Skip to main content
Erschienen in: Journal of Sol-Gel Science and Technology 3/2012

01.12.2012 | Original Paper

Upconversion luminescence of Er3+/Yb3+ co-doped nanolangasite synthesized by a modified Pechini route

verfasst von: Ana-Maria Voiculescu, Serban Georgescu, Silviu Nastase, Cristian Matei, Daniela Berger, Cristina Matei, Angela Stefan, Octavian Toma

Erschienen in: Journal of Sol-Gel Science and Technology | Ausgabe 3/2012

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config
loading …

Abstract

Nanopowders of langasite (La3Ga5SiO14) doped with 1 at.% Er3+ and 3 at.% Yb3+ were synthesized for the first time by a modified Pechini route and annealed in air at 700, 750, 800, 900, and 1,000 °C. The langasite powders were characterized by XRD, FTIR and luminescence techniques. Crystallization began at 750 °C and pure langasite phase was obtained for the samples annealed at 800 and 900 °C. Traces of LaGaO3 and Ga2O3 were observed in the sample annealed at 1,000 °C. Bright green and red luminescence was observed for pumping at 973 nm whose intensity increased with annealing temperature due to the removal of the adsorbed impurities and the improvement of crystallinity.

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Literatur
1.
Zurück zum Zitat Kaminskii AA, Silvestrova IM, Sarkisov SE, Denisenko GA (1983) Investigation of trigonal (La1−x Ndx)3Ga5SiO14 crystals. II. spectral laser and electrochemical properties. Phys Stat Sol (a) 80:607–620CrossRef Kaminskii AA, Silvestrova IM, Sarkisov SE, Denisenko GA (1983) Investigation of trigonal (La1−x Ndx)3Ga5SiO14 crystals. II. spectral laser and electrochemical properties. Phys Stat Sol (a) 80:607–620CrossRef
2.
Zurück zum Zitat Ryba-Romanowski Dominiak-Dzik WG, Solarz P, Berkowski M (2003) Optical study of erbium-doped La3Ga5.5Ta0.5O14 single crystal. Mol Phys 101:1067–1072CrossRef Ryba-Romanowski Dominiak-Dzik WG, Solarz P, Berkowski M (2003) Optical study of erbium-doped La3Ga5.5Ta0.5O14 single crystal. Mol Phys 101:1067–1072CrossRef
3.
Zurück zum Zitat Burkov VI, Lysenko OA, Mill BV (2010) Absorption and circular dichroism spectra of La3Ga5SiO14 crystals doped with Pr3+, Ho3+, and Er3+ ions. Crystallogr Rep 55:983–989CrossRef Burkov VI, Lysenko OA, Mill BV (2010) Absorption and circular dichroism spectra of La3Ga5SiO14 crystals doped with Pr3+, Ho3+, and Er3+ ions. Crystallogr Rep 55:983–989CrossRef
4.
Zurück zum Zitat Kaminskii AA, Butashin AV, Demidovich AA, Koptev VG, Mill BV, Shkadarevich AP (1989) Broad-band tunable stimulated emission from octahedral Cr3+ ions in new acentric crystals with Ca-gallogermanate structure. Phys Stat Sol (a) 112:197–206CrossRef Kaminskii AA, Butashin AV, Demidovich AA, Koptev VG, Mill BV, Shkadarevich AP (1989) Broad-band tunable stimulated emission from octahedral Cr3+ ions in new acentric crystals with Ca-gallogermanate structure. Phys Stat Sol (a) 112:197–206CrossRef
5.
Zurück zum Zitat Voda M, García Solé J, Jaque F, Vergara I, Kaminskii A, Mill B, Butashin A (1994) Fano antiresonances in the optical-absorption spectra of Cr3+-doped La3Ga5.5Nb0.5O14 and La3Ga5.5Ta0.5O14 crystals. Phys Rev B 49:3755–3759CrossRef Voda M, García Solé J, Jaque F, Vergara I, Kaminskii A, Mill B, Butashin A (1994) Fano antiresonances in the optical-absorption spectra of Cr3+-doped La3Ga5.5Nb0.5O14 and La3Ga5.5Ta0.5O14 crystals. Phys Rev B 49:3755–3759CrossRef
