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Erschienen in: Polymer Bulletin 5/2018

19.07.2017 | Original Paper

Waterborne polyurethane/Fe3O4-synthetic talc composites: synthesis, characterization, and magnetic properties

verfasst von: Leonardo M. dos Santos, Rosane Ligabue, Angela Dumas, Christophe Le Roux, Pierre Micoud, Jean-François Meunier, François Martin, Marta Corvo, Pedro Almeida, Sandra Einloft

Erschienen in: Polymer Bulletin | Ausgabe 5/2018

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Abstract

Nano-Fe3O4-synthetic talc gel was used as filler in the synthesis of waterborne polyurethane/Fe3O4-synthetic talc nanocomposites. This filler presents numerous edges (Si–O and Mg–O) and OH groups easily forming hydrogen bonds and polar interaction with water conferring hydrophilic character, consequently improving filler dispersion within a water-based matrix. Yet, the use of waterborne polyurethane (WPU) as matrix must be highlighted due to its environmentally friendly characteristics and low toxicity compared to solvent-based product. Fe3O4-synthetic talc-nanofillers were well dispersed into the polyurethane matrix even at high filler content as supported by XRD and TEM analyses. NMR indicates the interaction of filler OH groups with the matrix. For all nanocomposites, one can see a typical ferromagnetic behavior below Curie temperature (about 120 K) and a superparamagnetic behavior above this temperature. The use of Fe3O4-synthetic talc for obtaining magnetic nanocomposites resulted in improved materials with superior mechanical properties compared to solvent-based nanocomposites.

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Metadaten
Titel
Waterborne polyurethane/Fe3O4-synthetic talc composites: synthesis, characterization, and magnetic properties
verfasst von
Leonardo M. dos Santos
Rosane Ligabue
Angela Dumas
Christophe Le Roux
Pierre Micoud
Jean-François Meunier
François Martin
Marta Corvo
Pedro Almeida
Sandra Einloft
Publikationsdatum
19.07.2017
Verlag
Springer Berlin Heidelberg
Erschienen in
Polymer Bulletin / Ausgabe 5/2018
Print ISSN: 0170-0839
Elektronische ISSN: 1436-2449
DOI
https://doi.org/10.1007/s00289-017-2133-9

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