Skip to main content
Fachgebiete
Automobil + Motoren Bauwesen + Immobilien Business IT + Informatik Elektrotechnik + Elektronik Energie + Nachhaltigkeit Finance + Banking Management + Führung Marketing + Vertrieb Maschinenbau + Werkstoffe Versicherung + Risiko
DE
EN
Bücher
Zeitschriften
Themenseiten
Organisationspsychologie Projektmanagement Marketing Smart Manufacturing
Weitere Formate
Podcasts Webinare Technik Webinare Wirtschaft Kongresse Veranstaltungskalender Awards
Jetzt Einzelzugang starten
Zugang für Unternehmen
Referenzkunden
SLX-Digitalkonferenz: Zukunftswerkstatt 2024

Mehr Umsatz mit Top-Kontakten

Am 7. Mai erfahren Sie, wie Vertriebsteams Leadgenerierung, Leadnurturing und Leadstrategien effizient steuern können.
Erweiterte Suche
Anmelden
nach oben
Journal of Materials Science: Materials in Electronics
Erschienen in: Journal of Materials Science: Materials in Electronics 17/2020

24.07.2020

Z-Scheme mechanism study of ternary BiPO4/reduced graphene oxide/protonated g-C3N4 photocatalyst with interfacial electric field mediating for the effective photocatalytic degradation of tetracycline

verfasst von: Ya-Mu Xia, Shan-Peng Chu, Zi-Yang Liao, Shu-Yu Sun, Xu Cheng, Wei-Wei Gao

Erschienen in: Journal of Materials Science: Materials in Electronics | Ausgabe 17/2020

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config
loading …

Abstract

Z-scheme heterojunction research has become a hotspot in the field of photocatalysis owing to the strong oxidative and reductive capacity for driving photocatalytic reactions. In this work, for the first time, a Z-scheme ternary bismuth phosphate/reduced graphene oxide/protonated g-C3N4 (BiPO4/rGO/pg-C3N4) photocatalyst was fabricated for photocatalytic degradation of tetracycline (TC). The optimal mass ratios of rGO and pg-C3N4 were confirmed as 1.2 wt% and 40 wt%, respectively. This Z-scheme heterojunction exhibited an enhanced TC degrading ability with an 80.0% of TC decomposition after 50 min simulated solar light irradiation, which was 3.3 and 6.3 times that of pg-C3N4 and BiPO4, respectively. Importantly, the internal electric field forced Z-scheme charge transfer of BiPO4/rGO/pg-C3N4 composites, possessing higher charge separation efficiency. The formation of the Z-scheme heterojunction was substantiated by radical scavenging experiments and Mott–Schottky measurements, and it was beneficial for the photocatalytic reaction by accelerating the charge separation and improving the redox ability. Moreover, rGO as cocatalyst could not only provide TC adsorption and catalytic sites but also further promote the charge transfer.
Vorheriger Artikel The sintering behavior and microwave dielectric properties of 0.67CaTiO3–0.33LaAlO3 ceramics sintered at medium temperatures with the additives of H3BO3–Li2CO3
Nächster Artikel Structural, optical and photocatalytic properties of pure and Pd-doped CdS thin films

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Springer Professional "Wirtschaft"

Online-Abonnement

Mit Springer Professional "Wirtschaft" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 340 Zeitschriften

aus folgenden Fachgebieten:

  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Versicherung + Risiko




Jetzt Wissensvorsprung sichern!

