Top

Journal of Materials Science

Published in:

13-07-2018 | Chemical routes to materials

A facile fabrication of nanoflower-like Co₃O₄ catalysts derived from ZIF-67 and their catalytic performance for CO oxidation

Authors: Ning Liu, Pin Tao, Chuwen Jing, Wenyuan Huang, Xiaodong Zhang, Minghong Wu, Jianqiu Lei, Liang Tang

Published in: Journal of Materials Science | Issue 21/2018

Activate our intelligent search to find suitable subject content or patents.

search-config

AI-assisted search

Off

Abstract

Herein, we reported a facile method for fabricating nanoflower-like Co₃O₄ catalysts via calcination treatment based on ZIF-67. The catalytic performances of the obtained Co₃O₄ catalysts were evaluated for the model reaction of CO oxidation. The results demonstrated that calcination temperature had a strong effect on the structure and catalytic reaction activity of Co₃O₄ catalyst. Co₃O₄ catalyst prepared at 400 °C (Co₃O₄-400) exhibited the optimum catalytic activity with a complete CO conversion temperature of 105 °C. This phenomenon was ascribed to the higher specific surface areas, smaller particle size, unique structure, good low-temperature reduction and higher abundances of surface Co²⁺ and adsorbed oxygen species. The addition of 1.0% water vapor had a negative effect on CO oxidation and the prepared Co₃O₄-400 catalyst presented long-term stability.

previous article Structural, optical, and photocatalytic investigation of nickel oxide@graphene oxide nanocomposite thin films by RF magnetron sputtering

next article Stable and recyclable Pd catalyst supported on modified silica hollow microspheres with macroporous shells for enhanced catalytic hydrogenation of NBR

Dont have a licence yet? Then find out more about our products and how to get one now:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

über 102.000 Bücher
über 537 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Finance + Banking
Management + Führung
Marketing + Vertrieb
Maschinenbau + Werkstoffe
Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

inform now

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

über 67.000 Bücher
über 390 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Maschinenbau + Werkstoffe

Jetzt Wissensvorsprung sichern!

inform now

Available only for authorised users

Yang YQ, Dong H, Wang Y, Wang YX, Liu N, Wang DJ, Zhang XD (2017) A facile synthesis for porous CuO/Cu₂O composites derived from MOFs and their superior catalytic performance for CO oxidation. Inorg Chem Commun 86:74–77. https://doi.org/10.1016/j.inoche.2017.09.027 CrossRef

Yang YQ, Dong H, Wang Y, He C, Wang YX, Zhang XD (2018) Synthesis of octahedral like Cu-BTC derivatives derived from MOF calcined under different atmosphere for application in CO oxidation. J Solid State Chem 258:582–587. https://doi.org/10.1016/j.jssc.2017.11.033 CrossRef

Cui LF, Zhao D, Yang Y, Wang YX, Zhang XD (2017) Synthesis of highly efficient α-Fe₂O₃ catalysts for CO oxidation derived from MIL-100(Fe). J Solid State Chem 247:168–172. https://doi.org/10.1016/j.jssc.2017.01.013 CrossRef

Zhang XD, Dong H, Wang Y, Liu N, Zuo YH, Cui LF (2016) Study of catalytic activity at the Ag/Al-SBA-15 catalysts for CO oxidation and selective CO oxidation. Chem Eng J 283:1097–1107. https://doi.org/10.1016/j.cej.2015.08.064 CrossRef

Zheng FC, Yin ZC, Xu SH, Zhang YG (2016) Formation of Co₃O₄ hollow polyhedrons from metal-organic frameworks and their catalytic activity for CO oxidation. Mater Lett 182:214–217. https://doi.org/10.1016/j.matlet.2016.06.108 CrossRef

Lv S, Xia G, Jin C, Hao C, Wang L, Li J, Zhang Y, Zhu JJ (2016) Low-temperature CO oxidation by Co₃O₄ nanocubes on the surface of Co(OH)₂ nanosheets. Catal Commun 86:100–103. https://doi.org/10.1016/j.catcom.2016.08.020 CrossRef

Xie XW, Li Y, Liu ZQ, Haruta M, Shen W (2009) Low-temperature oxidation of CO catalysed by Co₃O₄ nanorods. Nature 458(7239):746–749. https://doi.org/10.1038/nature07877 CrossRef

Yu FL, Qu ZP, Zhang XD, Fu Q, Wang Y (2013) Investigation of CO and formaldehyde oxidation over mesoporous Ag/Co₃O₄ catalysts. J Energy Chem 22:845–852. https://doi.org/10.1016/S2095-4956(14)60263-1 CrossRef

Hu LH, Sun KQ, Peng Q, Xu BQ, Li YD (2010) Surface active sites on Co₃O₄ nanobelt and nanocube model catalysts for CO oxidation. Nano Res 3:363–368. https://doi.org/10.1007/s12274-010-1040-2 CrossRef

10.