6.
Zurück zum Zitat Casalboni M, Luci A, Grassano UM, Mill BV, Kaminskii AA (1994) Optical spectroscopy of La3Ga5SiO14: Cr3+ crystals. Phys Rev B 49:3781–3790CrossRef Casalboni M, Luci A, Grassano UM, Mill BV, Kaminskii AA (1994) Optical spectroscopy of La3Ga5SiO14: Cr3+ crystals. Phys Rev B 49:3781–3790CrossRef
7.
Zurück zum Zitat Georgescu S, Toma O, Chinie AM, Gheorghe L, Achim A, Stefan AS (2008) Excited state dynamics of Eu3+ in the partially disordered crystals La3Ga5SiO14 and La3Ga5.5Ta0.5O14. J Luminescence 128:741–743CrossRef Georgescu S, Toma O, Chinie AM, Gheorghe L, Achim A, Stefan AS (2008) Excited state dynamics of Eu3+ in the partially disordered crystals La3Ga5SiO14 and La3Ga5.5Ta0.5O14. J Luminescence 128:741–743CrossRef
8.
Zurück zum Zitat Georgescu S, Voiculescu AM, Toma O, Nastase S, Matei C, Osiac M (2010) Luminescence of Eu-doped langanite nanopowders synthesized by a citrate sol–gel method. J Alloys Compd 507:470–474CrossRef Georgescu S, Voiculescu AM, Toma O, Nastase S, Matei C, Osiac M (2010) Luminescence of Eu-doped langanite nanopowders synthesized by a citrate sol–gel method. J Alloys Compd 507:470–474CrossRef
9.
Zurück zum Zitat Kaminskii AA, Sarkisov SE, Mill BV, Khodzhabagyan GG (1982) Sov Phys Dokl 27:403–405 Kaminskii AA, Sarkisov SE, Mill BV, Khodzhabagyan GG (1982) Sov Phys Dokl 27:403–405
10.
Zurück zum Zitat Bohm J, Heimann RB, Hengst M, Roewer R, Schindler J (1999) Czochralski growth and characterization of piezoelectric single crystals with langasite structure: La3Ga5SiO14 (LGS), La3Ga5.5Nb0.5O14 (LGN), and La3Ga5.5Ta0.5O14 (LGT). Part I J Crystal Growth 204:128–136CrossRef Bohm J, Heimann RB, Hengst M, Roewer R, Schindler J (1999) Czochralski growth and characterization of piezoelectric single crystals with langasite structure: La3Ga5SiO14 (LGS), La3Ga5.5Nb0.5O14 (LGN), and La3Ga5.5Ta0.5O14 (LGT). Part I J Crystal Growth 204:128–136CrossRef
11.
Zurück zum Zitat Jung IH, Auh KH (1999) Crystal growth and piezoelectric properties of langasite (La3Ga5SiO14) crystals. Mater Lett 41:241–246CrossRef Jung IH, Auh KH (1999) Crystal growth and piezoelectric properties of langasite (La3Ga5SiO14) crystals. Mater Lett 41:241–246CrossRef
12.
Zurück zum Zitat Gheorghe L, Georgescu S, Constantinescu S, Mateescu I, Diamandescu L, Dumitrache L, Borca E (2002) Synthesis, growth and characterisation of langasite crystals. In: IEEE Ultrasonics symposium Proceedings, vols. 1 and 2, Book Series: Ultrasonics symposium, pp 965–968 Gheorghe L, Georgescu S, Constantinescu S, Mateescu I, Diamandescu L, Dumitrache L, Borca E (2002) Synthesis, growth and characterisation of langasite crystals. In: IEEE Ultrasonics symposium Proceedings, vols. 1 and 2, Book Series: Ultrasonics symposium, pp 965–968
13.
Zurück zum Zitat Uda S, Wang SQ, Konoshi N, Inaba H, Harada J (2002) Growth habits of 3 and 4-inch langasite singlecrystals. J Crystal Growth 237:707–713CrossRef Uda S, Wang SQ, Konoshi N, Inaba H, Harada J (2002) Growth habits of 3 and 4-inch langasite singlecrystals. J Crystal Growth 237:707–713CrossRef
14.
