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Erschienen in: Journal of Material Cycles and Waste Management 1/2024

23.11.2023 | ORIGINAL ARTICLE

Role of polyacrylamide in the removal of soluble phosphorus and fluorine from phosphogypsum

verfasst von: Chufang Liang, Siting Xu, Fang Zhou, Bona Deng, Meng Tian, Lisen Zhang, Chunqiao Xiao, Ruan Chi

Erschienen in: Journal of Material Cycles and Waste Management | Ausgabe 1/2024

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Abstract

Phosphogypsum, an industrial solid waste produced in wet phosphoric acid production, is difficult to be utilized due to the harmful impurities such as phosphorus and fluorine. In this study, lime neutralization process was introduced to remove soluble phosphorus and soluble fluorine from phosphogypsum in presence of polyacrylamide. The effects of polyacrylamide content, CaO content and aging time on the removal efficiencies of soluble phosphorus and soluble fluorine were investigated by response surface methodology. The results showed that in the presence of 0.03% polyacrylamide, the removal efficiencies of soluble phosphorus and soluble fluorine in phosphogypsum increased from 86.25% and 94.02% to 93.27% and 96.07%, respectively. The optimum removal conditions for soluble phosphorus and soluble fluorine were determined by the response surface method with polyacrylamide content of 0.022%, aging time of 2.203 h and CaO content of 1.956%, and the optimized removal efficiencies of soluble phosphorus and soluble fluorine were 99.12% and 96.84%, respectively. Compared with separate lime action, the removal efficiencies were increased by 12.87% and 2.82%, respectively. The accuracy of the results was demonstrated through in situ leaching experiments. The treated phosphogypsum, the 0.02% soluble phosphorus and 0.03% soluble fluorine met the requirements of gypsum building materials.

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Literatur
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Zurück zum Zitat Gadaleta S, Paschalis E, Betts F, Mendelsohn R, Boskey A (1996) Fourier transform infrared spectroscopy of the solution-mediated conversion of amorphous calcium phosphate to hydroxyapatite: new correlations between X-ray diffraction and infrared data. Calcif Tissue Int 58:9–16. https://doi.org/10.1007/BF02509540CrossRef Gadaleta S, Paschalis E, Betts F, Mendelsohn R, Boskey A (1996) Fourier transform infrared spectroscopy of the solution-mediated conversion of amorphous calcium phosphate to hydroxyapatite: new correlations between X-ray diffraction and infrared data. Calcif Tissue Int 58:9–16. https://​doi.​org/​10.​1007/​BF02509540CrossRef
Metadaten
Titel
Role of polyacrylamide in the removal of soluble phosphorus and fluorine from phosphogypsum
verfasst von
Chufang Liang
Siting Xu
Fang Zhou
Bona Deng
Meng Tian
Lisen Zhang
Chunqiao Xiao
Ruan Chi
Publikationsdatum
23.11.2023
Verlag
Springer Japan
Erschienen in
Journal of Material Cycles and Waste Management / Ausgabe 1/2024
Print ISSN: 1438-4957
Elektronische ISSN: 1611-8227
DOI
https://doi.org/10.1007/s10163-023-01849-8

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