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Journal of Polymer Research

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01.08.2023 | Original Paper

Wettability studies of layer-by-layer films of Nafion/ Polyethylenemine/SiO₂ nanoparticles

verfasst von: Choonghyun Sung, Minhyuk Kang

Erschienen in: Journal of Polymer Research | Ausgabe 8/2023

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Abstract

Biological systems with special wettability have attracted significant interest as superwetting surfaces. Recently, there has been a growing interest in unusual oleophobic/hydrophilic surfaces that exhibit high oil contact angle (OCA) and low water contact angle (WCA). Although these surfaces demonstrate potential applications in water/oil separation, detergent-free cleaning, and oil-repellent anti-fogging, their fabrication is challenging because of the lower surface tension of oil than that of water. In this study, we prepared layer-by-layer (LbL) films consist of Nafion (NAF), branched polyethyleneimine (PEI), and SiO₂ nanoparticles, and studied the effect of the LbL assembly condition on film growth and water/oil wettability. Typical WCA and OCA values of NAF/PEI film were ~128° and ~21°, respectively. The WCA and OCA changed as the SiO₂ nanoparticles were added and the films were treated with perfluorooctane sulfonate. When the WCA and OCA difference was the smallest, the WCA and OCA values of the NAF/PEI/ SiO₂ film were 121° and 91°, respectively. Furthermore, we prepared two-layer LbL films by coating NAF/PEI/SiO₂ films onto porous LbL films. As the PFOS-terminated NAF/PEI/SiO₂ film were deposited, the WCA decreased from 119 to 78°, and the OCA was fairly constant at 108°, showing a reversal of the WCA and OCA values. We expect that this study will provide a better understanding of the fabrication of LbL-assembled oleophobic/hydrophilic surface.

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Titel: Wettability studies of layer-by-layer films of Nafion/ Polyethylenemine/SiO2 nanoparticles
verfasst von: Choonghyun Sung
Minhyuk Kang
Publikationsdatum: 01.08.2023
Verlag: Springer Netherlands
Erschienen in: Journal of Polymer Research / Ausgabe 8/2023
Print ISSN: 1022-9760
Elektronische ISSN: 1572-8935
DOI: https://doi.org/10.1007/s10965-023-03719-1

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