Skip to main content
Top

2021 | OriginalPaper | Chapter

A Mathematical Correlation of Compressive Strength Among Silica, Alumina and Calcia Present in Composite Red Mud and Iron Ore Tailingbricks

Authors : M. Beulah, Pranab Das, G. Gayathri, M. R. Sudhir, K. Sarath Chandra, P. Sasha Rai

Published in: Advances in Geotechnics and Structural Engineering

Publisher: Springer Singapore

Activate our intelligent search to find suitable subject content or patents.

search-config
loading …

Abstract

Waste Red Mud generated from bauxite beneficiation in aluminium industry contains sodium oxide in minor amount along with silica and alumina in significant quantities. Waste iron ore tailings from beneficiation of iron ore in steel industry contain silica and alumina in significant quantities. A combination of both these materials in different amounts along with GGBS and lime addition resulted in complex alkali-activated reaction products consisting of (Si/Al), (Ca/Si) and (Ca/(Si+Al)) complexes which influence compressive strength of the test samples on curing for extended time periods at room temperature. Individual correlation coefficients of these complexes with compressive strength yielded high values with (Si/Al) and (Ca/Si+Al) ratios (0.92 and 0.96, respectively) while showing a poor correlation coefficient with (Ca/Si) ratio (0.88). A direct regression analysis between compressive strength and (Si/Al) ratio and (Ca/Si+Al) ratio indicated negative values with (Si/Al) ratios but positive values with (Ca/ (Si+Al)) ratios. It is therefore concluded that the addition of lime and GGBS (contributed from both GGBS and lime addition) resulted in Ca-Si-Al complex formations which are responsible for improved compressive strength of the samples.

Dont have a licence yet? Then find out more about our products and how to get one now:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Springer Professional "Wirtschaft"

Online-Abonnement

Mit Springer Professional "Wirtschaft" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 340 Zeitschriften

aus folgenden Fachgebieten:

  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Versicherung + Risiko




Jetzt Wissensvorsprung sichern!