Song W, Poyraz AS, Meng Y, Ren Z, Chen SY, Suib SL (2014) Mesoporous Co₃O₄ with controlled porosity: inverse micelle synthesis and high-performance catalytic CO oxidation at − 60 °C. Chem Mater 26:4629–4639. https://doi.org/10.1021/cm502106v CrossRef

11.

Huang WY, Liu N, Zhang XD, Wu MH, Tang L (2017) Metal organic framework g-C₃N₄/MIL-53(Fe) heterojunctions with enhanced photocatalytic activity for Cr(VI) reduction under visible light. Appl Surf Sci 425:107–116. https://doi.org/10.1016/j.apsusc.2017.07.050 CrossRef

12.

Liu N, Huang WY, Zhang XD, Tang L, Wang L, Wang YX, Wu MH (2018) Ultrathin graphene oxide encapsulated in uniform MIL-88A(Fe) for enhanced visible light-driven photodegradation of RhB. Appl Catal B 221:119–128. https://doi.org/10.1016/j.apcatb.2017.09.020 CrossRef

13.

Zhang XD, Yang Y, Huang WY, Yang YQ, Wang YX, He C, Liu N, Wu MH, Tang L (2018) g-C₃N₄/UiO-66 nanohybrids with enhanced photocatalytic activities for the oxidation of dye under visible light irradiation. Mater Res Bull 99:349–358. https://doi.org/10.1016/j.materresbull.2017.11.028 CrossRef

14.

Zhang XD, Li HX, Lv XT, Xu JC, Wang YX, He C, Liu N, Yang YQ, Wang Y (2018) Facile synthesis of highly efficient amorphous Mn-MIL-100 catalysts: the formation mechanism and the structure changes during the application for CO oxidation. Chem Eur J 24:8822–8832. https://doi.org/10.1002/chem.201800773 CrossRef

15.

Zhang XD, Hou FL, Yang Y, Wang Y, Liu N, Chen D, Yang YQ (2017) A facile synthesis for cauliflower like CeO₂ catalysts from Ce-BTC precursor and their catalytic performance for CO oxidation. Appl Surf Sci 423:771–779. https://doi.org/10.1016/j.apsusc.2017.06.235 CrossRef

16.

Zhang XD, Yang Y, Song L, Wang YX, He C, Wang Z, Cui LF (2018) High and stable catalytic activity of Ag/Fe₂O₃ catalysts derived from MOFs for CO oxidation. Mol Catal 447:80–89. https://doi.org/10.1016/j.mcat.2018.01.007 CrossRef

17.

Zhang XD, Yang Y, Lv XT, Wang YX, Cui LF (2017) Effects of preparation method on the structure and catalytic activity of Ag-Fe₂O₃ catalysts derived from MOFs. Catalysts 7:382. https://doi.org/10.3390/catal7120382 CrossRef

18.

Borhani S, Moradia M, Kiani MA, Hajati S, Toth J (2017) Co_xZn_1−x ZIF-derived binary Co₃O₄/ZnO wrapped by 3D reduced graphene oxide for asymmetric supercapacitor: comparison of pure and heat-treated bimetallic MOF. Ceram Int 43:14413–14425. https://doi.org/10.1016/j.ceramint.2017.07.211 CrossRef

19.

Bigdeli H, Moradi M, Hajati S, Kiani MA, Toth J (2017) Cobalt terephthalate MOF-templated synthesis of porous nano-crystalline Co₃O₄ by the new indirect solid state thermolysis as cathode material of asymmetric supercapacitor. Physica E 94:158–166. https://doi.org/10.1016/j.physe.2017.08.005 CrossRef

20.

Wang WX, Li YW, Zhang RJ, He DH, Liu HL, Liao SJ (2011) Metal-organic framework as a host for synthesis of nanoscale Co₃O₄ as an active catalyst for CO oxidation. Catal Commun 12:875–879. https://doi.org/10.1016/j.catcom.2011.02.001 CrossRef

21.

