nach oben

Journal of Polymer Research

Erschienen in:

01.11.2023 | Original Paper

Preparation of polyaniline@graphene nanocomposite with oxidative polymerization of pre-assembled of aniline for supercapacitor electrodes

verfasst von: Aiping Zhu, Jiawen Zhang, Boyi Situ, Yushun Ma, Zhibin Ji, Zhengkang Peng, Zihan Yan, Yusong Tu

Erschienen in: Journal of Polymer Research | Ausgabe 11/2023

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config

KI-gestützte Suche

Aus

Abstract

In this study, we report a facile strategy to prepare polyaniline and graphene nanopieces (PANI@GNP) nanocomposite by the oxidative polymerization of the aniline pre-assembled on the GNP surface. The morphology, chemical structure and interfacial interaction of the synthesized samples were characterized by scanning electron microscopy (SEM), transmission electron microscopy (TEM), Raman and x-ray photoelectron spectroscopy (XPS). The resulting PANI@GNP nanocomposite with a 0.33:1 mass ratio of PANI to GNP, has a large specific surface area, electron doping interface, excellent conductivity and reversible redox activity. The PANI@GNP symmetrical supercapacitor with the unique π-π electronic interaction demonstrates 351.7 F/g of specific capacitance; 57.5% of the rate property when the the current density increases from 1 to 10 A/g; the capacity retained 80% of the initial value in constant current charge–discharge mode (at the current density of 10 A/g) after 2000 cycles. This scalable preparation process makes PANI@GNP nanocomposite promising application in electrochemical devices.

Vorheriger Artikel An atomistic molecular dynamic model to study the properties of LLDPE and wax

Nächster Artikel Artificial intelligence-based optimization for ring-opening metathesis polymerization of proton exchange membrane

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

über 102.000 Bücher
über 537 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Finance + Banking
Management + Führung
Marketing + Vertrieb
Maschinenbau + Werkstoffe
Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

über 67.000 Bücher
über 390 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Maschinenbau + Werkstoffe

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Nur mit Berechtigung zugänglich

Gao F, Mu J, Bi Z, Wang S, Li Z (2021) Recent advances of polyaniline composites in anticorrosive coatings: A review[J]. Prog Org Coat 151:106071. https://doi.org/10.1016/j.porgcoat.2020.106071CrossRef

Tian Z, Yu H, Wang L, Muhammad S, Ren F, Ren P, Chen Y, Sun R, Sun Y, Huang L (2014) Recent progress in the preparation of polyaniline nanostructures and their applications in anticorrosive coatings. RSC Adv 54:28195–28208. https://doi.org/10.1039/C4RA03146F

Wang J, Zheng R, Chen Y, Bai H, Zhang T (2020) Superacid-doped polyaniline as a soluble polymeric active electrolyte for supercapacitors. Soft Matter 16(31):7305–7311. https://doi.org/10.1039/d0sm00847hCrossRefPubMed

Rahman M, Joy P, Uddin M, Mukhlish M, Khan M (2021) Improvement of capacitive performance of polyaniline based hybrid supercapacitor. Heliyon 7(7):e07407. https://doi.org/10.1016/J.HELIYON.2021.E07407CrossRefPubMedPubMedCentral

Mahalakshmi S, Sridevi V (2021) In Situ Electrodeposited Gold Nanoparticles on Polyaniline-Modified Electrode Surface for the Detection of Dopamine in Presence of Ascorbic Acid and Uric Acid. Electrocatalysis 12(4):415–435. https://doi.org/10.1007/S12678-021-00665-8CrossRef

Vanitha C, Sanmugam A, Yogananth A, Rajasekar M, Kuppusamy PG, Devasagayam G (2022) A facile synthesis of polyaniline-WO3 hybrid nanocomposite for enhanced dopamine detection. Mater Lett 328(1):133149. https://doi.org/10.1016/J.MATLET.2022.133149CrossRef

Rui M, Zhu A (2021) The synthesis and corrosion protection mechanisms of PANI/CNT nanocomposite doped with organic phosphoric acid. Prog Org Coat 153:106134. https://doi.org/10.1016/J.PORGCOAT.2021.106134CrossRef

Mu S (2011) Synthesis of poly(aniline-co-5-aminosalicylic acid) and its properties. Synth Met 161(13–14):1306–1312. https://doi.org/10.1016/j.synthmet.2011.04.028CrossRef

Mu S (2010) Nanostructured polyaniline synthesized using interface polymerization and its redox activity in a wide pH range. Synth Met 160(17–18):1931–1937. https://doi.org/10.1016/j.synthmet.2010.07.012CrossRef

10.