Literature
1.
go back to reference Ascensão G, Seabra MP, Aguiar JB, Labrincha JA (2017) Red Mud-based geopolymers with tailored alkali diffusion properties and pH buffering ability. J Clean Prod 148:23–30CrossRef Ascensão G, Seabra MP, Aguiar JB, Labrincha JA (2017) Red Mud-based geopolymers with tailored alkali diffusion properties and pH buffering ability. J Clean Prod 148:23–30CrossRef
2.
go back to reference He J, Jie Y, Zhang J, Yu Y, Zhang G (2013) Synthesis and characterization of Red Mud and rice husk ash-based geopolymer composites. Cem Concr Compos 37:108–118CrossRef He J, Jie Y, Zhang J, Yu Y, Zhang G (2013) Synthesis and characterization of Red Mud and rice husk ash-based geopolymer composites. Cem Concr Compos 37:108–118CrossRef
3.
go back to reference Provis JL, Lukey GC, Van Deventer JSJ (2005) Do geopolymers actually contain nanocrystalline zeolites? A re-examination of existing results. Chem Mater 17:3075–3085 Provis JL, Lukey GC, Van Deventer JSJ (2005) Do geopolymers actually contain nanocrystalline zeolites? A re-examination of existing results. Chem Mater 17:3075–3085
4.
go back to reference Xu H, Van Deventer JSJ (2002) Geo-polymerisation of multiple minerals. Miner Eng 15:1131–1139 Xu H, Van Deventer JSJ (2002) Geo-polymerisation of multiple minerals. Miner Eng 15:1131–1139
5.
go back to reference Juenger MCG, Winnefeld F, Provis JL, Ideker JH (2011) Advances in alternative cementitious binders. Cem Concr Res 41:1232–1243 Juenger MCG, Winnefeld F, Provis JL, Ideker JH (2011) Advances in alternative cementitious binders. Cem Concr Res 41:1232–1243
6.
go back to reference Koshy N, Dondrob K, Hu L, Wen Q, Meegoda JN (2019) Synthesis and characterization of geopolymers derived from coal gangue, fly ash and Red Mud. Constr Build Mater 206:287–296 Koshy N, Dondrob K, Hu L, Wen Q, Meegoda JN (2019) Synthesis and characterization of geopolymers derived from coal gangue, fly ash and Red Mud. Constr Build Mater 206:287–296
7.
go back to reference Zhang M, El-Korchi T, Zhang G, Liang J, Tao M (2014) Synthesis factors affecting mechanical properties, microstructure, and chemical composition of Red Mud-fly ash based geopolymers. Fuel 134:315–325CrossRef Zhang M, El-Korchi T, Zhang G, Liang J, Tao M (2014) Synthesis factors affecting mechanical properties, microstructure, and chemical composition of Red Mud-fly ash based geopolymers. Fuel 134:315–325CrossRef
8.
go back to reference Kumar A, Kumar S (2013) Development of paving blocks from synergistic use of Red Mud and fly ash using geo-polymerization. Constr Build Mater 38:865–871CrossRef Kumar A, Kumar S (2013) Development of paving blocks from synergistic use of Red Mud and fly ash using geo-polymerization. Constr Build Mater 38:865–871CrossRef
9.
go back to reference Hu W, Nie Q, Huang B, Shu X, He Q (2018) Mechanical and microstructural characterization of geopolymers derived from Red Mud and fly ashes. J Clean Prod 186:799–806CrossRef Hu W, Nie Q, Huang B, Shu X, He Q (2018) Mechanical and microstructural characterization of geopolymers derived from Red Mud and fly ashes. J Clean Prod 186:799–806CrossRef
10.
go back to reference Ducman V, Korat L (2016) Characterization of geopolymer fly-ash based foams obtained with the addition of Al powder or H2O2 as foaming agents. Mater Charact Ducman V, Korat L (2016) Characterization of geopolymer fly-ash based foams obtained with the addition of Al powder or H2O2 as foaming agents. Mater Charact
11.
go back to reference He J, Zhang J, Yu Y, Zhang G (2012) The strength and microstructure of two geopolymers derived from metakaolin and Red Mud-fly ash admixture: A comparative study. Constr Build Mater 30:80–91CrossRef He J, Zhang J, Yu Y, Zhang G (2012) The strength and microstructure of two geopolymers derived from metakaolin and Red Mud-fly ash admixture: A comparative study. Constr Build Mater 30:80–91CrossRef
12.
go back to reference Hajjaji W, Andrejkovičová S, Zanelli C, Alshaaer M, Dondi M, Labrincha JA, Rocha F (2013) Composition and technological properties of geopolymers based on metakaolin and Red Mud. Mater Des 52:648–654CrossRef Hajjaji W, Andrejkovičová S, Zanelli C, Alshaaer M, Dondi M, Labrincha JA, Rocha F (2013) Composition and technological properties of geopolymers based on metakaolin and Red Mud. Mater Des 52:648–654CrossRef
13.
go back to reference Geng JJ, Zhou M, Li Y, Chen Y, Han Y, Wan S, Zhou X, Hou H (2017) Comparison of Red Mud and coal gangue blended geopolymers synthesized through thermal activation and mechanical grinding pre-activation. Constr Build Mater 153:185–192CrossRef Geng JJ, Zhou M, Li Y, Chen Y, Han Y, Wan S, Zhou X, Hou H (2017) Comparison of Red Mud and coal gangue blended geopolymers synthesized through thermal activation and mechanical grinding pre-activation. Constr Build Mater 153:185–192CrossRef
