nach oben

Erschienen in:

2024 | OriginalPaper | Buchkapitel

Sustainable Pathways for Hydrogen Production via Molecular Catalysts

verfasst von : Mahendra Kumar Awasthi, Surabhi Rai, Arnab Dutta

Erschienen in: Climate Action and Hydrogen Economy

Verlag: Springer Nature Singapore

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config

KI-gestützte Suche

Aus

Abstract

The current global energy requirement is primarily dependent on conventional fossil fuels (coal, oil, and natural gas), which invariably emit a copious amount of CO₂, leading to adverse climate change effects. Therefore, it is highly commendable to search for carbon footprint-free energy alternatives. Renewable energy resources (solar, wind, tidal, etc.) have emerged as apt alternatives to resolve this conundrum; however, they require a stable energy vector due to their intrinsic intermittence. Hydrogen molecule fits the bill as it can be directly used in a fuel cell for energy production, following a greener pathway. Therefore, hydrogen production has become a bustling research area via sustainable methods. Since water is an abundant resource of protons and covers over 71% of the planet, hydrogen evolution from water becomes useful. Hydrogen can be produced from water through electrical, photochemical, and biological means. Among these methods, water electrolysis is regarded as one of the environmentally friendly techniques to produce hydrogen. Besides this, hydrogen can also be generated via the photochemical splitting of water, where solar energy can be directly involved. Here in this chapter, we have depicted the recent advancements in electrochemical and photochemical hydrogen production using bio-inspired molecular catalysts.

Learning objectives:

Current approach for production of hydrogen
Role of bio-inspired molecular catalysis in hydrogen production
Pathways for sustainable hydrogen production from water

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

über 102.000 Bücher
über 537 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Finance + Banking
Management + Führung
Marketing + Vertrieb
Maschinenbau + Werkstoffe
Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

über 67.000 Bücher
über 390 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Maschinenbau + Werkstoffe

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Vorheriges Kapitel Green Hydrogen from Biomass Through Gasification—A Carbon Negative Route for Hydrogen Production

Nächstes Kapitel Hydrogen Production from Liquid Hydrogen Carriers

Ipcc (2022) Global warming of 1.5 °C: IPCC special report on impacts of global warming of 1.5°C above pre-industrial levels in context of strengthening response to climate change, sustainable development, and efforts to eradicate poverty, 1st edn. Cambridge University Press. https://doi.org/10.1017/9781009157940

US EPA O. Overview of greenhouse gases. https://www.epa.gov/ghgemissions/overview-greenhouse-gases. Accessed 13 Oct 2022

Changes since the industrial revolution. American Chemical Society. https://www.acs.org/content/acs/en/climatescience/greenhousegases/industrialrevolution.html. Accessed 13 Oct 2022

Changes in the climate. Center for Climate and Energy Solutions

India. https://climateactiontracker.org/countries/india/. Accessed 13 Oct 2022

Lewis NS, Nocera DG (2006) Powering the planet: chemical challenges in solar energy utilization. Proc Natl Acad Sci 103(43):15729–15735. https://doi.org/10.1073/pnas.0603395103CrossRef

Hydrogen-storage materials for mobile applications. Nature. https://www.nature.com/articles/35104634. Accessed 13 Oct 2022

A hydrogen economy. Science. https://www.science.org/doi/https://doi.org/10.1126/science.176.4041.1323. Accessed 13 Oct 2022

Armaroli (2011) The hydrogen issue. ChemSusChem. Wiley Online Library. https://chemistry-europe.onlinelibrary.wiley.com/doi/abs/https://doi.org/10.1002/cssc.201000182. Accessed 13 Oct 2022

10.

Eberle U, Felderhoff M, Schüth F (2009) Chemical and physical solutions for hydrogen storage. Angew Chem Int Ed 48(36):6608–6630. https://doi.org/10.1002/anie.200806293CrossRef

11.

Arregi A, Amutio M, Lopez G, Bilbao J, Olazar M (2018) Evaluation of thermochemical routes for hydrogen production from biomass: a review. Energy Convers Manag 165:696–719. https://doi.org/10.1016/j.enconman.2018.03.089CrossRef

12.

Jiang H-L, Singh SK, Yan J-M, Zhang X-B, Xu Q (2010) Liquid-phase chemical hydrogen storage: catalytic hydrogen generation under ambient conditions. Chemsuschem 3(5):541–549. https://doi.org/10.1002/cssc.201000023CrossRef

13.

