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Journal of Polymer Research

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01-12-2013 | Original Paper

A facile approach to the synthesis of CdSe/P3HT nanocomposites

Authors: Xianglong Duan, Haihong Ma, Weibing Xu, Zhengfa Zhou, Fengmei Ren

Published in: Journal of Polymer Research | Issue 12/2013

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Abstract

In this article, we report a facile, direct synthesis route to prepare CdSe/P3HT nanocomposites with CdO used as cadmium source, Se powder as selenium source, liquid paraffin and oleic acid as solvents, P3HT as a conjugated polymer template. The effect of the reaction temperature as well as the Cd:Se molar ratio on the morphology and photovoltaic property of CdSe/P3HT nanocomposites was studied. The results show that the shape and the degree of aggregation of CdSe nanocrystals are not only temperature-dependent, but also heavily influenced by the Cd:Se ratio, changing from dot-shaped to tetrapod-shaped, and from homo-dispersed to seriously aggregative. The UV–vis absorption spectra of CdSe-P3HT show a broader range and higher intensity of absorption than that of pure P3HT. The improved PL quenching in PL spectra of CdSe-P3HT indicates charge transfer between CdSe nanocrystals and P3HT.

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Title: A facile approach to the synthesis of CdSe/P3HT nanocomposites
Authors: Xianglong Duan
Haihong Ma
Weibing Xu
Zhengfa Zhou
Fengmei Ren
Publication date: 01-12-2013
Publisher: Springer Netherlands
Published in: Journal of Polymer Research / Issue 12/2013
Print ISSN: 1022-9760
Electronic ISSN: 1572-8935
DOI: https://doi.org/10.1007/s10965-013-0315-1

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