Zurück zum Zitat Uda S, Inaba H, Harada J, Hoshikawa K (2004) Growth of langasite via Bridgman technique along [0001], \( [2\bar{1}\bar{1}0] \) and \( [01\bar{1}1] \) for piezoelectric applications. J Crystal Growth 271: 229–237 Uda S, Inaba H, Harada J, Hoshikawa K (2004) Growth of langasite via Bridgman technique along [0001], \( [2\bar{1}\bar{1}0] \) and \( [01\bar{1}1] \) for piezoelectric applications. J Crystal Growth 271: 229–237
15.
Zurück zum Zitat Taishi T, Hayashi T, Bamba N, Ohno Y, Yonenaga I, Hoshikawa K (2007) Oxygen defects in langasite (La3Ga5SiO14) single crystal grown by vertical bridgman (VB) method. Phys B 401:437–440CrossRef Taishi T, Hayashi T, Bamba N, Ohno Y, Yonenaga I, Hoshikawa K (2007) Oxygen defects in langasite (La3Ga5SiO14) single crystal grown by vertical bridgman (VB) method. Phys B 401:437–440CrossRef
16.
Zurück zum Zitat Klemenz C (2002) High-quality langasite films grown by liquid phase epitaxy. J Crystal Growth 237:714–719CrossRef Klemenz C (2002) High-quality langasite films grown by liquid phase epitaxy. J Crystal Growth 237:714–719CrossRef
17.
Zurück zum Zitat Zhang X, Yuan D, Guo S (2007) Sol–gel preparation of a new compound with Ca3Ga2Ge4O14 structure: La3Al5.5Ta0.5O14. J Crystal Growth 308:80–83CrossRef Zhang X, Yuan D, Guo S (2007) Sol–gel preparation of a new compound with Ca3Ga2Ge4O14 structure: La3Al5.5Ta0.5O14. J Crystal Growth 308:80–83CrossRef
18.
Zurück zum Zitat Zhang X, Yuan DR, Yu FP, Duan XL, Shi XZ, Guo SY (2007) Synthesis of a novel langanite-type compound La3Al5.5Nb0.5O14 by the sol–gel process. Mater Lett 61:5150–5152CrossRef Zhang X, Yuan DR, Yu FP, Duan XL, Shi XZ, Guo SY (2007) Synthesis of a novel langanite-type compound La3Al5.5Nb0.5O14 by the sol–gel process. Mater Lett 61:5150–5152CrossRef
19.
Zurück zum Zitat Yu FP, Yuan DR, Kong LM, Duan XL, Guo SY, Wang XQ, Zhao X (2008) Fluorescence properties of Dy3+ doped La3Ga5.5Nb0.5O14 nanocrystals. Nanotechnology 19:045705CrossRef Yu FP, Yuan DR, Kong LM, Duan XL, Guo SY, Wang XQ, Zhao X (2008) Fluorescence properties of Dy3+ doped La3Ga5.5Nb0.5O14 nanocrystals. Nanotechnology 19:045705CrossRef
20.
Zurück zum Zitat Yu FP, Yuan DR, Kong LM, Duan XL, Guo SY, Wang XQ, Zhao X (2008) Effects of Er3+ doping concentration and calcination on fluorescence properties of La3Ga5.5Nb0.5O14 nanocrystals. Cryst Res Technol 43:522–525CrossRef Yu FP, Yuan DR, Kong LM, Duan XL, Guo SY, Wang XQ, Zhao X (2008) Effects of Er3+ doping concentration and calcination on fluorescence properties of La3Ga5.5Nb0.5O14 nanocrystals. Cryst Res Technol 43:522–525CrossRef
21.
Zurück zum Zitat Yu FP, Yuan DR, Zhao X, Guo SY, Duan XL, Kong LM, Wang XQ (2008) Effects of Eu3+ doping concentration and sintering temperature on fluorescence properties of La3Ga5.5Nb0.5O14 nanoparticles. J Crystal Growth 310:3256–3259CrossRef Yu FP, Yuan DR, Zhao X, Guo SY, Duan XL, Kong LM, Wang XQ (2008) Effects of Eu3+ doping concentration and sintering temperature on fluorescence properties of La3Ga5.5Nb0.5O14 nanoparticles. J Crystal Growth 310:3256–3259CrossRef
22.
Zurück zum Zitat Voiculescu AM, Georgescu S, Toma O, Nastase S, Birjega R, Petrescu L, Enculescu I, Matei E (2011) Upconversion luminescence of Er, Yb—doped nanolanganite powders synthesized by a citrate sol–gel method. Optoelectron Adv Mater-Rapid Commun 5:1170–1173 Voiculescu AM, Georgescu S, Toma O, Nastase S, Birjega R, Petrescu L, Enculescu I, Matei E (2011) Upconversion luminescence of Er, Yb—doped nanolanganite powders synthesized by a citrate sol–gel method. Optoelectron Adv Mater-Rapid Commun 5:1170–1173