Sartbaeva A, Kuznetsov VL, Wells SA, Edwards PP (2008) Hydrogen nexus in a sustainable energy future. Energy Environ Sci 1(1):79–85. https://doi.org/10.1039/B810104NCrossRef

14.

Chisholm G, Zhao T, Cronin L (2022) 24-hydrogen from water electrolysis. In: Letcher TM (ed) Storing energy, 2nd edn. Elsevier, pp 559–591. https://doi.org/10.1016/B978-0-12-824510-1.00015-5

15.

Kalamaras CM, Efstathiou AM (2013) Hydrogen production technologies: current state and future developments. Conf Pap Sci 2013:e690627. https://doi.org/10.1155/2013/690627CrossRef

16.

Megía PJ, Vizcaíno AJ, Calles JA, Carrero A (2021) Hydrogen production technologies: from fossil fuels toward renewable sources. Mini Rev Energy Fuels 35(20):16403–16415. https://doi.org/10.1021/acs.energyfuels.1c02501CrossRef

17.

Chen L, Qi Z, Zhang S, Su J, Somorjai GA (2020) Catalytic hydrogen production from methane: a review on recent progress and prospect. Catalysts 10(8):858. https://doi.org/10.3390/catal10080858CrossRef

18.

Basile A, Liguori S, Iulianelli A (2015) 2-membrane reactors for methane steam reforming (MSR). In: Basile A, Di Paola L, Hai Fl, Piemonte V (eds) Membrane reactors for energy applications and basic chemical production. Woodhead Publishing Series in Energy, Woodhead Publishing, pp 31–59. https://doi.org/10.1016/B978-1-78242-223-5.00002-9

19.

Velazquez Abad A, Dodds PE (2017) Production of hydrogen. In: Abraham MA (ed) Encyclopedia of sustainable technologies. Elsevier, Oxford, pp 293–304. https://doi.org/10.1016/B978-0-12-409548-9.10117-4

20.

Liu K, Song C, Subramani V (2009) Hydrogen and syngas production and purification technologies. John Wiley & Sons

21.

Chadwick MJ, Highton NH, Lindman N (eds) (1987) 6-Coal conversion technologies. In environmental impacts of coal mining & utilization. Amsterdam, Pergamon, pp 105–155. https://doi.org/10.1016/B978-0-08-031427-3.50015-3

22.

Treese SA (2015) Hydrogen production and management for petroleum processing. In: Treese SA, Jones DS, Pujado PR (eds) Handbook of petroleum processing. Springer International Publishing, Cham, pp 1–67. https://doi.org/10.1007/978-3-319-05545-9_12-2

23.

Ohta T (ed) (1979) Chapter 3-water electrolysis. In: Solar-hydrogen energy systems. Pergamon, pp 35–58. https://doi.org/10.1016/B978-0-08-022713-9.50009-4

24.

Padhi SK, Rai S, Akhter SS (2020) Redox-induced structural switching through sporadic pyridine-bridged CoIIcoII dimer and electrocatalytic proton reduction. Inorg Chem 59(11):7810–7821. https://doi.org/10.1021/acs.inorgchem.0c00911CrossRef

25.

Alternative Fuels Data Center: Hydrogen production and distribution. https://afdc.energy.gov/fuels/hydrogen_production.html. Accessed 14 Oct 2022

26.

Zhu C, Liu C, Fu Y, Gao J, Huang H, Liu Y, Kang Z (2019) Construction of CDs/CdS photocatalysts for stable and efficient hydrogen production in water and seawater. Appl Catal B Environ 242:178–185. https://doi.org/10.1016/j.apcatb.2018.09.096CrossRef

27.

Sen R, Das S, Nath A, Maharana P, Kar P, Verpoort F, Liang P, Roy S (2022) Electrocatalytic water oxidation: an overview with an example of translation from lab to market. Front Chem 10

28.

Sapountzi FM, Gracia JM, Weststrate CJ (2017) Kees-J, Fredriksson HOA, Niemantsverdriet JW (Hans) Electrocatalysts for the generation of hydrogen, oxygen and synthesis gas. Prog Energy Combust Sci 58:1–35. https://doi.org/10.1016/j.pecs.2016.09.001

29.

Naimi Y, Antar A, Naimi Y, Antar A (2018) Hydrogen generation by water electrolysis. IntechOpen. https://doi.org/10.5772/intechopen.76814

30.