Jetzt informieren
Literatur
1.
X. Wu, W. Zhao, Y. Huang, G. Zhang, Mechanistic study of amorphous CoSx cages as advanced oxidation catalysts for excellent peroxymonosulfate activation towards antibiotics degradation. Chem. Eng. J. 381, 122768 (2020)
2.
T. Heberer, Occurrence, fate, and removal of pharmaceutical residues in the aquatic environment: a review of recent research data. Toxicol. Lett. 131, 5–17 (2002)
3.
Y. He, Z. Huang, Z. Ma, B. Yao, H. Liu, L. Hu, Q. Zhao, Q. Yang, D. Liu, D. Du, Highly efficient photocatalytic performance and mechanism of α-ZnTcPc/g-C3N4 composites for methylene blue and tetracycline degradation under visible light irradiation. Appl. Surf. Sci. 498, 143834 (2019)
4.
Y. Liu, J. Kong, J. Yuan, W. Zhao, X. Zhu, C. Sun, J. Xie, Enhanced photocatalytic activity over flower-like sphere Ag/Ag2CO3/BiVO4 plasmonic heterojunction photocatalyst for tetracycline degradation. Chem. Eng. J. 331, 242–254 (2018)
5.
M. Liras, M. Barawi, A. Víctor, Hybrid materials based on conjugated polymers and inorganic semiconductors as photocatalysts: from environmental to energy applications. Chem. Soc. Rev. 48, 5454–5487 (2019)
6.
Z. Li, Z. Zhang, L. Wang, X. Meng, Bismuth chromate (Bi2CrO6): a promising semiconductor in photocatalysis. J. Catal. 382, 40–48 (2020)
7.
T. Wang, X. Liu, D. Han, C. Ma, Y. Liu, P. Huo, Y. Yan, Bi-based semiconductors composites of BiVO4 quantum dots decorated Bi12TiO20 via in-suit growth with ultrasound for enhancing photocatalytic performance. J. Alloy. Compd. 785, 460–467 (2019)
8.
L. Zhang, J. Ran, S.Z. Qiao, M. Jaroniec, Characterization of semiconductor photocatalysts. Chem. Soc. Rev. 48, 5184–5206 (2019)
9.
T. Cai, Y. Liu, L. Wang, S. Zhang, Y. Zeng, J. Yuan, J. Ma, W. Dong, C. Liu, S. Luo, Silver phosphate-based Z-Scheme photocatalytic system with superior sunlight photocatalytic activities and anti-photocorrosion performance. Appl. Catal. B 208, 1–13 (2017)
10.
L. Lin, Z. Yu, X. Wang, Crystalline carbon nitride semiconductors for photocatalytic water splitting. Angew. Chem. Int. Ed. 131, 6225–6236 (2019)
11.
J. Fu, J. Yu, C. Jiang, B. Cheng, g-C3N4-based heterostructured photocatalysts. Adv. Energy Mater. 8, 1701503 (2018)
12.
M. Yan, F. Zhu, W. Gu, L. Sun, W. Shi, Y. Hua, Construction of nitrogen-doped graphene quantum dots-BiVO4/g-C3N4 Z-scheme photocatalyst and enhanced photocatalytic degradation of antibiotics under visible light. RSC Adv. 6, 61162–61174 (2016)
13.
D. Xu, B. Cheng, W. Wang, C. Jiang, J. Yu, Ag2CrO4/g-C3N4/graphene oxide ternary nanocomposite Z-scheme photocatalyst with enhanced CO2 reduction activity. Appl. Catal. B 231, 368–380 (2018)
14.
Z. Li, S. Yang, J. Zhou, D. Li, X. Zhou, C. Ge, Y. Fang, Novel mesoporous g-C3N4 and BiPO4 nanorods hybrid architectures and their enhanced visible-light-driven photocatalytic performances. Chem. Eng. J. 241, 344–351 (2014)
15.
B.S. Naidu, B. Vishwanadh, V. Sudarsan, R.K. Vatsa, BiPO4: a better host for doping lanthanide ions. Dalton Trans. 41, 3194–3203 (2012)
16.
H. Xu, Y. Xu, H. Li, J. Xia, J. Xiong, S. Yin, C. Huang, H. Wan, Synthesis, characterization and photocatalytic property of AgBr/BiPO4 heterojunction photocatalyst. Dalton Trans. 41, 3387–3394 (2012)
17.
F. Duo, Y. Wang, X. Mao, X. Zhang, Y. Wang, C. Fan, A BiPO4/BiOCl heterojunction photocatalyst with enhanced electron-hole separation and excellent photocatalytic performance. Appl. Surf. Sci. 340, 35–42 (2015)
18.
J. Li, H. Yuan, Z. Zhu, Improved photoelectrochemical performance of Z-scheme g-C3N4/Bi2O3/BiPO4 heterostructure and degradation property. Appl. Surf. Sci. 385, 34–41 (2016)
19.
