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Cellulose

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10.03.2018 | Original Paper

Ultrasound-assisted conversion of cellulose into hydrogel and functional carbon material

verfasst von: Teck Wei Ching, Victoria Haritos, Akshat Tanksale

Erschienen in: Cellulose | Ausgabe 4/2018

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Abstract

Microcrystalline cellulose (MCC) was fibrillated using an ultrasound probe to produce a hydrogel, which after freeze-drying and carbonisation under N₂ atmosphere at elevated temperatures produced highly porous carbon. Ultrasound treatment in the absence of acid resulted in high aspect ratio, nanocrystalline cellulose due to fibrillation of the outer layers of the MCC fibre bundles, whereas in the presence of acid, cleavage of glycosidic bonds resulted in smaller aspect ratio fibres. Carbonisation of the acid-generated nanocrystalline cellulose samples at 800 °C provided the highest BET surface area of 917.0 m²/g, with over 18% pore volume in mesopores. The resulting high surface area carbon was able to absorb 100% of methylene blue in a solution having an initial concentration of 10 mg/L in 20 min which is comparable with many commercially available activated carbon products.

Graphical Abstract

Ultrasonication of microcrystalline cellulose resulted in nanocrystalline cellulose hydrogel which after freeze drying and carbonisation provided high surface area mesoporous carbon.

Vorheriger Artikel Preparation of cellulose-chitosan foams using an aqueous lithium bromide solution and their adsorption ability for Congo red

Nächster Artikel Potential of cellulose paper coated with silver nanoparticles: a benign option for emergency drinking water filter

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Altenor S, Carene B, Emmanuel E, Lambert J, Ehrhardt J-J, Gaspard S (2009) Adsorption studies of methylene blue and phenol onto vetiver roots activated carbon prepared by chemical activation. J Hazard Mater 165:1029–1039CrossRef

Basta A, Fierro V, El-Saied H, Celzard A (2009) 2-Steps KOH activation of rice straw: an efficient method for preparing high-performance activated carbons. Biores Technol 100:3941–3947CrossRef

Brinchi L, Cotana F, Fortunati E, Kenny J (2013) Production of nanocrystalline cellulose from lignocellulosic biomass: technology and applications. Carbohyd Polym 94:154–169CrossRef

Budarin V, Clark JH, Hardy JJ, Luque R, Milkowski K, Tavener SJ, Wilson AJ (2006) Starbons: new starch-derived mesoporous carbonaceous materials with tunable properties. Angew Chem 118:3866–3870CrossRef

Budarin VL, Clark JH, Luque R, Macquarrie DJ (2007) Versatile mesoporous carbonaceous materials for acid catalysis. Chem Commun 6:634–636CrossRef

Cazetta AL et al (2011) NaOH-activated carbon of high surface area produced from coconut shell: kinetics and equilibrium studies from the methylene blue adsorption. Chem Eng J 174:117–125CrossRef

Celzard A, Marêché J, Payot F (2000) Simple method for characterizing synthetic graphite powders. J Phys D Appl Phys 33:1556CrossRef

Chakraborty A, Sain M, Kortschot M (2005) Cellulose microfibrils: a novel method of preparation using high shear refining and cryocrushing. Holzforschung 59:102–107CrossRef

Chen W, Yu H, Liu Y, Chen P, Zhang M, Hai Y (2011) Individualization of cellulose nanofibers from wood using high-intensity ultrasonication combined with chemical pretreatments. Carbohyd Polym 83:1804–1811CrossRef

Chen A et al (2016) Synthesis of hollow mesoporous carbon spheres via “dissolution-capture” method for effective phenol adsorption. Carbon 103:157–162CrossRef

Cheng Q, Wang S, Rials TG (2009) Poly (vinyl alcohol) nanocomposites reinforced with cellulose fibrils isolated by high intensity ultrasonication. Compos A Appl Sci Manuf 40:218–224CrossRef

Cheng Q, Wang S, Han Q (2010) Novel process for isolating fibrils from cellulose fibers by high-intensity ultrasonication. II. Fibril characterization. J Appl Polym Sci 115:2756–2762CrossRef

Cho M-J, Park B-D (2011) Tensile and thermal properties of nanocellulose-reinforced poly (vinyl alcohol) nanocomposites. J Ind Eng Chem 17:36–40CrossRef

Ciardelli G, Corsi L, Marcucci M (2001) Membrane separation for wastewater reuse in the textile industry. Resour Conserv Recycl 31:189–197CrossRef

Cooper P (1993) Removing colour from dyehouse waste waters—a critical review of technology available. Color Technol 109:97–100

Dubinin M (1989) Fundamentals of the theory of adsorption in micropores of carbon adsorbents: characteristics of their adsorption properties and microporous structures. Carbon 27:457–467CrossRef

