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Journal of Materials Science

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02-03-2020 | Energy materials

A high-entropy perovskite titanate lithium-ion battery anode

Authors: Jinhua Yan, Dan Wang, Xiaoyan Zhang, Jinsheng Li, Qiang Du, Xinyue Liu, Jinrong Zhang, Xiwei Qi

Published in: Journal of Materials Science | Issue 16/2020

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Abstract

A class of high-entropy perovskite oxide (HEPO) [(Bi,Na)_1/5(La,Li)_1/5(Ce,K)_1/5Ca_1/5Sr_1/5]TiO₃ has been synthesized by conventional solid-state method and explored as anode material for lithium-ion batteries. The half-battery provides a high initial discharge capacity of about 125.9 mAh g⁻¹ and exhibits excellent cycle stability. An outstanding reversible capacity of 120.4 mAh g⁻¹ and superior delivering retention of ~ 100% can be obtained at 1000 mA g⁻¹ after 300 cycles. Even at a high current density of 3000 mA g⁻¹, a reversible capacity of 70 mAh g⁻¹ can be retained, indicating excellent rate performance. Such outstanding cycle and rate performance can be ascribed to the entropy-stabilized structure offered by mixed aliovalent cations and the charge compensation mechanism in HEPO, respectively. This work highlights the great potential of perovskite high-entropy oxides as anode materials for lithium-ion batteries.

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Akkerman QA, Gandini M, Di Stasio M, Rastogi P, Palazon F, Bertoni G, Ball JM, Prato M, Petrozza A, Manna L (2017) Strongly emissive perovskite nanocrystal inks for high-voltage solar cells. Nat Energy 2:1–7. https://doi.org/10.1038/nenergy.2016.194 CrossRef

Song ZP, Zhou HS (2013) Towards sustainable and versatile energy storage devices: an overview of organic electrode materials. Energy Environ Sci 6:2280–2301CrossRef

Dusastre V, Martiradonna L (2017) Materials for sustainable energy. Nat Mater 16:15–15CrossRef

Xiang H, Chen J, Li Z, Wang H (2011) An inorganic membrane as a separator for lithium-ion battery. J Power Sources 196:8651–8655CrossRef

Gao RH, Liu HD, Fu BW, Li SY, Long ZY, Sun DL, Song Y (2020) CoGeO₂(OH)₂ hydrangea assembled with 2D nanoplates towards application of lithium-ion batteries. J Alloys Compd 820:153295. https://doi.org/10.1109/TPEL.2019.2945513 CrossRef

Song ZY, Wang H, Hou J, Hofmann HF, Sun J (2020) Combined state and parameter estimation of lithium-ion battery with active current injection. IEEE Trans Power Electron 35:4439–4447CrossRef

Wu DX, Wang CY, Wu MG, Chao YF, He PB, Ma JM (2020) Porous bowl-shaped VS2 nanosheets/graphene composite for high-rate lithium-ion storage. J Energy Chem 43:24–32CrossRef

Wu JB, Pan GX, Zhong WW, Yang L, Deng SJ, Xia XH (2020) Rational synthesis of Cr_0.5Nb_24.5O₆₂ microspheres as high-rate electrodes for lithium ion batteries. J Colloid Interface Sci 562:511–517CrossRef

Chen X, He W, Ding L-X, Wang S, Wang H (2019) Enhancing interfacial contact in all solid state batteries with a cathode-supported solid electrolyte membrane framework. Energy Environ Sci 12:938–944CrossRef

10.

Jiang ZY, Wang SQ, Chen XZ, Yang WL, Yao X, Hu XC, Han QY, Wang HH (2019) Tape-casting Li_0.34La_0.56TiO₃ ceramic electrolyte films permit high energy density of lithium-metal batteries. Adv Mater. https://doi.org/10.1002/adma.201906221 CrossRef

11.

Zhao J, Zhou G, Yan K, Xie J, Li Y, Liao L, Jin Y, Liu K, Hsu PC, Wang J, Cheng HM, Cui Y (2017) Air-stable and freestanding lithium alloy/graphene foil as an alternative to lithium metal anodes. Nat Nanotechnol 12:993–999CrossRef

12.