Zhu A, Wang H, Zhang C, Rui M, Zhou C, Chen C (2017) A facile, solvent-free and scalable method to prepare poly(aniline-co-5-aminosalicylic acid) with enhanced electrochemical activity for corrosion protection. Prog Org Coat 112:109–117. https://doi.org/10.1016/j.porgcoat.2017.07.006CrossRef

11.

Zhu A, Wang H, Zhang C (2018) In situ synthesis of graphene/poly(aniline-Co-5-aminosalicylic acid) nanocomposites toward improved electroactivity. Polym Compos 39(8):2915–2921. https://doi.org/10.1002/pc.24288CrossRef

12.

Mahalakshmi S, Sridevi V (2019) Conducting, crystalline and electroactive polyaniline-Au nanocomposites through combined acid and oxidative doping pathways for biosensing applications: Detection of dopamine. Mater Chem Phys 235:121728–121728. https://doi.org/10.1016/j.matchemphys.2019.121728CrossRef

13.

Kumar A, Kumar V, Awasthi K (2018) Polyaniline-Carbon Nanotube Composites: Preparation Methods. Properties, and Applications, Polymer-Plastics Technology and Engineering 57(2):70–97. https://doi.org/10.1080/03602559.2017.1300817CrossRef

14.

Rajyalakshmi T, Pasha A, Khasim S, Lakshmi M, Murugendrappa MV, Badi N (2020) Enhanced Charge Transport and Corrosion Protection Properties of Polyaniline-Carbon Nanotube Composite Coatings on Mild Steel. J Electron Mater 49(1):341–352. https://doi.org/10.1007/s11664-019-07783-6CrossRef

15.

Singh P, Shukla SK (2020) Advances in polyaniline-based nanocomposites. J Mater Sci 55(4):1331–1365. https://doi.org/10.1007/s10853-019-04141-zCrossRef

16.

Huang Y, Zhang B, Wu J, Hong R, Xu J (2022) Preparation and Characterization of Graphene Oxide/Polyaniline/Polydopamine Nanocomposites towards Long-Term Anticorrosive Performance of Epoxy Coatings. Polymers 14(16):3355–3355. https://doi.org/10.3390/POLYM14163355CrossRefPubMedPubMedCentral

17.

Zhang J, Zhu A (2021) Study on the synthesis of PANI/CNT nanocomposite and its anticorrosion mechanism in waterborne coatings. Prog Org Coat 156:106447. https://doi.org/10.1016/J.PORGCOAT.2021.106447CrossRef

18.

Babel V, Hiran BL (2021) A review on polyaniline composites: Synthesis, characterization, and applications. Polym Compos 42(7):3142–3157. https://doi.org/10.1002/PC.26048CrossRef

19.

Huang Z, Li L, Wang Y, Zhang C, Liu T (2018) Polyaniline/graphene nanocomposites towards high-performance supercapacitors: A review. Compos Commun 8:83–91. https://doi.org/10.1016/j.coco.2017.11.005CrossRef

20.

Kausar A (2022) Polyaniline/graphene nanoplatelet nanocomposite towards high-end features and applications. Mater Res Innovations 26(4):249–261. https://doi.org/10.1080/14328917.2021.1934281CrossRef

21.

Wang T, Yu J, Wang M, Cao Y, Dai W, Shen D, Guo L, Wu Y, Bai H, Dai D, Lyu J, Jiang N, Pan C, Lin C (2017) Effect of different sizes of graphene on thermal transport performance of graphene paper. Compos Commun 5:46–53. https://doi.org/10.1016/j.coco.2017.07.001CrossRef

22.

Stoller MD, Park S, Zhu Y, An J, Ruoff RS (2008) Graphene-based ultracapacitors. Nano Lett 8(10):3498–3502. https://doi.org/10.1021/nl802558y

23.

Okhay O, Tkach A (2022) Polyaniline-Graphene Electrodes Prepared by Electropolymerization for High-Performance Capacitive Electrodes: A Brief Review. Batteries 8(10):191–191. https://doi.org/10.3390/BATTERIES8100191CrossRef

24.

