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15.03.2023 | Original Research Article

A Nanosized Manganese-Based Chalcogenide Composite for Enhanced Electrocatalytic OER

verfasst von: F. F. Alharbi, Hafiz Muhammad Tahir Farid

Erschienen in: Journal of Electronic Materials | Ausgabe 6/2023

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Abstract

The excruciatingly sluggish kinetics of the water-splitting reaction impedes the production of hydrogen (H₂) from water. Additionally, the design of effective oxygen evolution reaction (OER) electrocatalysts needs to be improved to better understand the major barrier to the OER. As inexpensive electrocatalysts for electrochemical water splitting, manganese bichalcogenide heterostructures and their equivalents, manganese oxide (MnO) and manganese sulfide (MnS), are synthesized, characterized, and electrochemically evaluated in this study. Powder x-ray diffraction (PXRD), Fourier transform infrared (FTIR) spectroscopy, and scanning electron microscopy (SEM) are all used to study these electrocatalysts. The MnS/MnO electrocatalyst is found to be extremely effective and stable, and it starts the OER at an astonishingly low potential of 331 mV (vs. reversible hydrogen electrode [RHE]), with a Tafel slope of 33 mV dec⁻¹ at 10 mA cm⁻². The MnS/MnO electrocatalyst outperforms its MnO and MnS counterparts under identical electrochemical conditions for OER in an aqueous KOH (1.0 M) solution. These outcomes surpass those of benchmark rare earth metal and Mn-based electrocatalysts. The stability results of long-term analysis and cycling analysis indicate that the fabricated nanohybrids are stable for 30 h after 1000 cycles. This innovation offers a desirable non-noble metal that is very effective and stable as an OER electrocatalyst.

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I. Ganesh, Conversion of carbon dioxide into methanol—a potential liquid fuel: fundamental challenges and opportunities (a review). Renew. Sustain. Energy Rev. 31, 221 (2014). https://doi.org/10.1016/J.RSER.2013.11.045.CrossRef

J. Blanco, S. Malato, P. Fernández-Ibañez, D. Alarcón, W. Gernjak, and M.I. Maldonado, Review of feasible solar energy applications to water processes. Renew. Sustain. Energy Rev. 13, 1437 (2009). https://doi.org/10.1016/J.RSER.2008.08.016.CrossRef

M. Pudukudy, Z. Yaakob, M. Mohammad, B. Narayanan, and K. Sopian, Renewable hydrogen economy in Asia—opportunities and challenges: An overview. Renew. Sustain. Energy Rev. 30, 743 (2014). https://doi.org/10.1016/J.RSER.2013.11.015.CrossRef

I.R. Hamdani and A.N. Bhaskarwar, Recent progress in material selection and device designs for photoelectrochemical water-splitting. Renew. Sustain. Energy Rev. 138, 110503 (2021). https://doi.org/10.1016/J.RSER.2020.110503.CrossRef

F. Abdelghafar, X. Xu, S.P. Jiang, and Z. Shao, Designing single-atom catalysts toward improved alkaline hydrogen evolution reaction. Mater. Rep. Energy. 2, 100144 (2022). https://doi.org/10.1016/J.MATRE.2022.100144.CrossRef

Y. Ma, X. Wang, Y. Jia, X. Chen, H. Han, and C. Li, Titanium dioxide-based nanomaterials for photocatalytic fuel generations. Chem. Rev. 114, 9987 (2014). https://doi.org/10.1021/CR500008U/SUPPL_FILE/CR500008U_SI_001.PDF.CrossRef

C.R. Lhermitte and K. Sivula, Alternative oxidation reactions for solar-driven fuel production. ACS Catal. 9, 2007 (2019).https://doi.org/10.1021/ACSCATAL.8B04565/ASSET/IMAGES/MEDIUM/CS-2018-04565V_0008.GIF.CrossRef

W. Zhang, W. Lai, and R. Cao, Energy-related small molecule activation reactions: oxygen reduction and hydrogen and oxygen evolution reactions catalyzed by porphyrin- and corrole-based systems. Chem. Rev. 117, 3717 (2017). https://doi.org/10.1021/ACS.CHEMREV.6B00299/SUPPL_FILE/CR6B00299_SI_002.PDF.CrossRef

Y. Yu, J. Zhou, Z. Sun, Y.D. Yu, J. Zhou, and Z.M. Sun, Novel 2D transition-metal carbides: ultrahigh performance electrocatalysts for overall water splitting and oxygen reduction. Adv. Funct. Mater. 30, 2000570 (2020). https://doi.org/10.1002/ADFM.202000570.CrossRef

10.

