Skip to main content
Erschienen in: Clean Technologies and Environmental Policy 8/2014

01.12.2014 | Original Paper

Removal of organochlorine pesticides by chitosan loaded with silver oxide nanoparticles from water

verfasst von: Bahar Rahmanifar, Shahram Moradi Dehaghi

Erschienen in: Clean Technologies and Environmental Policy | Ausgabe 8/2014

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config
loading …

Abstract

Silver oxide nanoparticles embedded chitosan beads were studied to remove pesticides from water. A simple and an effective approach was used in regard to preparing AgO nanoparticles on the surface of chitosan. The chitosan–AgO nanoparticles (CS–AgONPs) composite was characterized by infrared spectroscopy (FTIR), X-ray diffraction, and scanning electron microscopy. The CS–AgONPs composite beads were optimized to remove maximum permethrin as the model pesticide, with amount of sorbent, agitating time, initial concentration of pesticide, and pH parameters. In optimum conditions, room temperature, pH 7, and the CS–AgONPs beads could recover 99 % pesticides of permethrin solution (0.1 mg L-1) which were characterized by using UV spectrophotometer at 272 nm. In comparison with the pure chitosan, the removal capacity of CS–AgONPs beads has been increased to 49 %. The CS–AgONPs composite beads have high capacity as an adsorbent which could explore a new biocompatible and eco-friendly strategy for pesticide removal, and appears to be the new promising material in water treatment application.

