Skip to main content
Erschienen in:

08.10.2022

Use of Solid Slag Mixtures in a Ladle Furnace Unit

verfasst von: A. N. Zolin, A. A. Dobromilov, R. D. Esil’baev, R. K. Shafigulin, V. S. Gulyakov, A. S. Vusikhis

Erschienen in: Metallurgist | Ausgabe 5-6/2022

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config
loading …

Abstract

High quality steels have a low sulfur content. Steel is purified from sulfur by treating it with highly basic slags. Scarce fluorspar is used to provide slags with the required fluidity, which decomposes during smelting with the liberation of toxic fluorine into a workshop atmosphere. Alumina is also a thinner for highly basic slags, which is present in sufficient concentrations in aluminothermic production slags that are sent to landfill and create pressure on the environment. Slag dumps are “technogenic deposits” that can be a raw material base. In particular, industrial ferroalloy slags with a high alumina content may be used to prepare a thinning slag-forming mixture that can be used in steelmaking instead of scarce fluorspar. Preparation of a slag-forming mixture from waste slag will reduce the environmental pressure on slag dumps and their use as a slag thinner during steel refining in the working area of a steelmaking workshop by eliminating toxic fluorine emissions released during fluorspar decomposition. Replacement of scarce fluorspar with a slag-forming mixture in steelmaking will reduce steel cost by lowering aluminum consumption for slag deoxidation.