S. Li, Y. Gao, N. Li, L. Ge, X. Bu, and P. Feng, Transition metal-based bimetallic MOFs and MOF-derived catalysts for electrochemical oxygen evolution reaction. Energy Environ. Sci. 14, 1897 (2021). https://doi.org/10.1039/D0EE03697H.CrossRef

11.

S. Zhao, Y. Wang, J. Dong, C.T. He, H. Yin, P. An, K. Zhao, X. Zhang, C. Gao, L. Zhang, J. Lv, J. Wang, J. Zhang, A.M. Khattak, N.A. Khan, Z. Wei, J. Zhang, S. Liu, H. Zhao, and Z. Tang, Ultrathin metal-organic framework nanosheets for electrocatalytic oxygen evolution. Nat. Energy 112(1), 1 (2016). https://doi.org/10.1038/nenergy.2016.184.CrossRef

12.

S. Zhao, D.W. Wang, R. Amal, and L. Dai, Carbon-based metal-free catalysts for key reactions involved in energy conversion and storage. Adv. Mater. 31, 1801526 (2019). https://doi.org/10.1002/ADMA.201801526.CrossRef

13.

T. Zhao, Y. Wang, S. Karuturi, K. Catchpole, Q. Zhang, and C. Zhao, Design and operando/in situ characterization of precious-metal-free electrocatalysts for alkaline water splitting. Carbon Energy 2, 582 (2020). https://doi.org/10.1002/CEY2.79.CrossRef

14.

S. Chandrasekaran, D. Ma, Y. Ge, L. Deng, C. Bowen, J. Roscow, Y. Zhang, Z. Lin, R.D.K. Misra, J. Li, P. Zhang, and H. Zhang, Electronic structure engineering on two-dimensional (2D) electrocatalytic materials for oxygen reduction, oxygen evolution, and hydrogen evolution reactions. Nano Energy 77, 105080 (2020). https://doi.org/10.1016/J.NANOEN.2020.105080.CrossRef

15.

X. Cao, T. Wang, and L. Jiao, Transition-metal (Fe Co, and Ni)-based nanofiber electrocatalysts for water splitting. Adv. Fiber Mater. 34(3), 210 (2021). https://doi.org/10.1007/S42765-021-00065-Z.CrossRef

16.

L. Wei, E.H. Ang, Y. Yang, Y. Qin, Y. Zhang, M. Ye, Q. Liu, and C.C. Li, Recent advances of transition metal based bifunctional electrocatalysts for rechargeable zinc-air batteries. J. Power Sources 477, 228696 (2020). https://doi.org/10.1016/J.JPOWSOUR.2020.228696.CrossRef

17.

H. Zhong, C.A. Campos-Roldán, Y. Zhao, S. Zhang, Y. Feng, and N. Alonso-Vante, Recent advances of cobalt-based electrocatalysts for oxygen electrode reactions and hydrogen evolution reaction. Catalyst 2018(8), 559 (2018). https://doi.org/10.3390/CATAL8110559.CrossRef

18.

C.Z. Yuan, K.S. Hui, H. Yin, S. Zhu, J. Zhang, X.L. Wu, X. Hong, W. Zhou, X. Fan, F. Bin, F. Chen, and K.N. Hui, Regulating intrinsic electronic structures of transition-metal-based catalysts and the potential applications for electrocatalytic water splitting. ACS Mater. Lett. 3, 752 (2021). https://doi.org/10.1021/ACSMATERIALSLETT.0C00549/ASSET/IMAGES/MEDIUM/TZ0C00549_0020.GIF.CrossRef

19.

A. Garg, S. Basu, N.P. Shetti, and K.R. Reddy, 2D materials and its heterostructured photocatalysts: synthesis, properties, functionalization and applications in environmental remediation. J. Environ. Chem. Eng. 9, 106408 (2021). https://doi.org/10.1016/J.JECE.2021.106408.CrossRef

20.

N.F.H. Nik Zaiman, N. Shaari, and N.A.M. Harun, Developing metal-organic framework-based composite for innovative fuel cell application: an overview. Int. J. Energy Res. 46, 471 (2022). https://doi.org/10.1002/ER.7198.CrossRef

21.

X. Rui, H. Tan, and Q. Yan, Nanostructured metal sulfides for energy storage. Nanoscale 6, 9889 (2014). https://doi.org/10.1039/C4NR03057E.CrossRef

22.

