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Journal of Coatings Technology and Research

Erschienen in:

10.07.2019

Tunable surface chemistry and wettability of octafluorocyclobutane and acrylic acid copolymer combined LDPE substrate by pulsed plasma polymerization

verfasst von: I. Muzammil, Y. P. Li, X. Y. Li, D. K. Dinh, M. Imran, H. Sattar, M. K. Lei

Erschienen in: Journal of Coatings Technology and Research | Ausgabe 3/2020

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Abstract

Octafluorocyclobutane and acrylic acid (C₄F₈-co-AA) are plasma copolymerized onto low-density polyethylene (LDPE) and glass slides under various pulsation periods of radio frequency pulsed plasma. The surface wettability of plasma polymer coating is traditionally considered as a substrate-independent property. The combined effect of ultrathin C₄F₈-co-AA coatings and LDPE substrate on surface wettability is presented. The high concentration of the carboxylic acid functional groups gives rise to hydrophilicity via lowering duty cycle, and substrate impact gives rise to hydrophobicity for ultrathin coatings. The X-ray photoelectron spectroscopy and coating thickness measurements confirmed that the sudden increase in water contact angle for the lower duty cycle is influenced by the hydrophobic substrate for ultrathin polymer coatings. It is highlighted that the precise control over the surface wettability is attained by tuning the plasma parameters. The substrate-dependent wettability for flat substrate persisted for longer than 8 weeks, which demonstrates wetting stability for ultrathin coatings.

Vorheriger Artikel Synthesis and application of silver nanoparticles as biocidal agent in polyurethane coating

Nächster Artikel Wetting metamorphosis of hydrophobic fluoropolymer coatings submerged in water and ultrasonically vibrated

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Titel: Tunable surface chemistry and wettability of octafluorocyclobutane and acrylic acid copolymer combined LDPE substrate by pulsed plasma polymerization
verfasst von: I. Muzammil
Y. P. Li
X. Y. Li
D. K. Dinh
M. Imran
H. Sattar
M. K. Lei
Publikationsdatum: 10.07.2019
Verlag: Springer US
Erschienen in: Journal of Coatings Technology and Research / Ausgabe 3/2020
Print ISSN: 1547-0091
Elektronische ISSN: 1935-3804
DOI: https://doi.org/10.1007/s11998-019-00244-z

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