14.
go back to reference Zhuang XY, Chen L, Komarneni S, Zhou CH, Tong DS, Yang HM, Yu WH, Wang H (2016) Fly ash-based geopolymer: clean production, properties and applications. J Clean Prod 125:253–267CrossRef Zhuang XY, Chen L, Komarneni S, Zhou CH, Tong DS, Yang HM, Yu WH, Wang H (2016) Fly ash-based geopolymer: clean production, properties and applications. J Clean Prod 125:253–267CrossRef
15.
go back to reference Wang SD, Scrivener KL, Pratt P (1994) Factors affecting the strength of alkali-activated slag. Cement Concr Res 24:1033–1043CrossRef Wang SD, Scrivener KL, Pratt P (1994) Factors affecting the strength of alkali-activated slag. Cement Concr Res 24:1033–1043CrossRef
16.
go back to reference Shi C, Qian J (2000) High performance cementing materials from industrial slags—a review. Resour Conserv Recycl 29:195–207CrossRef Shi C, Qian J (2000) High performance cementing materials from industrial slags—a review. Resour Conserv Recycl 29:195–207CrossRef
17.
go back to reference Li C, Sun H, Li L (2010) A review: the comparison between alkali-activated slag (Si+Ca) and metakaolin (Si+Al) cements. Cement Concrete Res 40:1341–1349CrossRef Li C, Sun H, Li L (2010) A review: the comparison between alkali-activated slag (Si+Ca) and metakaolin (Si+Al) cements. Cement Concrete Res 40:1341–1349CrossRef
18.
go back to reference Nicholson CL, Murray BJ, Fletcher RA, Brew D, Mackenzie KJ, Schmücker M (2005) Novel geopolymer materials containing borate structural units. In: World congress geopolymer (Saint-Quentin), pp 31–33 Nicholson CL, Murray BJ, Fletcher RA, Brew D, Mackenzie KJ, Schmücker M (2005) Novel geopolymer materials containing borate structural units. In: World congress geopolymer (Saint-Quentin), pp 31–33
20.
go back to reference Benavent V, Steins P, Sobrados I, Sanz J, Lambertin D, Frizon F et al (2016) Impact of aluminium on the structure of geopolymers from the early stages to consolidated material. Cement Concr Res 90:27–35CrossRef Benavent V, Steins P, Sobrados I, Sanz J, Lambertin D, Frizon F et al (2016) Impact of aluminium on the structure of geopolymers from the early stages to consolidated material. Cement Concr Res 90:27–35CrossRef
21.
go back to reference Ding Y, Dai JG, Shi CJ (2016) Mechanical properties of alkali-activated concrete: A state-of-the-art review. Constr Build Mater 127:68–79CrossRef Ding Y, Dai JG, Shi CJ (2016) Mechanical properties of alkali-activated concrete: A state-of-the-art review. Constr Build Mater 127:68–79CrossRef
22.
go back to reference Shang J, Dai JG, Zhao TJ, Guo SY, Zhang P, Mu B (2018) Alternation of traditional cement mortars using fly ash-based geopolymer mortars modified by slag. J Clean Prod 203:746–756CrossRef Shang J, Dai JG, Zhao TJ, Guo SY, Zhang P, Mu B (2018) Alternation of traditional cement mortars using fly ash-based geopolymer mortars modified by slag. J Clean Prod 203:746–756CrossRef
23.
go back to reference Xue X, Liu YL, Dai JG, Poon CS, Zhang WD, Zhang P (2018) Inhibiting efflorescence formation on fly ash-based geopolymer via silane surface modification. Cement Concr Compos 94:43–52CrossRef Xue X, Liu YL, Dai JG, Poon CS, Zhang WD, Zhang P (2018) Inhibiting efflorescence formation on fly ash-based geopolymer via silane surface modification. Cement Concr Compos 94:43–52CrossRef
24.
go back to reference Garcia-Lodeiro I, Palomo A, Fernandez-Jimenez A, Macphee DE (2011) Compatibility studies between N-A-S-H and C-A-S-H gels. Study in the ternary diagram Na2O–CaO–Al2O3–SiO2–H2O. Cement Concr Res 41(9):923–931 Garcia-Lodeiro I, Palomo A, Fernandez-Jimenez A, Macphee DE (2011) Compatibility studies between N-A-S-H and C-A-S-H gels. Study in the ternary diagram Na2O–CaO–Al2O3–SiO2–H2O. Cement Concr Res 41(9):923–931
25.
go back to reference Yip CK, Lukey GC, van Deventer JSJ (2005) The coexistence of geo-polymeric gel and calcium silicate hydrate at the early stage of alkaline activation. Cement Concr Res 35(9):1688–1697. ISSN 0008-5846 Yip CK, Lukey GC, van Deventer JSJ (2005) The coexistence of geo-polymeric gel and calcium silicate hydrate at the early stage of alkaline activation. Cement Concr Res 35(9):1688–1697. ISSN 0008-5846
26.
go back to reference Yip CK, Lukey GC, Provis JL, van Deventer JSJ (2008) Effect of calcium silicate sources on geo-polymerisation. Cement Concr Res 38:554–564 Yip CK, Lukey GC, Provis JL, van Deventer JSJ (2008) Effect of calcium silicate sources on geo-polymerisation. Cement Concr Res 38:554–564
27.
go back to reference Alonso S, Palomo A (2001) Calorimetric study of Alkaline activation of calcium hydroxide metakaolin solid mixtures. Influence Cement Concr Res 2001(31):25–30CrossRef Alonso S, Palomo A (2001) Calorimetric study of Alkaline activation of calcium hydroxide metakaolin solid mixtures. Influence Cement Concr Res 2001(31):25–30CrossRef
