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Journal of Coatings Technology and Research

Erschienen in:

22.04.2019

UV-curable waterborne epoxy acrylate coating modified by monomethacryloyloxy-terminated fluorinated oligomer

verfasst von: Hongyi Shi, Weiqu Liu, Chunhua Liu, Sha He, Chi Jiang, Zhengfang Wang

Erschienen in: Journal of Coatings Technology and Research | Ausgabe 5/2019

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Abstract

Monomethacryloyloxy-terminated fluorinated oligomers (PPFOMA-GMA and PHFBMA-GMA) and methyl allyl alcohol polyoxyethylene ether-modified epoxy resin (HPEGEA) were successfully synthesized and used as reactive additives and emulsifier for epoxy acrylate, respectively. FTIR, ¹H NMR, and GPC were used to characterize the structures of PPFOMA-GMA, PHFBMA-GMA, and HPEGEA. The influence of the concentrations of PPFOMA-GMA and PHFBMA-GMA on the properties of waterborne epoxy acrylate (WEA) resin coatings was investigated. The surface energy of waterborne epoxy acrylate coating was decreased from 38.20 mN/m to 15.31 mN/m by adding just 0.21 wt% PPFOMA-GMA, indicating its high effectiveness in improving the hydrophobic properties of the surface. The surface compositions of the WEA resin coatings (with 0.85 wt% PPFOMA-GMA or 0.85 wt% PHFBMA-GMA) were characterized by XPS. The XPS results confirmed the quantitative enrichment of fluorine atoms on the surface. What is more, the physical properties of waterborne epoxy acrylate coatings prepared with different concentrations of fluorinated reactive additive, such as optical transmittance, adhesion (on glass, PET, and tinplate), pencil hardness, water absorption, and thermal properties, were also analyzed in detail. Hence, the waterborne epoxy acrylate coatings prepared with low concentrations of reactive additives were economical and have potential for large-scale industrial applications.

Vorheriger Artikel Influence of nano-silica and polyethylene wax on the scratch behavior of acrylic-based polyurethane coatings

Nächster Artikel Electrophoretically deposited graphene oxide–polymer bilayer coating on Cu-Ni alloy with enhanced corrosion resistance in simulated chloride environment

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Titel: UV-curable waterborne epoxy acrylate coating modified by monomethacryloyloxy-terminated fluorinated oligomer
verfasst von: Hongyi Shi
Weiqu Liu
Chunhua Liu
Sha He
Chi Jiang
Zhengfang Wang
Publikationsdatum: 22.04.2019
Verlag: Springer US
Erschienen in: Journal of Coatings Technology and Research / Ausgabe 5/2019
Print ISSN: 1547-0091
Elektronische ISSN: 1935-3804
DOI: https://doi.org/10.1007/s11998-019-00209-2

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