Yan N, Chen QW, Wang F, Wang Y, Zhong H, Hu L (2012) High catalytic activity for CO oxidation of Co₃O₄ nanoparticles in SiO₂ nanocapsules. J Mater Chem A 1:637–643. https://doi.org/10.1039/C2TA00132B CrossRef

22.

Bao SX, Yan N, Shi XH, Li R, Chen QW (2014) High and stable catalytic activity of porous Ag/Co₃O₄ nanocomposites derived from MOFs for CO oxidation. Appl Catal A 487:189–194. https://doi.org/10.1016/j.apcata.2014.09.015 CrossRef

23.

24.

Zhang C, Zhang L, Xu GC, Ma X, Li YH, Zhang CY, Jia DZ (2017) Metal organic framework-derived Co₃O₄ microcubes and their catalytic applications in CO oxidation. New J Chem 41:1631–1636. https://doi.org/10.1039/c6nj02507b CrossRef

25.

Li GQ, Zhang CH, Wang Z, Huang H, Peng H, Li XB (2018) Fabrication of mesoporous Co₃O₄ oxides by acid treatment and their catalytic performances for toluene oxidation. Appl Catal A 550:67–76. https://doi.org/10.1016/j.apcata.2017.11.003 CrossRef

26.

Shen LS, Wang CX (2014) Hierarchical Co₃O₄ nanoparticles embedded in a carbon matrix for lithium-ion battery anode materials. Electrochim Acta 133:16–22. https://doi.org/10.1016/j.electacta.2014.03.182 CrossRef

27.

Li GC, Hua XN, Liu PF, Xie YX, Han L (2015) Porous Co₃O₄ microflowers prepared by thermolysis of metal-organic framework for supercapacitor. Mater Chem Phys 168:127–131. https://doi.org/10.1016/j.matchemphys.2015.11.011 CrossRef

28.

Shahabuddin S, Muhamad Sarih N, Mohamad S, Baharin SNA (2016) Synthesis and characterization of Co₃O₄ nanocube doped polyaniline nanocomposites with enhanced methyl orange adsorption from aqueous solution. RSC Adv 6(49):43388–43400. https://doi.org/10.1039/C6RA04757B CrossRef

29.

Shahida MM, Rameshkumar P, Basirunc WJ, Chingd JC, Huange NM (2017) Cobalt oxide nanocubes interleaved reduced graphene oxide as an efficient electrocatalyst for oxygen reduction reaction in alkaline medium. Electrochim Acta 237:61–68. https://doi.org/10.1016/j.electacta.2017.03.088 CrossRef

30.

Kleitz F, Berube F, Guillet-Nicolas R, Yang CM, Thommes M (2010) Probing adsorption, pore condensation, and hysteresis behavior of pure fluids in three-dimensional cubic mesoporous KIT-6 silica. J Phys Chem C 114:9344–9355. https://doi.org/10.1021/jp909836v CrossRef

31.

Ma CY, Wang DH, Xue WJ, Dou BJ, Wang HL, Hao ZP (2011) Investigation of formaldehyde oxidation over Co₃O₄-Ce₂ and Au/Co₃O₄-CeO₂ catalysts at room temperature: effective removal and determination of reaction mechanism. Environ Sci Technol 45:3628–3634. https://doi.org/10.1021/es104146v CrossRef

32.

Ma CY, Mu Z, Li JJ, Jin YG, Cheng J, Lu GQ, Hao ZP, Qiao SZ (2010) Mesoporous Co₃O₄ and Au/Co₃O₄ catalysts for low-temperature oxidation of trace ethylene. J Am Chem Soc 132:2608–2613. https://doi.org/10.1021/ja906274t CrossRef

33.

Zhang YJ, Zhang L, Deng JG, Xie SH, Yang HG, Jiang Y, Dai HX (2015) Synthesis, characterization, and catalytic properties of MnO_x/SBA-16 for toluene oxidation. In: Proceedings of the 2014 international conference on materials science and energy engineering (Cmsee 2014), p 154. https://doi.org/10.1142/9789814678971_0024

34.

Zhang XD, Li HX, Hou FL, Yang Y, Dong H, Liu N, Wang YX, Cui LF (2017) Synthesis of highly efficient Mn₂O₃ catalysts for CO oxidation derived from Mn-MIL-100. Appl Surf Sci 411:27–33. https://doi.org/10.1016/j.apsusc.2017.03.179 CrossRef

35.

