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Journal of Nanoparticle Research

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01.06.2020 | Research paper

Ultrathin dense double-walled carbon nanotube membrane for enhanced lithium-sulfur batteries

verfasst von: Zhouting Sun, Chong Xie, Zhaoyang Fan, Fei Shen, Yuting Yin, Chunming Niu, Xiaogang Han

Erschienen in: Journal of Nanoparticle Research | Ausgabe 6/2020

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Abstract

Lithium-sulfur (Li-S) batteries are considered as next-generation technology for energy storage due to their high energy density. However, the rapid capacity fading resulted from the shuttle effect obstructs their practical application. Herein, ultrathin dense double-walled carbon nanotube (DWCNT) membrane has been designed to impede the shuttle effect. The outer wall of DWCNT helps to keep the integrity and conductivity for its inner wall. The defects on DWCNT are less than those on multi-walled CNT (MWCNT), which helps DWNCT to stack and form dense membrane. The tiny areal density of 0.00477 mg cm⁻² of DWCNT membrane would not weaken the Li-S battery’s energy density too much. The electrochemical tests suggested that the DWCNT membrane improved the cycling performance effectively. A possible reason was discussed. The cathode electrolyte interphase (CEI) grown on the DWCNTs made the membrane further dense, which promoted the blocking effect on polysulfides.

Vorheriger Artikel Comparative cytotoxic effect of citrate-capped gold nanoparticles with different sizes on noncancerous and cancerous cell lines

Nächster Artikel Controlled synthesis of reduced graphene oxide-carbon nanotube hybrids and their aqueous behavior

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Titel: Ultrathin dense double-walled carbon nanotube membrane for enhanced lithium-sulfur batteries
verfasst von: Zhouting Sun
Chong Xie
Zhaoyang Fan
Fei Shen
Yuting Yin
Chunming Niu
Xiaogang Han
Publikationsdatum: 01.06.2020
Verlag: Springer Netherlands
Erschienen in: Journal of Nanoparticle Research / Ausgabe 6/2020
Print ISSN: 1388-0764
Elektronische ISSN: 1572-896X
DOI: https://doi.org/10.1007/s11051-020-04895-7

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