Li J, Ren J, Xu Y, Ji H, Zou X (2019) Facile synthesis and characterization of three-dimensional graphene/polyaniline composites with enhanced electrochemical properties. J Mater Sci Mater Electron 30(7):6650–6659. https://doi.org/10.1007/s10854-019-00974-1CrossRef

25.

Wang Z, Jiang L, Wei Y, Zong C (2020) In-situ polymerization to prepare reduced graphene oxide/polyaniline composites for high performance supercapacitors. J Energy Storage 32:101742. https://doi.org/10.1016/j.est.2020.101742

26.

Park J, Yang X, Wickramasinghe D, Sundhoro M, Orbey N, Chow K-F, Yan M (2020) Functionalization of pristine graphene for the synthesis of covalent graphene–polyaniline nanocomposite. RSC Adv 10(44):26486–26493. https://doi.org/10.1039/d0ra03579c

27.

Li. Y, Zheng Y (2018) Preparation and electrochemical properties of polyaniline/reduced graphene oxide composites. J Appl Polym Sci 135(16):46103–46103. https://doi.org/10.1002/app.46103

28.

Jafari Y, Ghoreishi SM, Shabani-Nooshabadi M (2016) Electrochemical deposition and characterization of polyaniline-graphene nanocomposite films and its corrosion protection properties. J Polym Res 23(5). https://doi.org/10.1007/s10965-016-0983-8

29.

Lv F, Xiong S, Wang X, Chu J, Zhang R, Gong M, Wu B, Li Z, Zhu C, Yang Z, Yang C (2021) Electrochemical fabrication of polyaniline/graphene paper (PANI/GP) supercapacitor electrode materials on free-standing flexible graphene paper. High Perform Polym 33(10):1124–1131. https://doi.org/10.1177/09540083211023128CrossRef

30.

Hong XD, Fu JW, Liu Y (2019) Recent Progress on Graphene/Polyaniline Composites for High-performance Supercapacitors. Materials 12:1451. https://doi.org/10.3390/ma12091451

31.

Hameem H, Irfan SW, Samina H (2022) High performance nanostructured symmetric reduced graphene oxide/polyaniline supercapacitor electrode: effect of polyaniline morphology. Journal of Energy Storage 55(25):105–723. https://doi.org/10.1016/j.est.2022.105732CrossRef

32.

Fu HY, Gao B, Li JH et al (2023) Honeycomb graphene-polyaniline nanocomposites as novel electrode materials for high-performance supercapacitors. New J Chem 47:11001–11014. https://doi.org/10.1039/D3NJ01332D

33.

Xu GH, Wang N, Wei JY et al (2012) Preparation of Graphene Oxide/Polyaniline Nanocomposite with Assistance of Supercritical Carbon Dioxide for Supercapacitor Electrodes Ind. Eng Chem Res 51:14390–14398. https://doi.org/10.1021/ie301734f

34.

Kresse G, Hafner J (1994) Ab initio molecular-dynamics simulation of the liquid-metal–amorphous-semiconductor transition in germanium. Phys Rev B 49(20):14251–14269. https://doi.org/10.1103/physrevb.49.14251

35.

Kresse G, Furthmüller J (1996) Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set. Phys Rev B 54(16):11169–11186. https://doi.org/10.1103/physrevb.54.11169CrossRef

36.

Blöchl PE (1994) Projector augmented-wave method. Phys Rev B 50(24):17953–17979. https://doi.org/10.1103/PhysRevB.50.17953CrossRef

37.

Perdew JP, Burke K, Ernzerhof M (1996) Generalized gradient approximation made simple. Phys Rev Lett 77(18):3865–3868. https://doi.org/10.1103/physrevlett.77.3865CrossRefPubMed

38.

Grimme S, Antony J, Ehrlich S, Krieg H (2010) A consistent and accurate ab initio parametrization of density functional dispersion correction (DFT-D) for the 94 elements H-Pu. J Chem Phys 132(15):154104. https://doi.org/10.1063/1.3382344CrossRefPubMed

39.