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Literatur
Zurück zum Zitat Akhtar M, Hasany SM, Bhanger MI, Iqbal S (2007) Low cost sorbents for the removal of methyl parathion pesticide from aqueous solution. Chemosphere 66:1829–1838CrossRef Akhtar M, Hasany SM, Bhanger MI, Iqbal S (2007) Low cost sorbents for the removal of methyl parathion pesticide from aqueous solution. Chemosphere 66:1829–1838CrossRef
Zurück zum Zitat Altaher H (2012) The use of chitosan as a coagulant in the pre-treatment of turbid sea water. J Hazard Mater 233–234:97–102CrossRef Altaher H (2012) The use of chitosan as a coagulant in the pre-treatment of turbid sea water. J Hazard Mater 233–234:97–102CrossRef
Zurück zum Zitat Andres-Verges M, Serna CJ (1988) Morphological characterization of ZnO powders by X-ray and IR spectroscopy. J Mater Sci Lett 7:970–972CrossRef Andres-Verges M, Serna CJ (1988) Morphological characterization of ZnO powders by X-ray and IR spectroscopy. J Mater Sci Lett 7:970–972CrossRef
Zurück zum Zitat Arayne MS, Sultana N, Hussain F (2011) Validated RP-HPLC method for determination of permethrin in bulk and topical preparations using UV–Vis detector. J Chromatogr Sci 49:287–291CrossRef Arayne MS, Sultana N, Hussain F (2011) Validated RP-HPLC method for determination of permethrin in bulk and topical preparations using UV–Vis detector. J Chromatogr Sci 49:287–291CrossRef
Zurück zum Zitat Brugnerotto J, Lizardi J, Goycoolea FM, Arguelles-Monal W, Desbrieres J, Rinaudo M (2001) An infrared investigation in relation with chitin and chitosan characterization. Polymer 42:3569–3580CrossRef Brugnerotto J, Lizardi J, Goycoolea FM, Arguelles-Monal W, Desbrieres J, Rinaudo M (2001) An infrared investigation in relation with chitin and chitosan characterization. Polymer 42:3569–3580CrossRef
Zurück zum Zitat Chandy T, Sharma CP (1993) Chitosan matrix for oral sustained delivery of ampicillin. Biomaterials 14:939–944CrossRef Chandy T, Sharma CP (1993) Chitosan matrix for oral sustained delivery of ampicillin. Biomaterials 14:939–944CrossRef
Zurück zum Zitat Cheevaporn V, Pindang M, Helander HF (2010) Polycyclic aromatic hydrocarbon contamination in Nile Tilapia. Environ Asia 3(2):8–14 Cheevaporn V, Pindang M, Helander HF (2010) Polycyclic aromatic hydrocarbon contamination in Nile Tilapia. Environ Asia 3(2):8–14
Zurück zum Zitat Daneshvar N, Aber S, Seyed Dorraji MS, Khataee AR, Rasoulifard MH (2007) Photocatalytic degradation of the insecticide diazinon in the presence of prepared nanocrystalline ZnO powders under irradiation of UV–C light. Sep Purif Technol 58:91–98CrossRef Daneshvar N, Aber S, Seyed Dorraji MS, Khataee AR, Rasoulifard MH (2007) Photocatalytic degradation of the insecticide diazinon in the presence of prepared nanocrystalline ZnO powders under irradiation of UV–C light. Sep Purif Technol 58:91–98CrossRef
Zurück zum Zitat Dong ZF, Du YM, Fan LH, Wen Y, Liu H, Wang XH (2004) Preparation and properties of chitosan/gelatin/nano-TiO2 ternary composite films. J Funct Polym 17:61–66 Dong ZF, Du YM, Fan LH, Wen Y, Liu H, Wang XH (2004) Preparation and properties of chitosan/gelatin/nano-TiO2 ternary composite films. J Funct Polym 17:61–66
Zurück zum Zitat Fana L, Zhang Y, Luoa C, Lua F, Qiua H, Suna M (2012) Synthesis and characterization of magnetic β-cyclodextrin–chitosan nanoparticles as nano-adsorbents for removal of methyl blue. Int J Biol Macromol 50:444–450CrossRef Fana L, Zhang Y, Luoa C, Lua F, Qiua H, Suna M (2012) Synthesis and characterization of magnetic β-cyclodextrin–chitosan nanoparticles as nano-adsorbents for removal of methyl blue. Int J Biol Macromol 50:444–450CrossRef
Zurück zum Zitat Guo TY, Xia YQ, Hao GJ, Song MD, Zhang BH (2004) Adsorption separation of hemoglobin by molecularly imprinted chitosan beads. Biomaterials 25:5905–5912CrossRef Guo TY, Xia YQ, Hao GJ, Song MD, Zhang BH (2004) Adsorption separation of hemoglobin by molecularly imprinted chitosan beads. Biomaterials 25:5905–5912CrossRef