Artero V, Fontecave M (2005) Some general principles for designing electrocatalysts with hydrogenase activity. Coord Chem Rev 249(15):1518–1535. https://doi.org/10.1016/j.ccr.2005.01.014CrossRef

31.

Potential-dependent electrocatalytic pathways: controlling reactivity with pKa for mechanistic investigation of a nickel-based hydrogen evolution catalyst. J Am Chem Soc. https://pubs.acs.org/doi/https://doi.org/10.1021/jacs.5b08297. Accessed 10 Oct 2022

32.

Elgrishi N, Kurtz DA, Dempsey JL (2017) Reaction parameters influencing cobalt hydride formation kinetics: implications for benchmarking H2-evolution catalysts. J Am Chem Soc 139(1):239–244. https://doi.org/10.1021/jacs.6b10148CrossRef

33.

Rountree ES, Dempsey JL (2016) Reactivity of proton sources with a nickel hydride complex in acetonitrile: implications for the study of fuel-forming catalysts. Inorg Chem 55(10):5079–5087. https://doi.org/10.1021/acs.inorgchem.6b00885CrossRef

34.

Khan MA, Zhao H, Zou W, Chen Z, Cao W, Fang J, Xu J, Zhang L, Zhang J (2018) Recent progresses in electrocatalysts for water electrolysis. Electrochem Energy Rev 1(4):483–530. https://doi.org/10.1007/s41918-018-0014-zCrossRef

35.

Wang S, Lu A, Zhong C-J (2021) Hydrogen production from water electrolysis: role of catalysts. Nano Converg 8(1):4. https://doi.org/10.1186/s40580-021-00254-xCrossRef

36.

Sherman BD, Sheridan MV, Wee K-R, Song N, Dares CJ, Fang Z, Tamaki Y, Nayak A, Meyer TJ (2016) Analysis of homogeneous water oxidation catalysis with collector-generator cells. Inorg Chem 55(2):512–517. https://doi.org/10.1021/acs.inorgchem.5b02182CrossRef

37.

Suryanto BHR, Wang Y, Hocking RK, Adamson W, Zhao C (2019) Overall electrochemical splitting of water at the heterogeneous interface of nickel and iron oxide. Nat Commun 10(1):5599. https://doi.org/10.1038/s41467-019-13415-8CrossRef

38.

Zaccaria F, Menendez Rodriguez G, Rocchigiani L, Macchioni A (2022) Molecular catalysis in “green” hydrogen production. Front Catal 2

39.

Khandelwal S, Zamader A, Nagayach V, Dolui D, Mir AQ, Dutta A (2019) Inclusion of peripheral basic groups activates dormant cobalt-based molecular complexes for catalytic H2 evolution in water. ACS Catal 9(3):2334–2344. https://doi.org/10.1021/acscatal.8b04640CrossRef

40.

Razavet M, Artero V, Fontecave M (2005) Proton electroreduction catalyzed by cobaloximes: functional models for hydrogenases. Inorg Chem 44(13):4786–4795. https://doi.org/10.1021/ic050167zCrossRef

41.

Dolui D, Khandelwal S, Majumder P, Dutta A (2020) The odyssey of cobaloximes for catalytic H2 production and their recent revival with enzyme-inspired design. Chem Commun 56(59):8166–8181. https://doi.org/10.1039/D0CC03103HCrossRef

42.

Stubbert BD, Peters JC, Gray HB (2011) Rapid water reduction to H2 catalyzed by a cobalt bis(iminopyridine) complex. J Am Chem Soc 133(45):18070–18073. https://doi.org/10.1021/ja2078015CrossRef

43.

Roberts JAS, Bullock RM (2013) Direct determination of equilibrium potentials for hydrogen oxidation/production by open circuit potential measurements in acetonitrile. Inorg Chem 52(7):3823–3835. https://doi.org/10.1021/ic302461qCrossRef

44.

Dolui D, Das S, Bharti J, Kumar S, Kumar P, Dutta A (2020) Bio-inspired cobalt catalyst enables natural-sunlight-driven hydrogen production from aerobic neutral aqueous solution. Cell Rep Phys Sci 1(1):100007. https://doi.org/10.1016/j.xcrp.2019.100007CrossRef

45.

