rapeseed oil. Fuel 89(3):611–615CrossRef Simacek P, Kubicka D, Sebor G, Pospisil M (2010) Fuel properties of hydroprocessed rapeseed oil. Fuel 89(3):611–615CrossRef
Zurück zum Zitat Toth C, Baladincz P, Kovacs S, Hancsok J (2011) Producing clean diesel fuel by co-hydrogenation of vegetable oil with gas oil. Clean Technol Environ Policy 13:581–585CrossRef Toth C, Baladincz P, Kovacs S, Hancsok J (2011) Producing clean diesel fuel by co-hydrogenation of vegetable oil with gas oil. Clean Technol Environ Policy 13:581–585CrossRef
Zurück zum Zitat Veriansyah B, Han JY, Kim SK, Hong SA, Kim YJ, Lim JS, Kim J (2012) Production of renewable diesel by hydroprocessing of soybean oil: effect of catalysts. Fuel 94:578–585CrossRef Veriansyah B, Han JY, Kim SK, Hong SA, Kim YJ, Lim JS, Kim J (2012) Production of renewable diesel by hydroprocessing of soybean oil: effect of catalysts. Fuel 94:578–585CrossRef
Zurück zum Zitat Weber B, Stadlbauer E, Stengl S, Hossain M, Frank A, Steffens D, Schlich E, Schilling G (2012) Production of hydrocarbons from fatty acids and animal fat in the presence of water and sodium carbonate: reactor performance and fuel properties. Fuel 94:262–269CrossRef Weber B, Stadlbauer E, Stengl S, Hossain M, Frank A, Steffens D, Schlich E, Schilling G (2012) Production of hydrocarbons from fatty acids and animal fat in the presence of water and sodium carbonate: reactor performance and fuel properties. Fuel 94:262–269CrossRef
Metadaten
Titel
True boiling point distillation and product quality assessment of biocrude obtained from Mesua ferrea L. seed oil via hydroprocessing
verfasst von
Mohammad Aslam
N. C. Kothiyal
A. K. Sarma
Publikationsdatum
01.01.2015
Verlag
Springer Berlin Heidelberg
Erschienen in
Clean Technologies and Environmental Policy / Ausgabe 1/2015
Print ISSN: 1618-954X
Elektronische ISSN: 1618-9558
DOI
https://doi.org/10.1007/s10098-014-0774-z

Weitere Artikel der Ausgabe 1/2015

Clean Technologies and Environmental Policy 1/2015 Zur Ausgabe