Y. Hao, C. Chen, X. Yang, G. Xiao, B. Zou, J. Yang, and C. Wang, Studies on intrinsic phase-dependent electrochemical properties of MnS nanocrystals as anodes for lithium-ion batteries. J. Power Sources 338, 9 (2017). https://doi.org/10.1016/J.JPOWSOUR.2016.11.032.CrossRef

23.

Y. Wang, L. Liu, T. Ma, Y. Zhang, and H. Huang, 2D graphitic carbon nitride for energy conversion and storage. Adv. Funct. Mater. 31, 2102540 (2021). https://doi.org/10.1002/ADFM.202102540.CrossRef

24.

Y. Qu and X. Duan, Progress, challenge and perspective of heterogeneous photocatalysts. Chem. Soc. Rev. 42, 2568 (2013). https://doi.org/10.1039/C2CS35355E.CrossRef

25.

Z.P. Wu, X.F. Lu, S.Q. Zang, and X.W. Lou, Non-noble-metal-based electrocatalysts toward the oxygen evolution reaction. Adv. Funct. Mater. 30, 1910274 (2020). https://doi.org/10.1002/ADFM.201910274.CrossRef

26.

V.B.R. Boppana, and F. Jiao, Nanostructured MnO₂: an efficient and robust water oxidation catalyst. Chem. Commun. 47, 8973 (2011). https://doi.org/10.1039/C1CC12258D.CrossRef

27.

P.W. Menezes, A. Indra, P. Littlewood, M. Schwarze, C. Göbel, R. Schomäcker, and M. Driess, Nanostructured manganese oxides as highly active water oxidation catalysts: a boost from manganese precursor chemistry. Chemsuschem 7, 2202 (2014). https://doi.org/10.1002/CSSC.201402169.CrossRef

28.

V.B.R. Boppana, S. Yusuf, G.S. Hutchings, and F. Jiao, Nanostructured alkaline-cation-containing δ-MnO₂ for photocatalytic water oxidation. Adv. Funct. Mater. 23, 878 (2013). https://doi.org/10.1002/ADFM.201202141.CrossRef

29.

W. Li, X. Cui, R. Zeng, G. Du, Z. Sun, R. Zheng, S.P. Ringer, and S.X. Dou, Performance modulation of α-MnO₂ nanowires by crystal facet engineering. Sci. Rep. 51(5), 1 (2015). https://doi.org/10.1038/srep08987.CrossRef

30.

E. Hayashi, Y. Yamaguchi, K. Kamata, N. Tsunoda, Y. Kumagai, F. Oba, and M. Hara, Effect of MnO₂ crystal structure on aerobic oxidation of 5-hydroxymethylfurfural to 2,5-furandicarboxylic acid. J. Am. Chem. Soc. 141, 899 (2019). https://doi.org/10.1021/JACS.8B09917/SUPPL_FILE/JA8B09917_SI_001.PDF.CrossRef

31.

K. Zhang, X. Han, Z. Hu, X. Zhang, Z. Tao, and J. Chen, Nanostructured Mn-based oxides for electrochemical energy storage and conversion. Chem. Soc. Rev. 44, 699 (2015). https://doi.org/10.1039/C4CS00218K.CrossRef

32.

B. Liu, Y. Sun, L. Liu, S. Xu, and X. Yan, Advances in manganese-based oxides cathodic electrocatalysts for Li-air batteries. Adv. Funct. Mater. 28, 1704973 (2018). https://doi.org/10.1002/ADFM.201704973.CrossRef

33.

R. Zhang, Z. Yu, R. Jiang, J. Huang, Y. Hou, F. Yang, H. Zhu, B. Zhang, Y. Huang, and B. Ye, Dual synergistic effect of S-doped carbon bridged semi crystalline MILN-based Co₃S₄/MnS₂ nanostructure in electrocatalytic overall water splitting. Electrochim. Acta 366, 137438 (2021). https://doi.org/10.1016/J.ELECTACTA.2020.137438.CrossRef

34.

C. Manjunatha, S. Lakshmikant, L. Shreenivasa, N. Srinivasa, S. Ashoka, B.W. Shivraj, M. Selvaraj, U.S. Meda, G.S. Babu, and B.G. Pollet, Development of non-stoichiometric hybrid Co₃S₄/Co_0.85Se nanocomposites for an evaluation of synergistic effect on the OER performance. Surfaces Interfaces 25, 101161 (2021). https://doi.org/10.1016/J.SURFIN.2021.101161.CrossRef

35.