Lim S, Kim JH, Yamada Y, Munakata H, Lee YS, Kim SS, Kanamura K (2017) Improvement of rate capability by graphite foam anode for Li secondary batteries. J Power Sources 355:164–170CrossRef

13.

Luo S-H, Hu D-B, Liu H, Li J-Z, Yi T-F (2019) Hydrothermal synthesis and characterization of α-Fe₂O₃/C using acid-pickled iron oxide red for Li-ion batteries. J Hazard Mater 368:714–721CrossRef

14.

Liu H, Luo S-H, Yan S-X, Wang Q, Hu D-B, Wang Y-L, Feng J, Yi T-F (2019) High-performance α-Fe₂O₃/C composite anodes for lithium-ion batteries synthesized by hydrothermal carbonization glucose method used pickled iron oxide red as raw material. Compos Part B Eng 164:576–582CrossRef

15.

Huang G, Li Q, Yin DM, Wang LM (2017) Hierarchical porous Te@ZnCo₂O₄ nanofibers derived from Te@metal-organic frameworks for superior lithium storage capability. Adv Funct Mater 27:7–14

16.

Weng G-M, Kong J, Wang H, Karpovich C, Lipton J, Antonio F, Fishman ZS, Wang H, Yuan W, Taylor AD (2020) A highly efficient perovskite photovoltaic-aqueous Li/Na-ion battery system. Energy Storage Mater 24:557–564CrossRef

17.

Jiang Z, Xie H, Wang S, Song X, Yao X, Wang H (2018) Perovskite membranes with vertically aligned microchannels for all-solid-state lithium batteries. Adv Energy Mater 8:1801433. https://doi.org/10.1002/aenm.201801433 CrossRef

18.

Rost CM, Sachet E, Borman T, Moballegh A, Dickey EC, Hou D, Jones JL, Curtarolo S, Maria JP (2015) Entropy-stabilized oxides Nat Commun 6:8–14

19.

Chen KP, Pei XT, Tang L, Cheng HR, Li ZM, Li CW, Zhang XW, An LA (2018) A five-component entropy-stabilized fluorite oxide. J Eur Ceram Soc 38:4161–4164CrossRef

20.

Jiang SC, Hu T, Gild J, Zhou NX, Nie JY, Qin MD, Harrington T, Vecchio K, Luo J (2018) A new class of high-entropy perovskite oxides. Scr Mater 142:116–120CrossRef

21.

Ye BL, Ning SS, Liu D, Wen TQ, Chu YH (2019) One-step synthesis of coral-like high-entropy metal carbide powders. J Am Ceram Soc 102:6372–6378CrossRef

22.

Dabrowa J, Stygar M, Mikula A, Knapik A, Mroczka K, Tejchman W, Danielewski M, Martin M (2018) Synthesis and microstructure of the (Co, Cr, Fe, Mn, Ni)(3)O-4 high entropy oxide characterized by spinel structure. Mater Lett 216:32–36CrossRef

23.

Berardan D, Franger S, Meena AK, Dragoe N (2016) Room temperature lithium superionic conductivity in high entropy oxides. J Mater Chem A 4:9536–9541CrossRef

24.

Sarkar A, Velasco L, Wang D, Wang QS, Talasila G, de Biasi L, Kubel C, Brezesinski T, Bhattacharya SS, Hahn H, Breitung B (2018) High entropy oxides for reversible energy storage. Nat Commun 9:9–16CrossRef

25.

Sarkar A, Wang QS, Schiele A, Chellali MR, Bhattacharya SS, Wang D, Brezesinski T, Hahn H, Velasco L, Breitung B (2019) High-entropy oxides: fundamental aspects and electrochemical properties. Adv Mater 31:1806236. https://doi.org/10.1002/adma.201806236 CrossRef

26.

Berardan D, Meena AK, Franger S, Herrero C, Dragoe N (2017) Controlled Jahn-Teller distortion in (MgCoNiCuZn)O-based high entropy oxides. J Alloys Compd 704:693–700CrossRef

27.

Su S, Liu Q, Wang J, Fan L, Ma R, Chen S, Han X, Lu B (2019) Control of SEI formation for stable potassium-ion battery anodes by Bi-MOF-derived nanocomposites. ACS Appl Mater Interfaces 11:22474–22480CrossRef

28.