Q. Xu, L. Zhang, J. Yu, S. Wageh, A.A. Al-Ghamdi, M. Jaroniec, Direct Z-scheme photocatalysts: principles, synthesis, and applications. Mater. Today 21, 1042–1063 (2018)
20.
Y.M. Xia, W. Zhang, M.Y. Li, M. Xia, L.J. Zou, W.W. Gao, Effective electrochemical determination of chloramphenicol and florfenicol based on graphene/copper phthalocyanine nanocomposites modified glassy carbon electrode. J. Electrochem. Soc. 166, B654–B663 (2019)
21.
Y.M. Xia, J.H. Zhang, M. Xia, Y. Zhao, S.P. Chu, W.W. Gao, Peony-like magnetic graphene oxide/Fe3O4/BiOI nanoflower as a novel photocatalyst for enhanced photocatalytic degradation of Rhodamine B and Methylene blue dyes. J. Mater. Sci. 31, 1996–2009 (2020)
22.
Y. Li, H. Zhang, P. Liu, D. Wang, Y. Li, H. Zhao, Cross-linked g-C3N4/rGO nanocomposites with tunable band structure and enhanced visible light photocatalytic activity. Small 9, 3336–3344 (2013)
23.
F. Wu, X. Li, W. Liu, S. Zhang, Highly enhanced photocatalytic degradation of methylene blue over the indirect all-solid-state Z-scheme g-C3N4-RGO-TiO2 nanoheterojunctions. Appl. Surf. Sci. 405, 60–70 (2017)
24.
X. Miao, X. Shen, J. Wu, Z. Ji, J. Wang, L. Kong, M. Liu, C. Song, Fabrication of an all solid Z-scheme photocatalyst g-C3N4/GO/AgBr with enhanced visible light photocatalytic activity. Appl. Catal. A 539, 104–113 (2017)
25.
R. Zhu, F. Tian, R. Yang, J. He, J. Zhong, B. Chen, Z-scheme system ZnIn2S4/rGO/BiVO4 for hydrogen generation from water splitting and simultaneous degradation of organic pollutants under visible light. Renew. Energy 139, 22–27 (2019)
26.
L. Chen, F. He, N. Zhao, R. Guo, Fabrication of 3D quasi-hierarchical Z-scheme RGO-Fe2O3-MoS2 nanoheterostructures for highly enhanced visible-light-driven photocatalytic degradation. Appl. Surf. Sci. 420, 669–680 (2017)
27.
S. Hu, W. Zhang, J. Bai, G. Lu, L. Zhang, G. Wu, Construction of 2D/2D g-C3N4/rGO hybrid heterojunction catalyst with outstanding charge separation ability and nitrogen photofixation performance via surface protonation process. RSC Adv. 6, 25695–25702 (2016)
28.
X. Wang, M. Yu, W. Zhang, B. Zhang, L. Dong, Synthesis and microwave absorption properties of graphene/nickel composite materials. Appl. Phys. A 118, 1053–1058 (2015)
29.
L. Ge, F. Zuo, J. Liu, Q. Ma, C. Wang, D. Sun, L. Bartels, P. Feng, Synthesis and efficient visible light photocatalytic hydrogen evolution of polymeric g-C3N4 coupled with CdS quantum dots. J. Phys. Chem. C 116, 13708–13714 (2012)
30.
Y. He, J. Cai, T. Li, Y. Wu, Y. Yi, M. Luo, L. Zhao, Synthesis, characterization, and activity evaluation of DyVO4/g-C3N4 composites under visible-light irradiation. Ind. Eng. Chem. Res. 51, 14729–14737 (2012)
31.
J. Yu, K. Wang, W. Xiao, B. Cheng, Photocatalytic reduction of CO2 into hydrocarbon solar fuels over g-C3N4-Pt nanocomposite photocatalysts. Phys. Chem. Chem. Phys. 16, 11492–11501 (2014)
32.
B. Romero, S. Bruque, M.A. Aranda, J.E. Iglesias, Syntheses, crystal structures, and characterization of bismuth phosphates. Inorg. Chem. 33, 1869–1874 (1994)
33.
Q. Xiang, J. Yu, M. Jaroniec, Preparation and enhanced visible-light photocatalytic H2-production activity of graphene/C3N4 composites. J. Phys. Chem. C 115, 7355–7363 (2011)
34.
J. Xue, S. Ma, Y. Zhou, Z. Zhang, X. Liu, Fabrication of porous g-C3N4/Ag/Fe2O3 composites with enhanced visible light photocatalysis performance. RSC Adv. 5, 58738–58745 (2015)
35.
H. Huang, K. Xiao, N. Tian, F. Dong, T. Zhang, X. Du, Y. Zhang, Template-free precursor-surface-etching route to porous, thin g-C3N4 nanosheets for enhancing photocatalytic reduction and oxidation activity. J. Mater. Chem. A 5, 17452–17463 (2017)