Fan J, Li Y (2012) Maximizing the yield of nanocrystalline cellulose from cotton pulp fiber. Carbohydr Polym 88:1184–1188CrossRef

Fung P, Sin K, Tsui S (2000) Decolorisation and degradation kinetics of reactive dye wastewater by a UV/ultrasonic/peroxide system. Color Technol 116:170–173CrossRef

Gatenholm P, Klemm D (2010) Bacterial nanocellulose as a renewable material for biomedical applications. MRS Bull 35:208–213CrossRef

González I, Boufi S, Pèlach MA, Alcalà M, Vilaseca F, Mutjé P (2012) Nanofibrillated cellulose as paper additive in eucalyptus pulps. BioResources 7:5167–5180CrossRef

Habibi Y, Lucia LA, Rojas OJ (2010) Cellulose nanocrystals: chemistry, self-assembly, and applications. Chem Rev 110:3479–3500CrossRef

Hameed B, Din AM, Ahmad A (2007) Adsorption of methylene blue onto bamboo-based activated carbon: kinetics and equilibrium studies. J Hazard Mater 141:819–825CrossRef

Henriksson M, Henriksson G, Berglund L, Lindström T (2007) An environmentally friendly method for enzyme-assisted preparation of microfibrillated cellulose (MFC) nanofibers. Eur Polymer J 43:3434–3441CrossRef

Henriksson M, Berglund LA, Isaksson P, Lindstrom T, Nishino T (2008) Cellulose nanopaper structures of high toughness. Biomacromol 9:1579–1585CrossRef

Hsu YC, Chen JT, Yang HC, Chen JH (2001) Decolorization of dyes using ozone in gas-induced a reactor. AIChE J 47:169–176CrossRef

Hu L et al (2013) Transparent and conductive paper from nanocellulose fibers. Energy Environ Sci 6:513–518CrossRef

Ishii D, Saito T, Isogai A (2011) Viscoelastic evaluation of average length of cellulose nanofibers prepared by TEMPO-mediated oxidation. Biomacromol 12:548–550CrossRef

Iwamoto S, Nakagaito AN, Yano H, Nogi M (2005) Optically transparent composites reinforced with plant fiber-based nanofibers. Appl Phys A 81:1109–1112CrossRef

Jia Z, Li Z, Li S, Li Y, Zhu R (2016) Adsorption performance and mechanism of methylene blue on chemically activated carbon spheres derived from hydrothermally-prepared poly (vinyl alcohol) microspheres. J Mol Liq 220:56–62CrossRef

Kadam AA, Lee DS (2015) Glutaraldehyde cross-linked magnetic chitosan nanocomposites: reduction precipitation synthesis, characterization, and application for removal of hazardous textile dyes. Biores Technol 193:563–567CrossRef

Kannan N, Sundaram MM (2001) Kinetics and mechanism of removal of methylene blue by adsorption on various carbons—a comparative study. Dyes Pigm 51:25–40CrossRef

Karagöz S, Tay T, Ucar S, Erdem M (2008) Activated carbons from waste biomass by sulfuric acid activation and their use on methylene blue adsorption. Biores Technol 99:6214–6222CrossRef

Kerekes R, Schell C (1992) Characterization of fibre flocculation regimes by a crowding factor. J Pulp Paper Sci 18:J32–J38

Kim S-j, Jang J (2013) Effect of degree of polymerization on the mechanical properties of regenerated cellulose fibers using synthesized 1-allyl-3-methylimidazolium chloride. Fibers Polym 14:909–914CrossRef

Kondo T, Kose R, Naito H, Kasai W (2014) Aqueous counter collision using paired water jets as a novel means of preparing bio-nanofibers. Carbohydr Polym 112:284–290CrossRef

Korhonen JT, Kettunen M, Ras RH, Ikkala O (2011) Hydrophobic nanocellulose aerogels as floating, sustainable, reusable, and recyclable oil absorbents. ACS Appl Mater Interfaces 3:1813–1816CrossRef

Kose R, Kondo T (2011) Favorable 3D-network formation of chitin nanofibers dispersed in water prepared using aqueous counter collision. Sen’i Gakkaishi 67:91–95CrossRef

Lan W, Liu C-F, Yue F-X, Sun R-C, Kennedy JF (2011) Ultrasound-assisted dissolution of cellulose in ionic liquid. Carbohydr Polym 86:672–677CrossRef

Lee S-Y, Chun S-J, Kang I-A, Park J-Y (2009) Preparation of cellulose nanofibrils by high-pressure homogenizer and cellulose-based composite films. J Ind Eng Chem 15:50–55CrossRef