Wu J, Han C, Wu H, Liu H, Zhang Y, Lu C (2019) Nanocoating of Ce-tannic acid metal-organic coordination complex: surface modification of layered Li_1.2Mn_0.6Ni_0.2O₂ by CeO₂ coating for lithium-ion batteries. J Alloys Compd 25:3035–3040

29.

Lee K-C, Chang-Jian C-W, Ho B-C, Ding Y-R, Huang J-H, Hsiao Y-S (2019) Conductive PProDOT-Me₂–capped Li₄Ti₅O₁₂ microspheres with an optimized Ti³⁺/Ti⁴⁺ ratio for enhanced and rapid lithium-ion storage. Ceram Int 45:15252–15261CrossRef

30.

Osenciat N, Bérardan D, Dragoe D, Léridon B, Holé S, Meena AK, Franger S, Dragoe N (2019) Charge compensation mechanisms in Li^‐substituted high entropy oxides and influence on Li superionic conductivity. J Am Ceram Soc 102:6156–6162CrossRef

31.

Chen Z, Wang Z, Kim G-T, Yang G, Wang H, Wang X, Huang Y, Passerini S, Shen Z (2019) Enhancing the Electrochemical performance of LiNi_0.4Co_0.2Mn_0.4O₂ by V₂O₅/LiV₃O₈ Coating. ACS Appl Mater Interfaces 11:26994–27003CrossRef

32.

Shi W, Ding R, Xu QL, Yan T, Huang YX, Tan CN, Sun XJ, Gao P, Liu EH (2019) Vacancy defective perovskite Na_0.85Ni_0.45Co_0.55F_3.56 nanocrystal anodes for advanced lithium-ion storage driven by surface conversion and insertion hybrid mechanisms. Chem Commun 55:6739–6742CrossRef

33.

Zhang YN, Dong P, Zhao JB, Li X, Zhang YJ (2019) Simple solution-combustion synthesis of Fe₂TiO₅ nanomaterials with enhanced lithium storage properties. Ceram Int 45:11382–11387CrossRef

34.

Qiu CX, Yuan ZZ, Liu L, Cheng SJ, Liu JC (2013) Sol-gel synthesis and electrochemical performance of Li_4-xMg_xTi_5-xZr_xO₁₂ anode material for lithium-ion batteries. Chin J Chem 31:819–825CrossRef

35.

Han ZS, Kong FJ, He XL, Tao S, Jiang XF, Qian B (2019) CeO₂ nanoparticles embedded into one dimensional N doped carbon matrix as a high performance anode for lithium ion batteries. J Phys Chem Solids 134:187–192CrossRef

36.

Cai ZY, Xu L, Yan MY, Han CH, He L, Hercule KM, Niu CJ, Yuan ZF, Xu WW, Qu LB, Zhao KN, Mai LQ (2015) Manganese oxide/carbon yolk-shell nanorod anodes for high capacity lithium batteries. Nano Lett 15:738–744CrossRef

37.

Qiu N, Chen H, Yang ZM, Sun S, Wang Y, Cui YH (2019) A high entropy oxide (Mg_0.2Co_0.2Ni_0.2Cu_0.2Zn_0.2O) with superior lithium storage performance. J Alloys Compd 777:767–774CrossRef

38.

Sharma AS, Yadav S, Biswas K, Basu B (2018) High-entropy alloys and metallic nanocomposites: Processing challenges, microstructure development and property enhancement. Mater Sci Eng R Rep 131:1–42CrossRef

39.

Gu Y, Zhang X, Du Q, Li Y, Zhang M, Pan H, Qi X (2019) Electrochemical tuning induced oxygen vacancies for the photoluminescence enhancement. Ceram Int 46:4071–4078CrossRef

Title: A high-entropy perovskite titanate lithium-ion battery anode
Authors: Jinhua Yan
Dan Wang
Xiaoyan Zhang
Jinsheng Li
Qiang Du
Xinyue Liu
Jinrong Zhang
Xiwei Qi
Publication date: 02-03-2020
Publisher: Springer US
Published in: Journal of Materials Science / Issue 16/2020
Print ISSN: 0022-2461
Electronic ISSN: 1573-4803
DOI: https://doi.org/10.1007/s10853-020-04482-0

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