M.A. Raza, A. Wahab, A.H.U. Bhatti, A. Ahmad, R. Ahmad, N. Iqbal, and G. Ali, CoS₂/MnS₂ co-doped ZIF-derived nitrogen doped high surface area carbon-based electrode for high-performance supercapacitors. Electrochim. Acta 407, 139914 (2022). https://doi.org/10.1016/J.ELECTACTA.2022.139914.CrossRef

36.

K.K. Hazarika, B. Chutia, R.R. Changmai, P.K. Boruah, M.R. Das, and P. Bharali, FexCo₃-xO₄ nanohybrids anchored on a carbon matrix for high-performance oxygen electrocatalysis in alkaline media. ChemElectroChem 9, e202200867 (2022). https://doi.org/10.1002/CELC.202200867.CrossRef

37.

X. Xiong, Y. Ji, M. Xie, C. You, L. Yang, Z. Liu, A.M. Asiri, and X. Sun, MnO₂-CoP₃ nanowires array: an efficient electrocatalyst for alkaline oxygen evolution reaction with enhanced activity. Electrochem. Commun. 86, 161 (2018). https://doi.org/10.1016/J.ELECOM.2017.12.008.CrossRef

38.

B. Shabbir, M.Z. Ansari, S. Manzoor, A.G. Abid, M.U. Nisa, A.M. Shawky, S. Znaidia, S. Aman, M.N. Ashiq, and T.A. Taha, Facile synthesis of Er-MOF/Fe₂O₃ nanocomposite for oxygen evolution reaction. Mater. Chem. Phys. 292, 126861 (2022). https://doi.org/10.1016/J.MATCHEMPHYS.2022.126861.CrossRef

39.

Y. Zhai, X. Ren, Y. Sun, D. Li, B. Wang, and S. Liu, Synergistic effect of multiple vacancies to induce lattice oxygen redox in NiFe-layered double hydroxide OER catalysts. Appl. Catal. B Environ. 323, 122091 (2023). https://doi.org/10.1016/J.APCATB.2022.122091.CrossRef

40.

T. Wang, P. Wang, W. Zang, X. Li, D. Chen, Z. Kou, S. Mu, J. Wang, T.T. Wang, P. Wang, D. Chen, Z. Kou, S. Mu, W. Zang, X. Li, and J. Wang, Nanoframes of Co₃O₄-Mo₂N heterointerfaces enable high-performance bifunctionality toward both electrocatalytic HER and OER. Adv. Funct. Mater. 32, 2107382 (2022). https://doi.org/10.1002/ADFM.202107382.CrossRef

41.

J. Ahmed, N. Alhokbany, T. Ahamad, and S.M. Alshehri, Investigation of enhanced electro-catalytic HER/OER performances of copper tungsten oxide@reduced graphene oxide nanocomposites in alkaline and acidic media. New J. Chem. 46, 1267 (2022). https://doi.org/10.1039/D1NJ04617A.CrossRef

42.

A. Hameed, F. Zulfiqar, W. Iqbal, H. Ali, S. Shoaib, A. Shah, and M. Arif, Electrocatalytic water oxidation on CuO-Cu₂O modulated cobalt-manganese layered double hydroxide. RSC Adv. 12, 28954 (2022). https://doi.org/10.1039/D2RA05036F.CrossRef

43.

W. Jiang, H. Li, Y. Chen, Y. Wu, J.J. Li, X. Wang, X. Huang, and Y. Lao, OER properties of Ni-Co-CeO₂/Ni composite electrode prepared by magnetically induced jet electrodeposition. Int. J. Hydrogen Energy (2022). https://doi.org/10.1016/J.IJHYDENE.2022.10.231.CrossRef

44.

T. Chen, M. Qian, X. Tong, W. Liao, Y. Fu, H. Dai, and Q. Yang, Nanosheet self-assembled NiCoP microflowers as efficient bifunctional catalysts (HER and OER) in alkaline medium. Int. J. Hydrogen Energy 46, 29889 (2021). https://doi.org/10.1016/J.IJHYDENE.2021.06.121.CrossRef

45.

Z. Li, P. Wei, and G. Wang, Recent advances on perovskite electrocatalysts for water oxidation in alkaline medium. Energy Fuels 36, 11724 (2022). https://doi.org/10.1021/ACS.ENERGYFUELS.2C02236/ASSET/IMAGES/LARGE/EF2C02236_0013.JPEG.CrossRef

46.

N. Chen, X. Du, and X. Zhang, Controlled synthesis of MnS/ZnS hybrid material with different morphology as efficient water and urea electrolysis catalyst. Renew. Energy 193, 715 (2022). https://doi.org/10.1016/J.RENENE.2022.05.040.CrossRef

47.