Zurück zum Zitat Haroun AA, Mashaly HM, El-Sayed NH (2013) Novel nanocomposites based on gelatin/HPET/chitosan with high performance acid red 150 dye adsorption. Clean Technol Environ Policy 15:367–374CrossRef Haroun AA, Mashaly HM, El-Sayed NH (2013) Novel nanocomposites based on gelatin/HPET/chitosan with high performance acid red 150 dye adsorption. Clean Technol Environ Policy 15:367–374CrossRef
Zurück zum Zitat Hong-Liang F, Xiao-Yong G, Zeng-Yuan Z, Jiao-Min M (2010) Study on the crystalline structure and the thermal stability of silver-oxide films deposited by using direct-current reactive magnetron sputtering methods. J Korean Phys Soc 56(4):1176–1179CrossRef Hong-Liang F, Xiao-Yong G, Zeng-Yuan Z, Jiao-Min M (2010) Study on the crystalline structure and the thermal stability of silver-oxide films deposited by using direct-current reactive magnetron sputtering methods. J Korean Phys Soc 56(4):1176–1179CrossRef
Zurück zum Zitat Hu Z, Zhang J, Chan WL, Szeto YS (2006) Suspension of silver oxide nanoparticles in chitosan solution and its antibacterial activity in cotton fabrics. Mater Res Soc 920:0920-S02-03CrossRef Hu Z, Zhang J, Chan WL, Szeto YS (2006) Suspension of silver oxide nanoparticles in chitosan solution and its antibacterial activity in cotton fabrics. Mater Res Soc 920:0920-S02-03CrossRef
Zurück zum Zitat Hu Y, Bo Y, YaoBo L, RongShi C (2009) Preparation of magnetic chitosan microspheres and its applications in wastewater treatment. Sci China Ser B Chem 52(3):249–256CrossRef Hu Y, Bo Y, YaoBo L, RongShi C (2009) Preparation of magnetic chitosan microspheres and its applications in wastewater treatment. Sci China Ser B Chem 52(3):249–256CrossRef
Zurück zum Zitat Kumirska J, Czerwicka M, Kaczynski Z, Bychowska A, Brzozowski K, Thoming J, Stepnowski P (2010) Application of spectroscopic methods for structural analysis of chitin and chitosan. Mar Drugs 8:1567–1636CrossRef Kumirska J, Czerwicka M, Kaczynski Z, Bychowska A, Brzozowski K, Thoming J, Stepnowski P (2010) Application of spectroscopic methods for structural analysis of chitin and chitosan. Mar Drugs 8:1567–1636CrossRef
Zurück zum Zitat Li L-H, Deng J-C, Deng H-R, Liu Z-L, Xin L (2010) Synthesis and characterization of chitosan/ZnO nanoparticle composite membranes. Carbohydr Res 345:994–998CrossRef Li L-H, Deng J-C, Deng H-R, Liu Z-L, Xin L (2010) Synthesis and characterization of chitosan/ZnO nanoparticle composite membranes. Carbohydr Res 345:994–998CrossRef
Zurück zum Zitat Linnett PJ (2008) Permethrin toxicosis in cats. Aust Vet J 86(1–2):32–35CrossRef Linnett PJ (2008) Permethrin toxicosis in cats. Aust Vet J 86(1–2):32–35CrossRef
Zurück zum Zitat Pearson FG, Marchessault RH, Liang CY (1960) Infrared spectra of crystalline polysaccharides. V. Chitin. J Polym Sci 43:101–116 Pearson FG, Marchessault RH, Liang CY (1960) Infrared spectra of crystalline polysaccharides. V. Chitin. J Polym Sci 43:101–116
Zurück zum Zitat Saifuddin N, Dinara S (2011) Pretreatment of palm oil mill effluent (POME) using magnetic chitosan. E-J Chem 8(S1):S67–S78CrossRef Saifuddin N, Dinara S (2011) Pretreatment of palm oil mill effluent (POME) using magnetic chitosan. E-J Chem 8(S1):S67–S78CrossRef
Zurück zum Zitat Saifuddin N, Nian CY, Zhan LW, Ning KX (2011) Chitosan-silver nanoparticles composite as point-of-use drinking water filtration system for household to remove pesticides in water. Asian J Biochem. doi:10.3923/ajb.2011 Saifuddin N, Nian CY, Zhan LW, Ning KX (2011) Chitosan-silver nanoparticles composite as point-of-use drinking water filtration system for household to remove pesticides in water. Asian J Biochem. doi:10.​3923/​ajb.​2011
Zurück zum Zitat Salehi R, Arami M, Mahmoodi NM, Bahrami H, Khorramfar S (2010) Novel biocompatible composite (chitosan zinc oxide nanoparticle): preparation, characterization and dye adsorption properties. Colloids Surf B 80(1):86–93CrossRef Salehi R, Arami M, Mahmoodi NM, Bahrami H, Khorramfar S (2010) Novel biocompatible composite (chitosan zinc oxide nanoparticle): preparation, characterization and dye adsorption properties. Colloids Surf B 80(1):86–93CrossRef
Zurück zum Zitat Shu XZ, Zhu KJ (2001) Chitosan/gelation microspheres prepared by modified emulsification and ionotropic gelation. J Microencapsul 18:237–245CrossRef Shu XZ, Zhu KJ (2001) Chitosan/gelation microspheres prepared by modified emulsification and ionotropic gelation. J Microencapsul 18:237–245CrossRef
