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01.02.2014 | Original Paper

Xylan-type hemicelluloses supported terpyridine–palladium(II) complex as an efficient and recyclable catalyst for Suzuki–Miyaura reaction

verfasst von: Wei Chen, Linxin Zhong, Xinwen Peng, Jiehua Lin, Runcang Sun

Erschienen in: Cellulose | Ausgabe 1/2014

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Abstract

Xylan-type hemicelluloses supported terpyridine–palladium(II) as a novel biomass-supported catalyst was synthesized and characterized in terms of morphology, composition, and thermal stability. The nano-Pd catalyst was further explored for Suzuki–Miyaura reaction between arylboronic acid and aryl halide under aerobic condition, with a yield up to 98 %. In particular, the catalyst exhibited both high catalytic activity and stability for Suzuki–Miyaura reaction. Furthermore, the catalyst could be easily recovered by simple filtration and reused at least six times without significant loss of its catalytic activity. This work provides a novel and effective supported catalyst, and broadens the applications of polysaccharides in green catalysis.

Vorheriger Artikel Adsorption of four non-ionic cellulose derivatives on cellulose model surfaces

Nächster Artikel A morphological interpretation of water chemical exchange and mobility in cellulose materials derived from proton NMR T2 relaxation

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Titel: Xylan-type hemicelluloses supported terpyridine–palladium(II) complex as an efficient and recyclable catalyst for Suzuki–Miyaura reaction
verfasst von: Wei Chen
Linxin Zhong
Xinwen Peng
Jiehua Lin
Runcang Sun
Publikationsdatum: 01.02.2014
Verlag: Springer Netherlands
Erschienen in: Cellulose / Ausgabe 1/2014
Print ISSN: 0969-0239
Elektronische ISSN: 1572-882X
DOI: https://doi.org/10.1007/s10570-013-0092-3

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