Sharma A, Goyal PK, Rawal I, Rajpal A, Khokhar A, Kumar V, Dahiya S (2022) Structural characteristics and opto-electrical properties of in-situ synthesized polyaniline films. Opt Mater 131:112712. https://doi.org/10.1016/J.OPTMAT.2022.112712CrossRef

40.

Haba Y, Segal E, Narkis M, Titelman GI, Siegmann A (1999) Polymerization of aniline in the presence of DBSA in an aqueous dispersion. Synth Met 106(1):59–66. https://doi.org/10.1016/S0379-6779(99)00100-9CrossRef

41.

Zhu A, Shi P, Sun S, Rui M (2019) Construction of rGO/Fe₃O₄/PANI nanocomposites and its corrosion resistance mechanism in waterborne acrylate-amino coating. Prog Org Coat 133:117–124. https://doi.org/10.1016/j.porgcoat.2019.04.011CrossRef

42.

Cai K, Zuo S, Luo SP, Yao C, Liu W, Ma J, Mao H, Li Z (2016) Preparation of polyaniline/graphene composites with excellent anti-corrosion properties and their application in waterborne polyurethane anticorrosive coatings. RSC Adv 98:95965–95972. https://doi.org/10.1039/C6RA19618GCrossRef

43.

Fan H, Zhao N, Wang H, Xu J, Pan F (2014) 3D conductive network based free-standing PANI/RGO/MWNTs hybrid film for high performance flexible supercapacitor. J Mater Chem A 2(31):12340–12347. https://doi.org/10.1039/C4TA02118ECrossRef

44.

Wang JD, Peng TJ, Xian HY, Sun HJ (2015) Preparation and supercapacitive performance of three dimensional reduced graphene oxide/polyaniline composite. Acta Phys Chim Sin 31(1):90–98. https://doi.org/10.1039/C4TA02118E

45.

Yang C, Zhang LL, Hu NT et al (2017) Rational design of sandwiched polyaniline nanotube/layered graphene/polyaniline nanotube papers for high-volumetric supercapacitors. Chem Eng J 309:89–97. https://doi.org/10.1016/j.cej.2016.09.115

46.

Chu XY, Huang TQ, Hu YQ et al (2020) Wet-spinning assembly of nitrogen-doped graphene film for stable graphene-polyaniline supercapacitor electrodes with high mass loading. Sci China Mater 63(10):1889–1897. https://doi.org/10.1007/s40843-019-9436-1

47.

Liu ML, Long X, Tang HY et al (2022) The formation of uniform graphene-polyaniline hybrids using a completely miscible cosolvent that have an excellent electrochemical performance. New Carbon Mater 37(2):381–391CrossRef

Titel: Preparation of polyaniline@graphene nanocomposite with oxidative polymerization of pre-assembled of aniline for supercapacitor electrodes
verfasst von: Aiping Zhu
Jiawen Zhang
Boyi Situ
Yushun Ma
Zhibin Ji
Zhengkang Peng
Zihan Yan
Yusong Tu
Publikationsdatum: 01.11.2023
Verlag: Springer Netherlands
Erschienen in: Journal of Polymer Research / Ausgabe 11/2023
Print ISSN: 1022-9760
Elektronische ISSN: 1572-8935
DOI: https://doi.org/10.1007/s10965-023-03794-4

Premium Partner

Marktübersichten

Die im Laufe eines Jahres in der „adhäsion“ veröffentlichten Marktübersichten helfen Anwendern verschiedenster Branchen, sich einen gezielten Überblick über Lieferantenangebote zu verschaffen.

Zur Marktübersicht

Springer Professional

Abstract

Bitte loggen Sie sich ein, um Zugang zu Ihrer Lizenz zu erhalten.

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Springer Professional "Technik"

Weitere Artikel der Ausgabe 11/2023

Enzymatic synthesis of polypeptides in natural deep eutectic solvents

Impact of polymer particle purification on the structural and catalytic properties of in situ generated gold nanoparticles

An atomistic molecular dynamic model to study the properties of LLDPE and wax

The thermal stability and flame retardant effect of Al(OH)3 on NBR containing intumescent flame retardant

Development of cornstarch-based shear thickening fluid and characterization of the effects of the addition of halloysite nanotubes-silica hybrid reinforcements

Ambidextrous polyanthracene/poly(ethylene glycol) copolymer for high capacity silicon anode in Li-ion batteries

Premium Partner

Marktübersichten