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01.11.2023 | Original Paper

Ambidextrous polyanthracene/poly(ethylene glycol) copolymer for high capacity silicon anode in Li-ion batteries

verfasst von: Omer Suat Taskin, Neslihan Yuca, Joan Papavasiliou, George Avgouropoulos, Erhan Karabayir, Mehmet Emre Cetintasoglu, Emre Guney, Ilknur Kalafat, Busra Cetin, Emre Guzel, Osman Urper, Kaiying Wang

Erschienen in: Journal of Polymer Research | Ausgabe 11/2023

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Abstract

The demand for lithium-ion batteries has dramatically increased in the last decade. However, the battery life offered by suppliers does not the level that can adequately meet the needs of end users. The development of new generation materials is so crucial accordingly. The nano-sized silicon with high theoretical capacity as the anode active material is one of the most promising sources, however, there are some problems (volume expansion) need to be solved in the use of silicon. In this study, a new generation polymer binder containing conjugated anthracene units, which gives conductivity and ethylene glycol lateral groups as another segment of the polymer backbone, which allows volumetric expansion with its flexibility has been developed. After preparing an electrode with silicon and developed conductive polymer binder (9:1) without adding any conductive additive, 800 mAh/g specific capacity is acquired after 400^th cycle. It is thought that the obtained results will create an important infrastructure for the new generation conductive and flexible polymer binders for LIBs.

Vorheriger Artikel Development of cornstarch-based shear thickening fluid and characterization of the effects of the addition of halloysite nanotubes-silica hybrid reinforcements

Nächster Artikel Synthesis of a novel siloxane-based crosslink agent and its application in emulsion copolymerization of butyl acrylate and methyl methacrylate

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Titel: Ambidextrous polyanthracene/poly(ethylene glycol) copolymer for high capacity silicon anode in Li-ion batteries
verfasst von: Omer Suat Taskin
Neslihan Yuca
Joan Papavasiliou
George Avgouropoulos
Erhan Karabayir
Mehmet Emre Cetintasoglu
Emre Guney
Ilknur Kalafat
Busra Cetin
Emre Guzel
Osman Urper
Kaiying Wang
Publikationsdatum: 01.11.2023
Verlag: Springer Netherlands
Erschienen in: Journal of Polymer Research / Ausgabe 11/2023
Print ISSN: 1022-9760
Elektronische ISSN: 1572-8935
DOI: https://doi.org/10.1007/s10965-023-03804-5

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