Tang CW, Yu WY, Lin CJ, Wang CB, Chien SH (2007) Phase transformation in CeO₂-Co₃O₄ binary oxide under reduction and calcination pretreatments. Catal Lett 116:161–166. https://doi.org/10.1007/s10562-007-9105-x CrossRef

36.

Baidya T, Murayama T, Bera P, Safonova OV, Steiger P, Katiyar NK, Biswas K, Haruta M (2017) Low-temperature CO oxidation over combustion made Fe- and Cr-doped Co₃O₄ catalysts: role of dopant’s nature toward achieving superior catalytic activity and stability. J Phys Chem C 121:15256–15265. https://doi.org/10.1021/acs.jpcc.7b04348 CrossRef

37.

Yan XD, Tian LH, He M, Chen XB (2015) Three-dimensional crystalline/amorphous Co/Co₃O₄ core/shell nanosheets as efficient electrocatalysts for the hydrogen evolution reaction. Nano Lett 15:6015–6021. https://doi.org/10.1021/acs.nanolett.5b02205 CrossRef

38.

Cai T, Huang H, Deng W, Dai QG, Liu W, Wang XY (2015) Catalytic combustion of 1,2-dichlorobenzene at low temperature over Mn-modified Co₃O₄ catalysts. Appl Catal B 166:393–405. https://doi.org/10.1016/j.apcatb.2014.10.047 CrossRef

39.

Rokicińska A, Natkański P, Dudek B, Drozdek M, Lityńska-Dobrzyńska L, Kuśtrowski P (2016) Co₃O₄-pillared montmorillonite catalysts synthesized by hydrogel-assisted route for total oxidation of toluene. Appl Catal B 195:59–68. https://doi.org/10.1016/j.apcatb.2016.05.008 CrossRef

40.

Jiang Y, Xie SH, Yang HG, Deng JG, Liu YX, Dai HX (2017) Mn₃O₄-Au/3DOM La_0.6Sr_0.4CoO₃: high-performance catalysts for toluene oxidation. Catal Today 281:437–446. https://doi.org/10.1016/j.apcatb.2016.05.008 CrossRef

41.

Wang FG, Zhang LJ, Xu LL, Deng ZY, Shi WD (2017) Low temperature CO oxidation and CH₄ combustion over Co₃O₄ nanosheets. Fuel 203:419–429. https://doi.org/10.1016/j.fuel.2017.04.140 CrossRef

42.

Ding K, Wang D, Yang P, Hou PK, Cheng X (2016) Enhanced CO catalytic oxidation of flower-like Co₃O₄ composed of small nanoparticles. RSV Adv 6:16208–16214. https://doi.org/10.1039/C6RA01092J CrossRef

43.

Wang J, Zhong LP, Lu JC, Chen R, Lei YQ, Chen KZ, Han CY, He SF, Wan GP, Luo YM (2017) A solvent-free method to rapidly synthesize CuO-CeO₂ catalysts to enhance their CO preferential oxidation: effects of Cu loading and calcination temperature. Mol Catal 443:241–252. https://doi.org/10.1016/j.mcat.2017.10.012 CrossRef

44.

Wu MZ, Zhan WC, Guo Y, Wang YS, Guo YL, Gong XQ, Wang L, Lu GZ (2016) Solvent free selective oxidation of cyclohexane with molecular oxygen over manganese oxides: effect of the calcination temperature. Chin J Catal 37:184–192. https://doi.org/10.1016/S1872-2067(15)60983-4 CrossRef

45.

Liu CX, Liu Q, Bai L, Dong AQ, Liu GB, Wen SH (2013) Structure and catalytic performances of nanocrystalline Co₃O₄ catalysts for low temperature CO oxidation prepared by dry and wet synthetic routes. J Mol Catal A 370:1–6. https://doi.org/10.1016/j.molcata.2012.12.003 CrossRef

46.

Wang C, Tian CC, Guo YL, Zhang ZD, Hua WC, Zhan WC, Guo Y, Wang L, Lu GZ (2018) Ruthenium oxides supported on heterostructured CoPO-MCF materials for catalytic oxidation of vinyl chloride emissions. J Hazard Mater 342:290–296. https://doi.org/10.1016/j.jhazmat.2017.08.036 CrossRef

47.