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Literatur
1.
Zurück zum Zitat K. Dzhandl, Kh. P. Nartst, P. Raizinger, P. Schastny, and Kh. Tsinneker, “Quality specifications during highly efficient steel production,” Chern. Met., No. 2, 65–73 (2006). K. Dzhandl, Kh. P. Nartst, P. Raizinger, P. Schastny, and Kh. Tsinneker, “Quality specifications during highly efficient steel production,” Chern. Met., No. 2, 65–73 (2006).
2.
Zurück zum Zitat E. Kh. Shakhpazov, A. I. Zaitsev, I. G. Rodionova, and G. V. Semernin, “Key directions of metallurgical technology development for providing an increase in steel quality requirement,” Élekrometallurgiya, No. 2, 2–12 (2011). E. Kh. Shakhpazov, A. I. Zaitsev, I. G. Rodionova, and G. V. Semernin, “Key directions of metallurgical technology development for providing an increase in steel quality requirement,” Élekrometallurgiya, No. 2, 2–12 (2011).
3.
Zurück zum Zitat D. A. Dyudkin, S. Yu. Bat’, S. E. Grinberg, and S. N. Marintsev, Steel Production in a Ladle-Furnace Unit [in Russian], OOO Yugo-vostok Ltd., Donetsk (2003). D. A. Dyudkin, S. Yu. Bat’, S. E. Grinberg, and S. N. Marintsev, Steel Production in a Ladle-Furnace Unit [in Russian], OOO Yugo-vostok Ltd., Donetsk (2003).
4.
Zurück zum Zitat D. Ya. Povolotskii, V. A. Kudrin, and A. F. Vishkarev, Steel Furnace Treatment [in Russian], MiSIS, Moscow (1995). D. Ya. Povolotskii, V. A. Kudrin, and A. F. Vishkarev, Steel Furnace Treatment [in Russian], MiSIS, Moscow (1995).
5.
Zurück zum Zitat V. A. Kudrin, Steel Production Theory and Technology [in Russian], Metallurgiya, Moscow (2003). V. A. Kudrin, Steel Production Theory and Technology [in Russian], Metallurgiya, Moscow (2003).
6.
Zurück zum Zitat Yang Jing-Bo, Yang Shu-Feng, Gao Xiang-Zhou, and Li Jing-she, “Sulfur control in ultra-low sulfur steel refined by ladle furnace-vacuum degassing,” J. Metallurgical and Mining Industry, No. 3, 24–28 (2013). Yang Jing-Bo, Yang Shu-Feng, Gao Xiang-Zhou, and Li Jing-she, “Sulfur control in ultra-low sulfur steel refined by ladle furnace-vacuum degassing,” J. Metallurgical and Mining Industry, No. 3, 24–28 (2013).
7.
Zurück zum Zitat Jiang Zhouhua, Zhang Heyan, Zhan Dong-ping, et al., “Determination of process parameters for refining of ultra-low sulfur steels in ladle furnace,” J. Northeast Univ. Natur. Sci., No. 10. 952–955 (2002). Jiang Zhouhua, Zhang Heyan, Zhan Dong-ping, et al., “Determination of process parameters for refining of ultra-low sulfur steels in ladle furnace,” J. Northeast Univ. Natur. Sci., No. 10. 952–955 (2002).
8.
Zurück zum Zitat S. I. Gubenko, V. V. Parusov, and I. V. Derevyanchenko, Nonmetallic Inclusions in Steel [in Russian], Art. Press, Dnepropetrovsk (2005). S. I. Gubenko, V. V. Parusov, and I. V. Derevyanchenko, Nonmetallic Inclusions in Steel [in Russian], Art. Press, Dnepropetrovsk (2005).
9.
Zurück zum Zitat A. B. Sychkov, “Nonmetallic inclusions during production of high-carbon steel,” Vestn. MGTU im G. I. Nosova, No. 4, 40–49 (2007). A. B. Sychkov, “Nonmetallic inclusions during production of high-carbon steel,” Vestn. MGTU im G. I. Nosova, No. 4, 40–49 (2007).
10.
Zurück zum Zitat D. G. Elanskii and G. N. Elanskii, “Review of work in the plenary meeting of 14th international steel smelters congress,” Stal’, No. s11, 21–29 (2016). D. G. Elanskii and G. N. Elanskii, “Review of work in the plenary meeting of 14th international steel smelters congress,” Stal’, No. s11, 21–29 (2016).
11.
Zurück zum Zitat A. A. Safronov et al., “Production of pipe continuously-cast billet without coarse nonmetallic inclusions,” Stal’, No. 6, 22–27 (2016). A. A. Safronov et al., “Production of pipe continuously-cast billet without coarse nonmetallic inclusions,” Stal’, No. 6, 22–27 (2016).
12.
Zurück zum Zitat S. V. Zhuravleva, Yu. S. Paniotov, and V. S. Mameshin, “Evaluation of metal desulfurization in an LFU by a bivariant mechanism,” Matll Lit. Ukrainy, No. 2(261), 8–11 (2015). S. V. Zhuravleva, Yu. S. Paniotov, and V. S. Mameshin, “Evaluation of metal desulfurization in an LFU by a bivariant mechanism,” Matll Lit. Ukrainy, No. 2(261), 8–11 (2015).
13.
Zurück zum Zitat É. V. Parusov, A. B. Sychkov, L. V. Sagura, and I. N. Chuiko, “Orovision of ultraloz sulfur content with steel extra-furnace treatment,” Nauch. Tr. Vinits. Nats. Tekn. Univ., No. 1, 12–17 (2017). É. V. Parusov, A. B. Sychkov, L. V. Sagura, and I. N. Chuiko, “Orovision of ultraloz sulfur content with steel extra-furnace treatment,” Nauch. Tr. Vinits. Nats. Tekn. Univ., No. 1, 12–17 (2017).
