Spin-1 lattice-gas model. I. Condensation and solidification of a simple fluid

Joseph Lajzerowicz and Jean Sivardière
Phys. Rev. A 11, 2079 – Published 1 June 1975
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Abstract

A spin-1 lattice-gas model, similar to the Blume-Emery-Griffiths model for He3-He4 mixtures, is shown to describe condensation and solidification of a simple fluid. The Ising-like Hamiltonian of the system involves quadrupolar and dipolar interactions, which are responsible for condensation and solidification, respectively. The molecular-field approximation is used, and the ordinary phase diagram of a simple fluid is reproduced. However, for some range of the parameters, the liquid-gas equilibrium curve disappears. Also, the melting curve may exhibit a tricritical point: For pressures larger than the tricritical pressure, critical melting is found. Other physical applications of the model are briefly discussed.

  • Received 19 February 1974

DOI:https://doi.org/10.1103/PhysRevA.11.2079

©1975 American Physical Society

Authors & Affiliations

Joseph Lajzerowicz

  • Laboratoire de Spectrométrie Physique, Université Scientifique et Médicale de Grenoble, B. P. 53-38041 Grenoble Cedex, France

Jean Sivardière

  • Département de Recherche Fondamentale, Centre d'Etudes Nucléaires de Grenoble, B.P. 85-38041 Grenoble Cedex, France

See Also

Spin-1 lattice-gas model. II. Condensation and phase separation in a binary fluid

Jean Sivardière and Joseph Lajzerowicz
Phys. Rev. A 11, 2090 (1975)

Spin-1 lattice-gas model. III. Tricritical points in binary and ternary fluids

Jean Sivardière and Joseph Lajzerowicz
Phys. Rev. A 11, 2101 (1975)

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Issue

Vol. 11, Iss. 6 — June 1975

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