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Cellulose

Erschienen in:

01.02.2008

Upgrading of paper-grade pulps to dissolving pulps by nitren extraction: properties of nitren extracted xylans in comparison to NaOH and KOH extracted xylans

verfasst von: Ron Janzon, Bodo Saake, Jürgen Puls

Erschienen in: Cellulose | Ausgabe 1/2008

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Abstract

Different paper-grade pulps were extracted with nitren, NaOH and KOH in order to produce dissolving pulps and polymeric xylan. The yield and structure of the isolated nitren and alkali xylans were investigated by carbohydrate analysis, HPSEC and ¹H-NMR spectroscopy. In addition the effect of washing stages on the residual nickel content of the nitren xylans was investigated. By nitren extraction up to 98% of the xylan could be extracted out of the fully bleached eucalyptus and birch kraft pulps. The nitren extracted kraft xylans had DP values between 95 (birch) and 111 (eucalyptus). At most 5 mol% of the xylose units were substituted. In the case of pulps with low mannan content only marginally differences between the nitren and alkaline (KOH, NaOH) extractions occurred. The extraction of the relatively “mannnan rich” pulps of this study like softwood kraft and beech sulfite pulps revealed that the dissolution effect regarding mannans increased in the following order: nitren < KOH < NaOH. In general the nitren extractions required a lower chemical charge compared to the alkaline extractions, in order to yield similar amounts of xylans. On the other side the necessity of an effective nickel removal is a disadvantage of the nitren extractions.

Vorheriger Artikel Extraction of cellulose and preparation of nanocellulose from sisal fibers

Nächster Artikel Optimization of cellouronic acid synthesis by TEMPO-mediated oxidation of cellulose III from sugar beet pulp

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Titel: Upgrading of paper-grade pulps to dissolving pulps by nitren extraction: properties of nitren extracted xylans in comparison to NaOH and KOH extracted xylans
verfasst von: Ron Janzon
Bodo Saake
Jürgen Puls
Publikationsdatum: 01.02.2008
Verlag: Springer Netherlands
Erschienen in: Cellulose / Ausgabe 1/2008
Print ISSN: 0969-0239
Elektronische ISSN: 1572-882X
DOI: https://doi.org/10.1007/s10570-007-9154-8

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