14.
Zurück zum Zitat Julio Aníbal Morales Pereiraa, Vinicius Cardoso da Rochaa, Ayumi Yoshioka, Wagner Viana Bielefeldt, and Antônio Cezar Faria Vilelaa, “Analysis of secondary refining slag parameters with focus on inclusion cleanliness,” J. Materials Research, 21, No. 5, 1–11 (2018). Julio Aníbal Morales Pereiraa, Vinicius Cardoso da Rochaa, Ayumi Yoshioka, Wagner Viana Bielefeldt, and Antônio Cezar Faria Vilelaa, “Analysis of secondary refining slag parameters with focus on inclusion cleanliness,” J. Materials Research, 21, No. 5, 1–11 (2018).
15.
Zurück zum Zitat M. I. Gasik, M. M. Gasik. A. P. Gorobets. O. I. Polyakov, Yu. S. Proidak, A. I. Panchenko, and A. S. Sal’nikov, “Analysis of the stability of oxide-fluoride melts during refining treatment by electrometallurgical processes,” Metall. Gorn. Prom., No. 5, 2–29 (2011). M. I. Gasik, M. M. Gasik. A. P. Gorobets. O. I. Polyakov, Yu. S. Proidak, A. I. Panchenko, and A. S. Sal’nikov, “Analysis of the stability of oxide-fluoride melts during refining treatment by electrometallurgical processes,” Metall. Gorn. Prom., No. 5, 2–29 (2011).
16.
Zurück zum Zitat L. I. Leont’ev, V. I. Ponomarev, and O. Yu. Sheshukov, “ Treatment and utilization of metallurgical production technogenic waste,” Ékol. Prom. Rossii, 20, No. 3, 24–27 (2016). L. I. Leont’ev, V. I. Ponomarev, and O. Yu. Sheshukov, “ Treatment and utilization of metallurgical production technogenic waste,” Ékol. Prom. Rossii, 20, No. 3, 24–27 (2016).
17.
Zurück zum Zitat E. Drakaliysky, Du Sichen, and S. Seetharaman, “An experimental study of sulfide capacities in the system Al2O3–CaO–SiO2,” The Canadian J. of Metallurgy and Materials Science, 36, No. 2, 115–120 (1997). E. Drakaliysky, Du Sichen, and S. Seetharaman, “An experimental study of sulfide capacities in the system Al2O3–CaO–SiO2,” The Canadian J. of Metallurgy and Materials Science, 36, No. 2, 115–120 (1997).
18.
Zurück zum Zitat M. A. T. Andersson, P. G. Jönsson, and M. Hallberg, “Optimization of ladle slag composition by application of sulphide capacity model,” Ironmaking & Steelmaking, 27, 286–293 (2000).CrossRef M. A. T. Andersson, P. G. Jönsson, and M. Hallberg, “Optimization of ladle slag composition by application of sulphide capacity model,” Ironmaking & Steelmaking, 27, 286–293 (2000).CrossRef
19.
Zurück zum Zitat V. A. Rovnushkin, S. A. Spirin, V. V. Kromm, Yu. P. Petrenko, E. V. Shekhovstov, and I. V. Kostenko, “Use of aluminothermal production ferroalloy slags and master alloy for steel extra-furnace treatment,” Électrometallurgiya, No. 4, 10–11 (2009). V. A. Rovnushkin, S. A. Spirin, V. V. Kromm, Yu. P. Petrenko, E. V. Shekhovstov, and I. V. Kostenko, “Use of aluminothermal production ferroalloy slags and master alloy for steel extra-furnace treatment,” Électrometallurgiya, No. 4, 10–11 (2009).
20.
Zurück zum Zitat B. Buľko, J. Kijac, and M. Domovec, “Optimization slag composition in ladle furnace considering to effective steel desulfurization,” Acta Metallurgica Slovaca, 15, No. 2, 93–99 (2009). B. Buľko, J. Kijac, and M. Domovec, “Optimization slag composition in ladle furnace considering to effective steel desulfurization,” Acta Metallurgica Slovaca, 15, No. 2, 93–99 (2009).
21.
Zurück zum Zitat N. M. Bobkova, Physical Chemistry of Refractory Nonmetallic and Silicate Materials [in Russian], Vyssh. Shkola, Minsk (2007). N. M. Bobkova, Physical Chemistry of Refractory Nonmetallic and Silicate Materials [in Russian], Vyssh. Shkola, Minsk (2007).
Metadaten
Titel
Use of Solid Slag Mixtures in a Ladle Furnace Unit
verfasst von
A. N. Zolin
A. A. Dobromilov
R. D. Esil’baev
R. K. Shafigulin
V. S. Gulyakov
A. S. Vusikhis
Publikationsdatum
08.10.2022
Verlag
Springer US
Erschienen in
Metallurgist / Ausgabe 5-6/2022
Print ISSN: 0026-0894
Elektronische ISSN: 1573-8892
DOI
https://doi.org/10.1007/s11015-022-01383-2

Weitere Artikel der Ausgabe 5-6/2022

Metallurgist 5-6/2022 Zur Ausgabe

    Marktübersichten

    Die im Laufe eines Jahres in der „adhäsion“ veröffentlichten Marktübersichten helfen Anwendern verschiedenster Branchen, sich einen gezielten Überblick über Lieferantenangebote zu verschaffen.