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Journal of Polymer Research
Erschienen in: Journal of Polymer Research 4/2024

01.04.2024 | Original Paper

Efficient TEMPO functionalized temperature response nanoreactors: recoverable hydrophobic pockets for aerobic oxidation of alcohols in water

verfasst von: Xianbo Shen, Ji Wang, Xiaoyu Li, Xiaoping Jiang, Jie Cheng, Weihua Han, You Peng

Erschienen in: Journal of Polymer Research | Ausgabe 4/2024

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Abstract

With the growing popularity of "green chemistry," the selective oxidation of alcohols using water as a reaction medium and oxygen as an oxidant has increased significantly in the last few years. However, the solubility of organic substances and oxygen in water is relatively poor and generates such a large mass transfer resistance, which seriously reduces the efficiency of aqueous phase reaction. This work employed the construction of TEMPO nanoreactors based on thermoresponsive polymers to lower mass transfer resistance and promote the selective oxidation of alcohol. Compared with free TEMPO, it was discovered that the tethered organocatalyst's reactivity in water under air atmosphere was extraordinarily high within the nanostructure. Moreover, the nanoreactors can be easily recovered by increasing the temperature after the reaction, which can recycle up to five times while still being highly active. This work would offer some fresh perspectives on carrying out environmentally friendly reactions and demonstrate an inventive method for multiphase reaction intensification.
Vorheriger Artikel PVDF crystalline phases revisited: a first-principles computational study using the PBE-D3 functional
Nächster Artikel Isolation of microcrystalline cellulose from Musa paradisiaca (banana) plant leaves: physicochemical, thermal, morphological, and mechanical characterization for lightweight polymer composite applications

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Metadaten
Titel
Efficient TEMPO functionalized temperature response nanoreactors: recoverable hydrophobic pockets for aerobic oxidation of alcohols in water
verfasst von
Xianbo Shen
Ji Wang
Xiaoyu Li
Xiaoping Jiang
Jie Cheng
Weihua Han
You Peng
Publikationsdatum
01.04.2024
Verlag
Springer Netherlands
Erschienen in
Journal of Polymer Research / Ausgabe 4/2024
Print ISSN: 1022-9760
Elektronische ISSN: 1572-8935
DOI
https://doi.org/10.1007/s10965-024-03952-2

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