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Journal of Electronic Materials
Erschienen in: Journal of Electronic Materials 6/2023

13.04.2023 | Original Research Article

Multidimensional Hierarchical Hybrid Derived from Carbon-Based Microsphere-Supported Bimetallic Organic Frameworks Linked with Graphene Oxide for Efficient Oxygen Reduction Reaction

verfasst von: Yating Zhang, Pei He, Nana Zhang, Dongxian Zhuo, Xue Wang, Xiaobo Wang, Zhenghan Kong, Yanping Hu

Erschienen in: Journal of Electronic Materials | Ausgabe 6/2023

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Abstract

The rational construction and preparation of efficient, stable, and economic electrocatalysts for the oxygen reduction reaction (ORR) are necessary for fuel cells. In this work, we fabricated a porous carbon skeleton structure consisting of bimetallic organic framework (BMMOF)-derived N-doped microspheres linked with graphene oxide (GO) conducting network (denoted as UA-Co/RSC@NGF, where “UA” stands for ultrasound-assisted, “RSC” stands for resin microspheres, and “NGF” stands for N-doped graphene framework) as an efficient ORR catalyst by an ultrasound-assisted and one-step pyrolysis method. In this configuration, benefiting from the support of carbon microspheres and the strong synergistic coupling with GO, the structure of UA-Co/RSC@NGF is stabilized, and the large specific surface area enhances the density of active sites. With UA-Co/RSC@NGF as the catalyst, significant ORR properties were achieved with a high half-wave potential (E1/2, 0.90 V), an onset potential (Eonset, 1.03 V), and a large limited current density (5.37 mA cm−2). The durability and methanol resistance of UA-Co/RSC@NGF in alkaline media outperform commercially available Pt/C. This study may open a pathway for rationally designing multidimensional composite-structured carbon-based ORR catalysts for energy-related applications.
Vorheriger Artikel Energy Bandgap of Cd1−xZnxTe, Cd1−xZnxSe and Cd1−xZnxS Semiconductors: A First-Principles Analysis Based on Tran–Blaha–Modified Becke–Johnson Exchange Potential
Nächster Artikel Light-Dependent A.C. Transport Properties of Zinc Oxide (ZnO)/Reduced Graphene Oxide (rGO) Heterostructure Device: A Signature of Electrical Memory

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Metadaten
Titel
Multidimensional Hierarchical Hybrid Derived from Carbon-Based Microsphere-Supported Bimetallic Organic Frameworks Linked with Graphene Oxide for Efficient Oxygen Reduction Reaction
verfasst von
Yating Zhang
Pei He
Nana Zhang
Dongxian Zhuo
Xue Wang
Xiaobo Wang
Zhenghan Kong
Yanping Hu
Publikationsdatum
13.04.2023
Verlag
Springer US
Erschienen in
Journal of Electronic Materials / Ausgabe 6/2023
Print ISSN: 0361-5235
Elektronische ISSN: 1543-186X
DOI
https://doi.org/10.1007/s11664-023-10398-7

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