Top

Published in:

2021 | OriginalPaper | Chapter

2-(2-Methoxybenzylidene) Hydrazine-1-Carbothioamide as Efficient Organic Inhibitor for Mild Steel in Hydrochloric Acid Solution

Authors : Hana Ferkous, Souad Djellali, Rachid Sahraoui, Hamza Behloul, Khaoula Saoud, Alaaddin Çukurovali

Published in: Recent Advances in Environmental Science from the Euro-Mediterranean and Surrounding Regions (2nd Edition)

Publisher: Springer International Publishing

Activate our intelligent search to find suitable subject content or patents.

search-config

AI-assisted search

Off

Abstract

The 2-(2-methoxybenzylidene) hydrazine-1-carbothioamide (MBHCA), a Schiff base, is tested as a corrosion inhibitor of mild steel in a hydrochloric acid medium (1 M). The addition effect of this compound on the metal behaviour is monitored using potentiodynamic polarization tests and gravimetric method. The results show the significant reduction in the corrosion rate of steel with the increase of the concentration of the Schiff base; the inhibition efficiency of MBHCA reaches a maximum value of 97.9% at 200 ppm. Polarization measurements reveal that the presence of MBHCA decreases the current and shifts the corrosion potential to higher values considerably indicating that this Schiff base acts as a mixed inhibitor with cathodic predominance.

Dont have a licence yet? Then find out more about our products and how to get one now:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

über 102.000 Bücher
über 537 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Finance + Banking
Management + Führung
Marketing + Vertrieb
Maschinenbau + Werkstoffe
Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

inform now

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

über 67.000 Bücher
über 390 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Maschinenbau + Werkstoffe

Jetzt Wissensvorsprung sichern!

inform now

previous chapter Synthesis and Application of Algerian Natural Kaolin Modified 13X Zeolite for the Treatment of Real Textile Effluent

next chapter Thermodynamic and Electrochemical Studies of Corrosion Inhibition of Carbon Steel by Rosmarinus Officinalis Extract in Acid Medium

El Kacimi, Y., Azaroual, M.A., Touir, R., Galai, M., Alaoui, K., Sfaira, M., Ebn Touhami, M., Kaya, S.: Corrosion inhibition studies for mild steel in 5.0 M HCl by substituted phenyltetrazole. Euro-Mediterranean J. Environ. Integr. 2, 1–11 (2017). https://doi.org/10.1007/s41207-016-0011-8

Benbouya, K., Dkhireche, N., Rochdi, A., Chebab, A., Touir, R., Ebn Touhami, M., El Bakri, M., Sfaira, M.: Adsorption and inhibitive performance of 3-methylquinoxaline-2(1H)-thione against mild steel corrosion in phosphoric acid solution. Euro-Mediterranean J. Environ. Integr. 3, 1–11 (2018). https://doi.org/10.1007/s41207-017-0042-9CrossRef

Sastri, V.S.: Green Corrosion Inhibitors Theory and Practice. John Wiley & Sons, New Jersey (2011)CrossRef

H.Ferkous, M.Zerroug, M. Radjai, M.A. Chaouch, Z.Jebali,H.Majdoub, Electochemical and surface morphological studies of a carbon steel corrosion by natural product in acidic solution, Euro-Mediterranean J. Environ. Integr. 1291–1292 (2017)

Zhang, K., Xu, B., Yang, W., Yin, X., Liu, Y., Chen, Y.: Halogen-substituted imidazoline derivatives as corrosion inhibitors for mild steel in hydrochloric acid solution. Corros. Sci. 90, 284–295 (2015)CrossRef

Zhang, Q.H., Hou, B.S., Xu, N., Xiong, W., Liu, H.F., Zhang, G.A.: Effective inhibition on the corrosion of X65 carbon steel in the oilfield produced water by two Schiff bases, J. Mol. Liq. (2019)

Bedair, M.A., Soliman, S.A., Hegazy, M.A., Obot, I.B., Ahmed A. S.: Empirical and theoretical investigations on the corrosion inhibition characteristics of mild steel by three new Schiff base derivatives, J. Adhes. Sci. Technol. 1139–1168 (2019)

Yurt, A., Uluta, S., Dal, H.: Electrochemical and theoretical investigation on the corrosion of aluminium in acidic solution containing some Schiff bases, Appl. Surf. Sci. 253(2) 919–925 (2006)

Ma, H., Chen, S., Niu, L., Zhao, S., Li, S., Li, D.: Inhibition of copper corrosion by several Schiff bases in aerated halide solutions. J. Appl. Electrochem. 32(1), 65–72 (2002)CrossRef

10.

Solmaz, R., Altunbaş, E., Kardaş, G.: Adsorption and corrosion inhibition effect of 2-((5-mercapto-1,3,4-thiadiazol-2-ylimino)methyl)phenol schiff base on mild steel, Mater. Chem. Phys. 125(3), 796–801(2011)

11.

Ashassi-SorkhabI, H., Shaabani, B., Seifzadeh, D.: Corrosion inhibition of mild steel by some schiff base compounds in hydrochloric acid, Appl. Surf. Sci. 239(2), 154–164 (2005)

Title: 2-(2-Methoxybenzylidene) Hydrazine-1-Carbothioamide as Efficient Organic Inhibitor for Mild Steel in Hydrochloric Acid Solution
Authors: Hana Ferkous
Souad Djellali
Rachid Sahraoui
Hamza Behloul
Khaoula Saoud
Alaaddin Çukurovali
Publisher: Springer International Publishing
Book: Recent Advances in Environmental Science from the Euro-Mediterranean and Surrounding Regions (2nd Edition)
Print ISBN: 978-3-030-51209-5

Electronic ISBN: 978-3-030-51210-1

Copyright Year: 2021
DOI: https://doi.org/10.1007/978-3-030-51210-1_235