S. Guo, J. Wang, Y. Sun, L. Peng, and C. Li, Interface engineering of Co₃O₄/CeO₂ heterostructure in-situ embedded in Co/N-doped carbon nanofibers integrating oxygen vacancies as effective oxygen cathode catalyst for Li-O₂ battery. Chem. Eng. J. 452, 139317 (2023). https://doi.org/10.1016/J.CEJ.2022.139317.CrossRef

48.

L. Zhang, H. Li, B. Yang, Y. Zhou, Z. Zhang, and Y. Wang, Photo-deposition of ZnO/Co₃O₄ core-shell nanorods with p-n junction for efficient oxygen evolution reaction. J. Solid State Electrochem. 23, 3287 (2019). https://doi.org/10.1007/S10008-019-04444-W/FIGURES/7.CrossRef

49.

D. Jin, H. Yoo, Y. Lee, C. Lee, and M.H. Kim, IrO₂-ZnO composite nanorod array as an acid-stable electrocatalyst with superior activity for the oxygen evolution reaction. ACS Appl. Energy Mater. 5, 3810 (2022). https://doi.org/10.1021/ACSAEM.2C00292/ASSET/IMAGES/LARGE/AE2C00292_0009.JPEG.CrossRef

50.

M. Musiani, F. Furlanetto, and R. Bertoncello, Electrodeposited PbO₂ + RuO₂: a composite anode for oxygen evolution from sulphuric acid solution. J. Electroanal. Chem. 465, 160 (1999). https://doi.org/10.1016/S0022-0728(99)00080-7.CrossRef

51.

N. Alwadai, S. Manzoor, M. Al Huwayz, M. Abdullah, R.Y. Khosa, S. Aman, A.G. Abid, Z.A. Alrowaili, M.S. Al-Buriahi, and H.M.T. Farid, Facile synthesis of transition metal oxide SnO₂/MnO₂ hierarchical nanostructure: as an efficient electrocatalyst for robust oxygen evolution reaction. Surfaces Interfaces 36, 102467 (2023). https://doi.org/10.1016/J.SURFIN.2022.102467.CrossRef

52.

U. Aftab, A. Tahira, A. Gradone, V. Morandi, M.I. Abro, M.M. Baloch, A.L. Bhatti, A. Nafady, A. Vomiero, and Z.H. Ibupoto, Two step synthesis of TiO₂-Co₃O₄ composite for efficient oxygen evolution reaction. Int. J. Hydrogen Energy 46, 9110 (2021). https://doi.org/10.1016/J.IJHYDENE.2020.12.204.CrossRef

53.

H. You, B. Wang, Y. Wang, Y. Cao, K. Wei, and F. Gao, Efficient fish-scale CeO₂/NiFeCo composite material as electrocatalyst for oxygen evolution reaction. Nanotechnology 32, 365403 (2021). https://doi.org/10.1088/1361-6528/ABF690.CrossRef

54.

J. Zhang, W. He, H. Barike Aiyappa, T. Quast, S. Dieckhöfer, D. Öhl, J.R.C. Junqueira, Y.-T. Chen, J. Masa, W. Schuhmann, J. Zhang, W. He, H.B. Aiyappa, T. Quast, S. Dieckhöfer, D. Öhl, J.R.C. Junqueira, W. Schuhmann, Y. Chen, and J. Masa, Hollow CeO₂@Co₂N nanosheets derived from Co-ZIF-L for boosting the oxygen evolution reaction. Adv. Mater. Interfaces 8, 2100041 (2021). https://doi.org/10.1002/ADMI.202100041.CrossRef

55.

D. Taherinia, M. Moazzeni, and S. Moravej, Comparison of hydrothermal and electrodeposition methods for the synthesis of CoSe₂/CeO₂ nanocomposites as electrocatalysts toward oxygen evolution reaction. Int. J. Hydrogen Energy 47, 17650 (2022). https://doi.org/10.1016/J.IJHYDENE.2022.03.257.CrossRef

Titel: A Nanosized Manganese-Based Chalcogenide Composite for Enhanced Electrocatalytic OER
verfasst von: F. F. Alharbi
Hafiz Muhammad Tahir Farid
Publikationsdatum: 15.03.2023
Verlag: Springer US
Erschienen in: Journal of Electronic Materials / Ausgabe 6/2023
Print ISSN: 0361-5235
Elektronische ISSN: 1543-186X
DOI: https://doi.org/10.1007/s11664-023-10330-z

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