Dolui D, Mir AQ, Dutta A (2020) Probing the peripheral role of amines in photo- and electrocatalytic H2 production by molecular cobalt complexes. Chem Commun 56(94):14841–14844. https://doi.org/10.1039/D0CC05786JCrossRef

46.

Dolui D, Khandelwal S, Shaik A, Gaat D, Thiruvenkatam V, Dutta A (2019) Enzyme-inspired synthetic proton relays generate fast and acid-stable cobalt-based H2 production electrocatalysts. ACS Catal 9(11):10115–10125. https://doi.org/10.1021/acscatal.9b02953CrossRef

47.

Mir AQ, Saha S, Mitra S, Guria S, Majumder P, Dolui D, Dutta A (2022) The rational inclusion of vitamin b6 boosts artificial cobalt complex catalyzed green H2 production. Sustain Energy Fuels 6(18):4160–4168. https://doi.org/10.1039/D2SE00734GCrossRef

48.

Berben LA, Peters JC (2010) Hydrogen evolution by cobalt tetraimine catalysts adsorbed on electrode surfaces. Chem Commun 46(3):398–400. https://doi.org/10.1039/B921559JCrossRef

49.

Kandemir B, Kubie L, Guo Y, Sheldon B, Bren KL (2016) Hydrogen evolution from water under aerobic conditions catalyzed by a cobalt ATCUN metallopeptide. Inorg Chem 55(4):1355–1357. https://doi.org/10.1021/acs.inorgchem.5b02157CrossRef

50.

Kandemir B, Chakraborty S, Guo Y, Bren KL (2016) Semisynthetic and biomolecular hydrogen evolution catalysts. Inorg Chem 55(2):467–477. https://doi.org/10.1021/acs.inorgchem.5b02054CrossRef

51.

Firpo V, Le JM, Pavone V, Lombardi A, Bren KL (2018) Hydrogen evolution from water catalyzed by cobalt-mimochrome VI*a, a synthetic mini-protein. Chem Sci 9(45):8582–8589. https://doi.org/10.1039/C8SC01948GCrossRef

52.

Kleingardner JG, Kandemir B, Bren KL (2014) Hydrogen evolution from neutral water under aerobic conditions catalyzed by cobalt microperoxidase-11. J Am Chem Soc 136(1):4–7. https://doi.org/10.1021/ja406818hCrossRef

53.

Eckenhoff WT, Eisenberg R (2012) Molecular systems for light driven hydrogen production. Dalton Trans 41(42):13004–13021. https://doi.org/10.1039/C2DT30823A

54.

Andreiadis ES, Chavarot-Kerlidou M, Fontecave M, Artero V (2011) Artificial photosynthesis: from molecular catalysts for light-driven water splitting to photoelectrochemical cells. Photochem Photobiol 87(5):946–964. https://doi.org/10.1111/j.1751-1097.2011.00966.xCrossRef

55.

Dempsey JL, Brunschwig BS, Winkler JR, Gray HB (2009) Hydrogen evolution catalyzed by cobaloximes. Acc Chem Res 42(12):1995–2004. https://doi.org/10.1021/ar900253eCrossRef

56.

Abrahamse H, Hamblin MR (2016) New photosensitizers for photodynamic therapy. Biochem J 473(4):347–364. https://doi.org/10.1042/BJ20150942CrossRef

57.

Strieth-Kalthoff F, James MJ, Teders M, Pitzer L, Glorius F (2018) Energy transfer catalysis mediated by visible light: principles, applications, directions. Chem Soc Rev 47(19):7190–7202. https://doi.org/10.1039/C8CS00054A

58.

Goldsmith JI, Hudson WR, Lowry MS, Anderson TH, Bernhard S (2005) Discovery and high-throughput screening of heteroleptic iridium complexes for photoinduced hydrogen production. J Am Chem Soc 127(20):7502–7510. https://doi.org/10.1021/ja0427101CrossRef

59.

Visible light-driven hydrogen production from aqueous protons catalyzed by molecular cobaloxime catalysts. Inorganic Chem. https://pubs.acs.org/doi/full/https://doi.org/10.1021/ic900389z. Accessed 14 Oct 2022

60.

Zhang P, Wang M, Na Y, Li X, Jiang Y, Sun L (2010) Homogeneous photocatalytic production of hydrogen from water by a bioinspired [Fe 2 S 2 ] catalyst with high turnover numbers. Dalton Trans 39(5):1204–1206. https://doi.org/10.1039/B923159PCrossRef

61.