Rousseau S, Loridant S, Delichere P, Boreave A, Deloume JP, Vernoux P (2009) La_(1-x)Sr_xCo_1-yFe_yO₃ perovskites prepared by sol-gel method: characterization and relationships with catalytic properties for total oxidation of toluene. Appl Catal B 88:438–447. https://doi.org/10.1016/j.apcatb.2008.10.022 CrossRef

48.

Prasad R, Singh P (2012) A review on CO oxidation over copper chromite catalyst. Catal Rev 54:224. https://doi.org/10.1080/01614940.2012.648494 CrossRef

49.

El Kasmi A, Tian ZY, Vieker H, Beyer A, Chafik T (2016) Innovative CVD synthesis of Cu₂O catalysts for CO oxidation. Appl Catal B 186:10–18. https://doi.org/10.1016/j.apcatb.2015.12.034 CrossRef

50.

Naofumi U, Masayuki U, Jun WY, Kazuyuki K (2002) Synthesis of CeO₂ spherical fine particles by homogeneous precipitation method with polyethylene glycol. Chem Lett 31:854–855. https://doi.org/10.1246/cl.2002.854 CrossRef

51.

Gao Y, Shao N, Pei Y, Chen ZF, Zeng XC (2011) Catalytic activities of subnanometer gold clusters (Au₁₆-Au₁₈, Au₂₀, and Au₂₇-Au₃₅) for CO oxidation. ACS Nano 10:7818–7829. https://doi.org/10.1021/nn201817b CrossRef

52.

Kouotou PM, Vieker H, Tian ZY, Ngamou PHT, Kasmi AE, Beyer A, Golzhauser A, Hoinghaus KK (2014) Structure-activity relation of spinel-type Co-Fe oxides for low-temperature CO oxidation. Catal Sci Technol 4:3359–3367. https://doi.org/10.1039/c4cy00463a CrossRef

53.

Zhang XD, Hou FL, Li HX, Yang Y, Wang YX, Liu N, Yang Y (2018) A strawsheave-like metal organic framework Ce-BTC derivative containing high specific surface area for improving the catalytic activity of CO oxidation reaction. Microporous Mesoporous Mater 259:211–219. https://doi.org/10.1016/j.micromeso.2017.10.019 CrossRef

54.

Rajasree R (2004) Transient kinetics of carbon monoxide oxidation by oxygen over supported palladium/ceria/zirconia three-way catalysts in the absence and presence of water and carbon dioxide. J Catal 22:36–43. https://doi.org/10.1016/j.jcat.2003.12.014 CrossRef

55.

Yang H, Lv K, Zhu JJ, Li Q, Tang DG, Ho WK, Li M, Carabineiro SAC (2017) Effect of mesoporous g-C₃N₄ substrate on catalytic oxidation of CO over Co₃O₄. Appl Surf Sci 401:333–340. https://doi.org/10.1016/j.apsusc.2016.12.238 CrossRef

Title: A facile fabrication of nanoflower-like Co3O4 catalysts derived from ZIF-67 and their catalytic performance for CO oxidation
Authors: Ning Liu
Pin Tao
Chuwen Jing
Wenyuan Huang
Xiaodong Zhang
Minghong Wu
Jianqiu Lei
Liang Tang
Publication date: 13-07-2018
Publisher: Springer US
Published in: Journal of Materials Science / Issue 21/2018
Print ISSN: 0022-2461
Electronic ISSN: 1573-4803
DOI: https://doi.org/10.1007/s10853-018-2696-3

Springer Professional

Abstract

Please log in to get access to your license.

Dont have a licence yet? Then find out more about our products and how to get one now:

Springer Professional "Wirtschaft+Technik"

Springer Professional "Technik"

Other articles of this Issue 21/2018

pHe- and glutathione-stepwise-responsive polypeptide nanogel for smart and efficient drug delivery

Preparation of Y3Al5O12:Ce nanophosphors using salt microemulsion method and their luminescent properties

Charge transport properties of pyrene and its derivatives: optoelectronic and nonlinear optical applications

Electrochemical corrosion behaviors of titanium covered by various TiO2 nanotube films in artificial saliva

Compressional stability of optical fibres: a combined experimental and computer study

Stable and recyclable Pd catalyst supported on modified silica hollow microspheres with macroporous shells for enhanced catalytic hydrogenation of NBR

Premium Partners