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Journal of Polymer Research
Erschienen in: Journal of Polymer Research 4/2024

01.04.2024 | Original Paper

Effect of para-substituent on copolymerization and thermal degradation kinetics of styrene copolymers composed with maleic anhydride derivative

verfasst von: Changlei Yang, Yanping Wang, Yufei Liu, Jun Qin, Min He, Shuhao Qin, Jie Yu

Erschienen in: Journal of Polymer Research | Ausgabe 4/2024

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Abstract

The investigation of the polymerization kinetics and thermal degradation kinetics of maleic anhydride copolymers is of significant reference value for the synthesis of multifunctional and high-performance maleic anhydride-based copolymers and their applications in different fields. In this study, anhydride (MAH) derived styrene copolymers, namely Poly(N-phenylmaleimide-alt-styrene) (PNS), Poly(N-(4-carboxyphenyl)maleimide-alt-styrene) (PCS), andpoly(N-fluorine-phenylmaleimide-alt-styrene) (PFS), were prepared using a solution copolymerization method. The copolymerization kinetics and thermal degradation kinetics of MAH derived styrene copolymers were investigated using nuclear magnetic resonance (NMR) and thermogravimetric analysis (TGA), as well as the Arrhenius equation and Kim-Park method. The study revealed that the incorporation of carboxyl and fluorine groups had varying degrees of influence on maleic anhydride-styrene copolymers. The copolymerization rate constant (K value) followed the order PNS>PCS>PFS, while the copolymerization activation energy (Ea) followed the order PNS<PFS<PCS. Moreover, the thermal degradation activation energy (Ea′) followed the order PNS<PNS<PFS, indicating that PFS exhibited easier polymerization and the fluorine group significantly enhanced the thermal stability of the maleic anhydride-styrene copolymers.
Vorheriger Artikel Aquatic biodegradation of poly(β-hydroxybutyrate) in polylactic acid and maleic anhydride blended fibers
Nächster Artikel Investigating the effects of sequential aging temperature profiles on the response of neoprene rubber

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Metadaten
Titel
Effect of para-substituent on copolymerization and thermal degradation kinetics of styrene copolymers composed with maleic anhydride derivative
verfasst von
Changlei Yang
Yanping Wang
Yufei Liu
Jun Qin
Min He
Shuhao Qin
Jie Yu
Publikationsdatum
01.04.2024
Verlag
Springer Netherlands
Erschienen in
Journal of Polymer Research / Ausgabe 4/2024
Print ISSN: 1022-9760
Elektronische ISSN: 1572-8935
DOI
https://doi.org/10.1007/s10965-024-03945-1

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