36.
H. Katsumata, T. Sakai, T. Suzuki, S. Kaneco, Highly efficient photocatalytic activity of g-C3N4/Ag3PO4 hybrid photocatalysts through Z-scheme photocatalytic mechanism under visible light. Ind. Eng. Chem. Res. 53, 8018–8025 (2014)
37.
H. Li, J. Liu, W. Hou, N. Du, R. Zhang, X. Tao, Synthesis and characterization of g-C3N4/Bi2MoO6 heterojunctions with enhanced visible light photocatalytic activity. Appl. Catal. B 160, 89–97 (2014)
38.
H. Ye, H. Lin, J. Cao, S. Chen, Y. Chen, Enhanced visible light photocatalytic activity and mechanism of BiPO4 nanorods modified with AgI nanoparticles. J. Mol. Catal. A 397, 85–92 (2015)
39.
R. Hao, G. Wang, H. Tang, L. Sun, C. Xu, D. Han, Template-free preparation of macro/mesoporous g-C3N4/TiO2 heterojunction photocatalysts with enhanced visible light photocatalytic activity. Appl. Catal. B 187, 47–58 (2016)
40.
Y. Yan, X. Tang, C. Ma, H. Huang, K. Yu, Y. Liu, Z. Lu, C. Li, Z. Zhu, P. Huo, A 2D mesoporous photocatalyst constructed by the modification of biochar on BiOCl ultrathin nanosheets for enhancing the TC-HCl degradation activity. New J. Chem. 44, 79–86 (2020)
41.
T. Xiao, Z. Tang, Y. Yang, L. Tang, Y. Zhou, Zou. In situ construction of hierarchical WO3/g-C3N4 composite hollow microspheres as a Z-scheme photocatalyst for the degradation of antibiotics. Appl. Catal. B 220, 417–428 (2018)
42.
K.S. Sing, Reporting physisorption data for gas/solid systems with special reference to the determination of surface area and porosity. Pure Appl. Chem. 57, 603–619 (1985)
43.
X. Yang, F. Qian, Y. Wang, M. Li, J. Lu, Y. Li, M. Bao, Constructing a novel ternary composite (C16H33(CH3)3N)4W10O32/g-C3N4/rGO with enhanced visible-light-driven photocatalytic activity for degradation of dyes and phenol. Appl. Catal. B 200, 283–296 (2017)
44.
J. Lei, Y. Chen, F. Shen, L. Wang, Y. Liu, J. Zhang, Surface modification of TiO2 with g-C3N4 for enhanced UV and visible photocatalytic activity. J. Alloys Compd. 631, 328–334 (2015)
45.
W. Lu, T. Xu, Y. Wang, H. Hu, N. Li, X. Jiang, W. Chen, Synergistic photocatalytic properties and mechanism of g-C3N4 coupled with zinc phthalocyanine catalyst under visible light irradiation. Appl. Catal. B 180, 20–28 (2016)
46.
M. Li, L. Zhang, X. Fan, Y. Zhou, M. Wu, J. Shi, Highly selective CO2 photoreduction to CO over g-C3N4/Bi2WO6 composites under visible light. J. Mater. Chem. A 3, 5189–5196 (2015)
47.
N. Tian, Y. Zhang, X. Li, K. Xiao, X. Du, F. Dong, G.I. Waterhouse, T. Zhang, H. Huang, Precursor-reforming protocol to 3D mesoporous g-C3N4 established by ultrathin self-doped nanosheets for superior hydrogen evolution. Nano Energy 38, 72–81 (2017)
48.
C. Pan, Y. Zhu, New type of BiPO4 oxy-acid salt photocatalyst with high photocatalytic activity on degradation of dye. Environ. Sci. Technol. 44, 5570–5574 (2010)
49.
S. Liu, J. Chen, D. Xu, X. Zhang, M. Shen, Enhanced photocatalytic activity of direct Z-scheme Bi2O3/g-C3N4 composites via facile one-step fabrication. J. Mater. Res. 33, 1391–1400 (2018)
50.
D. Xu, B. Cheng, J. Zhang, W. Wang, J. Yu, W. Ho, Photocatalytic activity of Ag2MO4 (M = Cr, Mo, W) photocatalysts. J. Mater. Chem. A 3, 20153–20166 (2015)
51.
M. Ou, Q. Zhong, S. Zhang, L. Yu, Ultrasound assisted synthesis of heterogeneous g-C3N4/BiVO4 composites and their visible-light-induced photocatalytic oxidation of NO in gas phase. J. Alloys Compd. 626, 401–409 (2015)
52.
Y. He, L. Zhang, B. Teng, M. Fan, New application of Z-scheme Ag3PO4/g-C3N4 composite in converting CO2 to fuel. Environ. Sci. Technol. 49, 649–656 (2014)
53.
