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Journal of Materials Science: Materials in Electronics
Erschienen in: Journal of Materials Science: Materials in Electronics 6/2019

28.02.2019

Wide-range thermometry and up-conversion luminescence of Ca5(PO4)3F:Yb3+/Er3+ transparent glass ceramics

verfasst von: Xiangyu Liu, Yong Chen, Fei Shang, Guohua Chen, Jiwen Xu

Erschienen in: Journal of Materials Science: Materials in Electronics | Ausgabe 6/2019

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Abstract

Ca5(PO4)3F:Yb3+/Er3+ glass ceramics (GCs) were successfully manufactured via traditional controlled crystallization method. The structural, optical and up-conversion (UC) illuminant properties were systemically investigated by XRD, TEM, HRTEM, fluorescence spectra and luminescence lifetime measurements. The results show that Ca5(PO4)3F:Yb3+/Er3+ nanocrystals has been precipitated from the precursor glass matrix and the UC luminescence mechanism of PG and GC660 is two-photon process. The enhanced UC emission intensity and extended lifetime of Er3+ is observed in the GCs. Using the temperature dependent fluorescence intensity ratio (FIR) of thermally coupled emitting states (4S3/2, 2H11/2) as thermometric index, Ca5(PO4)3F:Yb3+/Er3+ GCs present wide temperature-sensing range (298–798 K) and high absolute sensitivity (51.9 × 10−4 K−1 at 600 K). This finding suggests that Ca5(PO4)3F:Yb3+/Er3+GC materials are promising in optical temperature measurement field.
Vorheriger Artikel Structure, morphology and magnetodielectric investigations of BaTi1−xFexO3−δ ceramics
Nächster Artikel Effects of Ca2+ substitution on microstructure and microwave dielectric properties of low loss Ba(Mg1/3Nb2/3)O3 perovskite ceramics

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Metadaten
Titel
Wide-range thermometry and up-conversion luminescence of Ca5(PO4)3F:Yb3+/Er3+ transparent glass ceramics
verfasst von
Xiangyu Liu
Yong Chen
Fei Shang
Guohua Chen
Jiwen Xu
Publikationsdatum
28.02.2019
Verlag
Springer US
Erschienen in
Journal of Materials Science: Materials in Electronics / Ausgabe 6/2019
Print ISSN: 0957-4522
Elektronische ISSN: 1573-482X
DOI
https://doi.org/10.1007/s10854-019-00865-5

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