23.
24.
Zurück zum Zitat Hu Y, Wang FW, Lin HL (2008) Photoluminescence of langasite thin films prepared from sol–gel process. Mater Chem Phys 107:82–84CrossRef Hu Y, Wang FW, Lin HL (2008) Photoluminescence of langasite thin films prepared from sol–gel process. Mater Chem Phys 107:82–84CrossRef
25.
Zurück zum Zitat Socrates G (2001) Infrared and Raman characteristic group frequencies. Wiley, Chichester Socrates G (2001) Infrared and Raman characteristic group frequencies. Wiley, Chichester
26.
Zurück zum Zitat Jinga C, Berger D, Matei C, Jinga S, Andronescu E (2010) Characterization of BaMg1/3(Ta1-xNbx)2/3O3 ceramics obtained by a modified Pechini method. J Alloys Compd 497:239–243CrossRef Jinga C, Berger D, Matei C, Jinga S, Andronescu E (2010) Characterization of BaMg1/3(Ta1-xNbx)2/3O3 ceramics obtained by a modified Pechini method. J Alloys Compd 497:239–243CrossRef
27.
Zurück zum Zitat Ouzaouit K, Benlhachemi A, Villain S, Essoumhi A, Benyaich H, Gavarri JR (2008) New method for preparation of polycrystalline langasite for gas sensors: structural studies. NATO science for peace and security series B—physics and biophysics, pp 191–203 Ouzaouit K, Benlhachemi A, Villain S, Essoumhi A, Benyaich H, Gavarri JR (2008) New method for preparation of polycrystalline langasite for gas sensors: structural studies. NATO science for peace and security series B—physics and biophysics, pp 191–203
28.
Zurück zum Zitat Georgescu S, Toma O, Voiculescu AM, Matei C, Birjega R, Petrescu L (2012) Infrared-excited bright green and red luminescence in La3Ga5.5Ta0.5O14 doped with erbium and ytterbium. Phys B 407:1124–1127CrossRef Georgescu S, Toma O, Voiculescu AM, Matei C, Birjega R, Petrescu L (2012) Infrared-excited bright green and red luminescence in La3Ga5.5Ta0.5O14 doped with erbium and ytterbium. Phys B 407:1124–1127CrossRef
29.
Zurück zum Zitat Wang Y, Ohwaki J (1993) New transparent vitroceramics codoped with Er3+ and Yb3+ for efficient frequency upconversion. Appl Phys Lett 63:3268–3270CrossRef Wang Y, Ohwaki J (1993) New transparent vitroceramics codoped with Er3+ and Yb3+ for efficient frequency upconversion. Appl Phys Lett 63:3268–3270CrossRef
30.
Zurück zum Zitat Lu GW, Li CX, Wang WC, Wang ZH, Wang ZM, Yuan DR, Xia HR (2004) Raman scattering spectra of La3Ga5SiO14 (LGS) crystals. Phys Stat Sol (b) 241:439–446CrossRef Lu GW, Li CX, Wang WC, Wang ZH, Wang ZM, Yuan DR, Xia HR (2004) Raman scattering spectra of La3Ga5SiO14 (LGS) crystals. Phys Stat Sol (b) 241:439–446CrossRef
Metadaten
Titel
Upconversion luminescence of Er3+/Yb3+ co-doped nanolangasite synthesized by a modified Pechini route
verfasst von
Ana-Maria Voiculescu
Serban Georgescu
Silviu Nastase
Cristian Matei
Daniela Berger
Cristina Matei
Angela Stefan
Octavian Toma
Publikationsdatum
01.12.2012
Verlag
Springer US
Erschienen in
Journal of Sol-Gel Science and Technology / Ausgabe 3/2012
Print ISSN: 0928-0707
Elektronische ISSN: 1573-4846
DOI
https://doi.org/10.1007/s10971-012-2900-x

Weitere Artikel der Ausgabe 3/2012

Journal of Sol-Gel Science and Technology 3/2012 Zur Ausgabe

    Marktübersichten

    Die im Laufe eines Jahres in der „adhäsion“ veröffentlichten Marktübersichten helfen Anwendern verschiedenster Branchen, sich einen gezielten Überblick über Lieferantenangebote zu verschaffen.