G.M. Kumar, P. Ilanchezhiyan, H.D. Cho, S. Yuldashev, H.C. Jeon, D.Y. Kim, T.W. Kang, Effective modulation of optical and photoelectrical properties of SnS2 hexagonal nanoflakes via Zn incorporation. Nanomaterials 9, 924 (2019)
54.
K. Sayama, A. Nomura, T. Arai, T. Sugita, R. Abe, M. Yanagida, T. Oi, Y. Iwasaki, Y. Abe, H. Sugihara, Photoelectrochemical decomposition of water into H2 and O2 on porous BiVO4 thin-film electrodes under visible light and significant effect of Ag ion treatment. J. Phys. Chem. B 110, 11352–11360 (2006)
55.
W. Luo, Z. Li, X. Jiang, T. Yu, L. Liu, X. Chen, J. Ye, Z. Zou, Correlation between the band positions of (SrTiO3)1–x·(LaTiO2N)x solid solutions and photocatalytic properties under visible light irradiation. Phys. Chem. Chem. Phys. 10, 6717–6723 (2008)
56.
H. Li, H. Yu, X. Quan, S. Chen, Y. Zhang, Uncovering the key role of the fermi level of the electron mediator in a Z-scheme photocatalyst by detecting the charge transfer process of WO3-metal-g-C3N4 (Metal = Cu, Ag, Au). ACS Appl. Mater. Interfaces 8, 2111–2119 (2016)
57.
E. Gao, W. Wang, M. Shang, J. Xu, Synthesis and enhanced photocatalytic performance of graphene-Bi2WO6 composite. Phys. Chem. Chem. Phys. 13, 2887–2893 (2011)
58.
D. Scaife, Oxide semiconductors in photoelectrochemical conversion of solar energy. Sol. Energy 25, 41–54 (1980)
59.
W. Iqbal, B. Qiu, J. Lei, L. Wang, J. Zhang, M. Anpo, One-step large-scale highly active g-C3N4 nanosheets for efficient sunlight-driven photocatalytic hydrogen production. Dalton Trans. 46, 10678–10684 (2017)
60.
L. Zhang, S. Li, B. Liu, D. Wang, T. Xie, Highly efficient CdS/WO3 photocatalysts: Z-scheme photocatalytic mechanism for their enhanced photocatalytic H2 evolution under visible light. ACS Catal. 4, 3724–3729 (2014)
61.
H. Yu, P. Xiao, J. Tian, F. Wang, J.G. Yu, Phenylamine-functionalized rGO/TiO2 photocatalysts: spatially separated adsorption sites and tunable photocatalytic selectivity. ACS Appl. Mater. Interfaces 8, 29470–29477 (2016)
62.
Y. Xu, Y. Mo, J. Tian, P. Wang, H. Yu, J. Yu, The synergistic effect of graphitic N and pyrrolic N for the enhanced photocatalytic performance of nitrogen-doped graphene/TiO2 nanocomposites. Appl. Catal. B 181, 810–817 (2016)
Metadaten
Titel
Z-Scheme mechanism study of ternary BiPO4/reduced graphene oxide/protonated g-C3N4 photocatalyst with interfacial electric field mediating for the effective photocatalytic degradation of tetracycline
verfasst von
Ya-Mu Xia
Shan-Peng Chu
Zi-Yang Liao
Shu-Yu Sun
Xu Cheng
Wei-Wei Gao
Publikationsdatum
24.07.2020
Verlag
Springer US
Erschienen in
Journal of Materials Science: Materials in Electronics / Ausgabe 17/2020
Print ISSN: 0957-4522
Elektronische ISSN: 1573-482X
DOI
https://doi.org/10.1007/s10854-020-04050-x

Weitere Artikel der Ausgabe 17/2020

Journal of Materials Science: Materials in Electronics 17/2020 Zur Ausgabe

OriginalPaper

Growth and characterization of ZnSe nanocrystals synthesized using solvothermal process

OriginalPaper

Hydrogen-rich c-Si interfacial modification to obtain efficient passivation for silicon heterojunction solar cell

OriginalPaper

Novel red-emitting BaGeTeO6:Sm3+ phosphors with high color purity for NUV excited with white LEDs

OriginalPaper

Regulating electronic properties of graphene sheet via n-type doping for solar cells applications

OriginalPaper

Vibrational modes in (TlGaS2)x‒(TlGaSe2)1−x mixed crystals by Raman measurements: compositional dependence of the mode frequencies and line-shapes

OriginalPaper

Novel color tunable phosphors NaYGeO4: Tm3+, Tb3+, Eu3+ for ultraviolet excited white LEDs with good thermal stability

Neuer Inhalt

    Bildnachweise