Li J et al (2012a) Homogeneous isolation of nanocellulose from sugarcane bagasse by high pressure homogenization. Carbohyd Polym 90:1609–1613CrossRef

Li W, Yue J, Liu S (2012b) Preparation of nanocrystalline cellulose via ultrasound and its reinforcement capability for poly (vinyl alcohol) composites. Ultrason Sonochem 19:479–485CrossRef

Lücking F, Köser H, Jank M, Ritter A (1998) Iron powder, graphite and activated carbon as catalysts for the oxidation of 4-chlorophenol with hydrogen peroxide in aqueous solution. Water Res 32:2607–2614CrossRef

Mahadeva SK, Yi C, Kim J (2011) Electrical and electromechanical properties of 1-butyl-3-methylimidazolium bis (trifluoromethylsulfonyl) imide-blended cellulose. Ionics 17:41–47CrossRef

Malik PK (2004) Dye removal from wastewater using activated carbon developed from sawdust: adsorption equilibrium and kinetics. J Hazard Mater 113:81–88CrossRef

Martinez D et al (2001) Characterizing the mobility of papermaking fibres during sedimentation. In: The science of papermaking: transactions of the 12th fundamental research symposium, Oxford. The Pulp and Paper Fundamental Research Society, Bury, UK, pp 225–254

McCormick CL, Callais PA, Hutchinson BH Jr (1985) Solution studies of cellulose in lithium chloride and N,N-dimethylacetamide. Macromolecules 18:2394–2401CrossRef

Mckay G, Otterburn M, Sweeney A (1980) The removal of colour from effluent using various adsorbents—III. Silica: rate processes. Water Res 14:15–20CrossRef

McKee JR, Hietala S, Seitsonen J, Laine J, Kontturi E, Ikkala O (2014) Thermoresponsive nanocellulose hydrogels with tunable mechanical properties. ACS Macro Lett 3:266–270CrossRef

Mishra SP, Manent A-S, Chabot B, Daneault C (2011) Production of nanocellulose from native cellulose—various options utilizing ultrasound. BioResources 7:0422–0436

Nakagaito A, Yano H (2004) The effect of morphological changes from pulp fiber towards nano-scale fibrillated cellulose on the mechanical properties of high-strength plant fiber based composites. Appl Phys A 78:547–552CrossRef

Namasivayam C, Kavitha D (2002) Removal of Congo Red from water by adsorption onto activated carbon prepared from coir pith, an agricultural solid waste. Dyes Pigm 54:47–58CrossRef

Nguyen-Le M-T, Lee B-K (2015) High temperature synthesis of interfacial functionalized carboxylate mesoporous TiO₂ for effective adsorption of cationic dyes. Chem Eng J 281:20–33CrossRef

O’Neill C, Hawkes FR, Hawkes DL, Lourenço ND, Pinheiro HM, Delée W (1999) Colour in textile effluents—sources, measurement, discharge consents and simulation: a review. J Chem Technol Biotechnol 74:1009–1018CrossRef

Pappas C, Tarantilis P, Daliani I, Mavromoustakos T, Polissiou M (2002) Comparison of classical and ultrasound-assisted isolation procedures of cellulose from kenaf (Hibiscus cannabinus L.) and eucalyptus (Eucalyptus rodustrus Sm.). Ultrason Sonochem 9:19–23CrossRef

Pereira MFR, Soares SF, Órfão JJ, Figueiredo JL (2003) Adsorption of dyes on activated carbons: influence of surface chemical groups. Carbon 41:811–821CrossRef

Perkins WS, Walsh W, Reed I, Namboodri C (1996) A demonstration of reuse of spent dyebath water following color removal with ozone. Text Chem Colorist 28:31–37

Punzi M, Anbalagan A, Börner RA, Svensson B-M, Jonstrup M, Mattiasson B (2015) Degradation of a textile azo dye using biological treatment followed by photo-Fenton oxidation: evaluation of toxicity and microbial community structure. Chem Eng J 270:290–299CrossRef

Revol J, Dietrich A, Goring D (1987) Effect of mercerization on the crystallite size and crystallinity index in cellulose from different sources. Can J Chem 65:1724–1725CrossRef

Robinson T, Chandran B, Nigam P (2002) Removal of dyes from a synthetic textile dye effluent by biosorption on apple pomace and wheat straw. Water Res 36:2824–2830CrossRef

Sabio E, González E, González J, González-Garcıa C, Ramiro A, Ganan J (2004) Thermal regeneration of activated carbon saturated with p-nitrophenol. Carbon 42:2285–2293CrossRef

Saito T, Nishiyama Y, Putaux J-L, Vignon M, Isogai A (2006) Homogeneous suspensions of individualized microfibrils from TEMPO-catalyzed oxidation of native cellulose. Biomacromol 7:1687–1691CrossRef