Zurück zum Zitat Sivaraj R, Namasivayam C, Kadirvelu K (2001) Orange peel as an adsorbent in the removal of acid violet 17 (acid dye) from aqueous solutions. Waste Manag 21:105–110CrossRef Sivaraj R, Namasivayam C, Kadirvelu K (2001) Orange peel as an adsorbent in the removal of acid violet 17 (acid dye) from aqueous solutions. Waste Manag 21:105–110CrossRef
Zurück zum Zitat Sokkera HH, El-Sawy NM, Hassan MA, El-Anadouli BE (2011) Adsorption of crude oil from aqueous solution by hydrogel of chitosan based polyacrylamide prepared by radiation induced graft polymerization. J Hazard Mater 190:359–365CrossRef Sokkera HH, El-Sawy NM, Hassan MA, El-Anadouli BE (2011) Adsorption of crude oil from aqueous solution by hydrogel of chitosan based polyacrylamide prepared by radiation induced graft polymerization. J Hazard Mater 190:359–365CrossRef
Zurück zum Zitat Sugashini S, Begum KMMS (2013) Optimization using central composite design (CCD) for the biosorption of Cr(VI) ions by cross linked chitosan carbonized rice husk (CCACR). Clean Technol Environ Policy 15:293–302CrossRef Sugashini S, Begum KMMS (2013) Optimization using central composite design (CCD) for the biosorption of Cr(VI) ions by cross linked chitosan carbonized rice husk (CCACR). Clean Technol Environ Policy 15:293–302CrossRef
Zurück zum Zitat Sung LP, Scierka S, Baghai-anaraki M, Ho DL (2003) Characterization of metal-oxide nanoparticles: synthesis and dispersion in polymeric coatings. Mater Res Soc 740:1541–1546 Sung LP, Scierka S, Baghai-anaraki M, Ho DL (2003) Characterization of metal-oxide nanoparticles: synthesis and dispersion in polymeric coatings. Mater Res Soc 740:1541–1546
Zurück zum Zitat Wan Ngah WS, Fatinathan S (2010) Pb(II) biosorption using chitosan and chitosan derivatives beads: equilibrium, ion exchange and mechanism studies. J Environ Sci 22(3):338–346CrossRef Wan Ngah WS, Fatinathan S (2010) Pb(II) biosorption using chitosan and chitosan derivatives beads: equilibrium, ion exchange and mechanism studies. J Environ Sci 22(3):338–346CrossRef
Zurück zum Zitat Wang L, Wang A (2008) Adsorption properties of Congo Red from aqueous solution onto N,O-carboxymethyl-chitosan. Bioresour Technol 99:1403–1408CrossRef Wang L, Wang A (2008) Adsorption properties of Congo Red from aqueous solution onto N,O-carboxymethyl-chitosan. Bioresour Technol 99:1403–1408CrossRef
Zurück zum Zitat Wen Y, Shen C, Ni Y, Tong S, Yu F (2012) Glow discharge plasma in water: a green approach to enhancing ability of chitosan for dye removal. J Hazard Mater 201–202:162–169CrossRef Wen Y, Shen C, Ni Y, Tong S, Yu F (2012) Glow discharge plasma in water: a green approach to enhancing ability of chitosan for dye removal. J Hazard Mater 201–202:162–169CrossRef
Zurück zum Zitat Yoshizuka K, Lou Z, Inoue K (2000) Silver-complexed chitosan microparticles for pesticide removal. React Funct Polym 44:47–54CrossRef Yoshizuka K, Lou Z, Inoue K (2000) Silver-complexed chitosan microparticles for pesticide removal. React Funct Polym 44:47–54CrossRef
Zurück zum Zitat Zhu H-Y, Fu Y-Q, Jiang R, Yao J, Xiao L, Zeng G-M (2012) Novel magnetic chitosan/poly(vinyl alcohol) hydrogel beads: preparation, characterization and application for adsorption of dye from aqueous solution. Bioresour Technol 105:24–30CrossRef Zhu H-Y, Fu Y-Q, Jiang R, Yao J, Xiao L, Zeng G-M (2012) Novel magnetic chitosan/poly(vinyl alcohol) hydrogel beads: preparation, characterization and application for adsorption of dye from aqueous solution. Bioresour Technol 105:24–30CrossRef
Metadaten
Titel
Removal of organochlorine pesticides by chitosan loaded with silver oxide nanoparticles from water
verfasst von
Bahar Rahmanifar
Shahram Moradi Dehaghi
Publikationsdatum
01.12.2014
Verlag
Springer Berlin Heidelberg
Erschienen in
Clean Technologies and Environmental Policy / Ausgabe 8/2014
Print ISSN: 1618-954X
Elektronische ISSN: 1618-9558
DOI
https://doi.org/10.1007/s10098-013-0692-5

Weitere Artikel der Ausgabe 8/2014

Clean Technologies and Environmental Policy 8/2014 Zur Ausgabe