Mir AQ, Joshi G, Ghosh P, Khandelwal S, Kar A, Hegde R, Khatua S, Dutta A (2019) Plasmonic gold nanoprism-cobalt molecular complex dyad mimics photosystem-II for visible–NIR illuminated neutral water oxidation. ACS Energy Lett 4(10):2428–2435. https://doi.org/10.1021/acsenergylett.9b01683CrossRef

62.

Joshi G, Mir AQ, Layek A, Ali A, Aziz SkT, Khatua S, Dutta A (2022) Plasmon-based small-molecule activation: a new dawn in the field of solar-driven chemical transformation. ACS Catal 1052–1067. https://doi.org/10.1021/acscatal.1c05245

63.

Joshi G, Saha A, Dutta A, Khatua S (2022) NIR-driven photocatalytic hydrogen production by silane-and tertiary amine-bound plasmonic gold nanoprisms. ACS Appl Mater Interfaces 14(34):38815–38823. https://doi.org/10.1021/acsami.2c10152CrossRef

64.

Tong L, Duan L, Zhou A, Thummel RP (2020) First-row transition metal polypyridine complexes that catalyze proton to hydrogen reduction. Coord Chem Rev 402:213079. https://doi.org/10.1016/j.ccr.2019.213079CrossRef

65.

Zhang P, Wang M, Li C, Li X, Dong J, Sun L (2009) Photochemical H2 production with noble-metal-free molecular devices comprising a porphyrin photosensitizer and a cobaloxime catalyst. Chem Commun 46(46):8806–8808. https://doi.org/10.1039/C0CC03154BCrossRef

66.

Natali M, Argazzi R, Chiorboli C, Iengo E, Scandola F (2013) Photocatalytic hydrogen evolution with a self-assembling reductant–sensitizer–catalyst system. Chem Eur J 19(28):9261–9271. https://doi.org/10.1002/chem.201300133

67.

Mir AQ, Dolui D, Khandelwal S, Bhatt H, Kumari B, Barman S, Kanvah S, Dutta A (2019) Developing photosensitizer-cobaloxime hybrids for solar-driven H2 production in aqueous aerobic conditions. JoVE J Vis Exp 152:e60231. https://doi.org/10.3791/60231

68.

Lubitz W, Ogata H, Rüdiger O, Reijerse E (2014) Hydrogenases. Chem Rev 114(8):4081–4148. https://doi.org/10.1021/cr4005814CrossRef

69.

Lee H-S, Vermaas WFJ, Rittmann BE (2010) Biological hydrogen production: prospects and challenges. Trends Biotechnol 28(5):262–271. https://doi.org/10.1016/j.tibtech.2010.01.007CrossRef

70.

Ahmed SF, Rafa N, Mofijur M, Badruddin IA, Inayat A, Ali MS, Farrok O, Yunus Khan TM (2021) Biohydrogen production from biomass sources: metabolic pathways and economic analysis. Front Energy Res 9

71.

Lamb JJ, Lien KM (2020) Chapter | Seven-promising selected biohydrogen solutions. In: Lamb JJ, Pollet BG (eds) Hydrogen, biomass and bioenergy. Hydrogen and Fuel Cells Primers, Academic Press, pp 119–132. https://doi.org/10.1016/B978-0-08-102629-8.00007-4

72.

Sampath P, Brijesh, Reddy KR, Reddy CV, Shetti NP, Kulkarni RV, Raghu AV (2020) Biohydrogen production from organic waste–a review. Chem Eng Technol 43(7):1240–1248. https://doi.org/10.1002/ceat.201900400

73.

Liu Y, Min J, Feng X, He Y, Liu J, Wang Y, He J, Do H, Sage V, Yang G, Sun Y (2020) A review of biohydrogen productions from lignocellulosic precursor via dark fermentation: perspective on hydrolysate composition and electron-equivalent balance. Energies 13(10):2451. https://doi.org/10.3390/en13102451CrossRef

Titel: Sustainable Pathways for Hydrogen Production via Molecular Catalysts
verfasst von: Mahendra Kumar Awasthi
Surabhi Rai
Arnab Dutta
Verlag: Springer Nature Singapore
Buch: Climate Action and Hydrogen Economy
Print ISBN: 978-981-9962-36-5

Electronic ISBN: 978-981-9962-37-2

Copyright-Jahr: 2024
DOI: https://doi.org/10.1007/978-981-99-6237-2_12