Shrotri A, Lambert LK, Tanksale A, Beltramini J (2013) Mechanical depolymerisation of acidulated cellulose: understanding the solubility of high molecular weight oligomers. Green Chem 15:2761–2768CrossRef

Sing KS (1985) Reporting physisorption data for gas/solid systems with special reference to the determination of surface area and porosity (Recommendations 1984). Pure Appl Chem 57:603–619CrossRef

Siró I, Plackett D (2010) Microfibrillated cellulose and new nanocomposite materials: a review. Cellulose 17:459–494CrossRef

Spence KL, Venditti RA, Rojas OJ, Habibi Y, Pawlak JJ (2011) A comparative study of energy consumption and physical properties of microfibrillated cellulose produced by different processing methods. Cellulose 18:1097–1111. https://doi.org/10.1007/s10570-011-9533-z CrossRef

Suslick KS, Price GJ (1999) Applications of ultrasound to materials chemistry. Annu Rev Mater Sci 29:295–326CrossRef

Tang L, Huang B, Ou W, Chen X, Chen Y (2011) Manufacture of cellulose nanocrystals by cation exchange resin-catalyzed hydrolysis of cellulose. Biores Technol 102:10973–10977CrossRef

Tian C, Yi J, Wu Y, Wu Q, Qing Y, Wang L (2016) Preparation of highly charged cellulose nanofibrils using high-pressure homogenization coupled with strong acid hydrolysis pretreatments. Carbohydr Polym 136:485–492CrossRef

Tischer PCF, Sierakowski MR, Westfahl H Jr, Tischer CA (2010) Nanostructural reorganization of bacterial cellulose by ultrasonic treatment. Biomacromol 11:1217–1224CrossRef

Uygur A, Kök E (1999) Decolorisation treatments of azo dye waste waters including dichlorotriazinyl reactive groups by using advanced oxidation method. Color Technol 115:350–354CrossRef

Valix M, Cheung W, McKay G (2004) Preparation of activated carbon using low temperature carbonisation and physical activation of high ash raw bagasse for acid dye adsorption. Chemosphere 56:493–501CrossRef

Varanasi S, He R, Batchelor W (2013) Estimation of cellulose nanofibre aspect ratio from measurements of fibre suspension gel point. Cellulose 20:1885–1896CrossRef

White RJ, Budarin V, Luque R, Clark JH, Macquarrie DJ (2009) Tuneable porous carbonaceous materials from renewable resources. Chem Soc Rev 38:3401–3418CrossRef

Wu F-C, Tseng R-L (2008) High adsorption capacity NaOH-activated carbon for dye removal from aqueous solution. J Hazard Mater 152:1256–1267CrossRef

Xie X, Goodell B, Zhang D, Nagle DC, Qian Y, Peterson ML, Jellison J (2009) Characterization of carbons derived from cellulose and lignin and their oxidative behavior. Biores Technol 100:1797–1802CrossRef

Xiong R, Zhang X, Tian D, Zhou Z, Lu C (2012) Comparing microcrystalline with spherical nanocrystalline cellulose from waste cotton fabrics. Cellulose 19:1189–1198CrossRef

Rodriguez Correa C, Stollovsky M, Hehr T, Rauscher Y, Rolli B, Kruse A (2017) Influence of the carbonization process on activated carbon properties from lignin and lignin-rich biomasses. ACS Sustain Chem Eng 5:8222–8233CrossRef

Zander NE, Dong H, Steele J, Grant JT (2014) Metal cation cross-linked nanocellulose hydrogels as tissue engineering substrates. ACS Appl Mater Interfaces 6:18502–18510CrossRef

Zhang L, Batchelor W, Varanasi S, Tsuzuki T, Wang X (2012) Effect of cellulose nanofiber dimensions on sheet forming through filtration. Cellulose 19:561–574CrossRef

Zhang Q, Benoit M, Vigier KDO, Barrault J, Jégou G, Philippe M, Jérôme F (2013) Pretreatment of microcrystalline cellulose by ultrasounds: effect of particle size in the heterogeneously-catalyzed hydrolysis of cellulose to glucose. Green Chem 15:963–969CrossRef

Titel: Ultrasound-assisted conversion of cellulose into hydrogel and functional carbon material
verfasst von: Teck Wei Ching
Victoria Haritos
Akshat Tanksale
Publikationsdatum: 10.03.2018
Verlag: Springer Netherlands
Erschienen in: Cellulose / Ausgabe 4/2018
Print ISSN: 0969-0239
Elektronische ISSN: 1572-882X
DOI: https://doi.org/10.1007/s10570-018-1746-y

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