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Advanced Control of Photochemical Reactions Leading to Synergetic Responses in Molecules and Mesoscopic Materials Read chapter Read first chapter

2020 | OriginalPaper | Chapter

18. π-Electronic Ion-Pairing Assemblies for Photoswitching Materials

Authors : Yohei Haketa, Ryohei Yamakado, Kazuki Urakawa, Hiromitsu Maeda

Published in: Photosynergetic Responses in Molecules and Molecular Aggregates

Publisher: Springer Singapore

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Abstract

Ion-pairing assemblies consisting of appropriately designed oppositely charged π-electronic systems give rise to various functional supramolecular assemblies including crystals and soft materials based on the anisotropic orientation of charged species through electrostatic and other weak noncovalent interactions. The introduction of photo-responsive moiety to the charged species facilitated the formation of photo-responsive ion-pairing assemblies, whose assembling modes were controlled by photoirradiation. Furthermore, pyrrole-based π-system–PtII complexes were designed and exhibited unique photo-induced excited-state dynamics.

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previous chapter Synergetic Photon Upconversion Realized by a Controlled Toroidal Interaction in Hexaarylbenzene Derivatives
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Metadata
Title
π-Electronic Ion-Pairing Assemblies for Photoswitching Materials
Authors
Yohei Haketa
Ryohei Yamakado
Kazuki Urakawa
Hiromitsu Maeda
Copyright Year
2020
Publisher
Springer Singapore
Book
Photosynergetic Responses in Molecules and Molecular Aggregates

Print ISBN: 978-981-15-5450-6

Electronic ISBN: 978-981-15-5451-3

Copyright Year: 2020

DOI
https://doi.org/10.1007/978-981-15-5451-3_18

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