28.
go back to reference Alonso S, Palomo A (2001) Alkaline activation of metakaolin and calcium hydroxide mixtures: influence of temperature, activator concentration and solids ratio. Mater Lett 47:55–62 Alonso S, Palomo A (2001) Alkaline activation of metakaolin and calcium hydroxide mixtures: influence of temperature, activator concentration and solids ratio. Mater Lett 47:55–62
29.
go back to reference Suraneni P, Puligilla S, Kim E (2014) Monitoring setting of geopolymers. Adv Civil Engg Mater 2014(3):177–192 ASTM International Suraneni P, Puligilla S, Kim E (2014) Monitoring setting of geopolymers. Adv Civil Engg Mater 2014(3):177–192 ASTM International
30.
go back to reference Lee W, Van Deventer J (2002) The effect of ionic contaminants on the early-age properties of alkali-activated fly ash-based cements. Cement Concr Res 32:577–584CrossRef Lee W, Van Deventer J (2002) The effect of ionic contaminants on the early-age properties of alkali-activated fly ash-based cements. Cement Concr Res 32:577–584CrossRef
31.
go back to reference Yip CK, van Deventer JSJ (2003) Microanalysis of calcium silicate hydrate gel formed within a geo-polymeric binder. J Mater Sci 38:3851–3860CrossRef Yip CK, van Deventer JSJ (2003) Microanalysis of calcium silicate hydrate gel formed within a geo-polymeric binder. J Mater Sci 38:3851–3860CrossRef
32.
go back to reference Temuujin J, van Riessen A, Williams R (2009) Influence of calcium compounds on the mechanical properties of fly ash geopolymer pastes. J Hazard Mater 167:82–88 Temuujin J, van Riessen A, Williams R (2009) Influence of calcium compounds on the mechanical properties of fly ash geopolymer pastes. J Hazard Mater 167:82–88
33.
go back to reference Van Jaarsveld JGS, Van Deventer JSJ, Lorenzen L (1997) The potential use of geo-polymeric materials to immobilise toxic metals: Part 1. Theory and applications. Miner Eng 10(7):659–669CrossRef Van Jaarsveld JGS, Van Deventer JSJ, Lorenzen L (1997) The potential use of geo-polymeric materials to immobilise toxic metals: Part 1. Theory and applications. Miner Eng 10(7):659–669CrossRef
34.
go back to reference Van Jaarsveld JGS, Van Deventer JSJ, Lorenzen L (1998) Factors affecting the immobilisation of metals in geo-polymerisedflyash. Metall Mater Trans B 29B:283–291CrossRef Van Jaarsveld JGS, Van Deventer JSJ, Lorenzen L (1998) Factors affecting the immobilisation of metals in geo-polymerisedflyash. Metall Mater Trans B 29B:283–291CrossRef
35.
go back to reference Van Jaarsveld JGS, Van Deventer JSJ, Schwartzman A (1999) The potential use of geo-polymeric materials to immobilise toxic metals: Part II. Material and leaching characteristics. Miner Eng 12(1):75–91CrossRef Van Jaarsveld JGS, Van Deventer JSJ, Schwartzman A (1999) The potential use of geo-polymeric materials to immobilise toxic metals: Part II. Material and leaching characteristics. Miner Eng 12(1):75–91CrossRef
36.
go back to reference Van Jaarsveld JGS, van Deventer JSJ (1999) Effect of the alkali metal activator on the properties of fly ashbasedgeopolymers. Ind Eng Chem Res 38(10):3932–3941CrossRef Van Jaarsveld JGS, van Deventer JSJ (1999) Effect of the alkali metal activator on the properties of fly ashbasedgeopolymers. Ind Eng Chem Res 38(10):3932–3941CrossRef
37.
go back to reference Van Jaarsveld JGS (2000) The physical and chemical characteristics of fly ash based geopolymers. PhD Thesis, The University of Melbourne Van Jaarsveld JGS (2000) The physical and chemical characteristics of fly ash based geopolymers. PhD Thesis, The University of Melbourne
38.
go back to reference Glukhovsky VD (1994) Ancient, modern and future concretes. In: Krivenko PV (ed) Proceedings of the first international conference on alkaline cements and concretes. VIPOL Stock Company, Kiev, Ukraine, pp 1–9 Glukhovsky VD (1994) Ancient, modern and future concretes. In: Krivenko PV (ed) Proceedings of the first international conference on alkaline cements and concretes. VIPOL Stock Company, Kiev, Ukraine, pp 1–9
39.
go back to reference Chen X, Sutrisno A, Struble L (2018) Effects of calcium on setting of metakaolin based geopolymer. J Am Ceram Soc 101:957–968CrossRef Chen X, Sutrisno A, Struble L (2018) Effects of calcium on setting of metakaolin based geopolymer. J Am Ceram Soc 101:957–968CrossRef
40.
go back to reference Pulgalia S, Mondal P (2015) Co-existence of aluminosilicate and calcium silicate gel characterized through selective dissolution and FTR spectral subtraction. Cement Concr Res 70:39–49 Pulgalia S, Mondal P (2015) Co-existence of aluminosilicate and calcium silicate gel characterized through selective dissolution and FTR spectral subtraction. Cement Concr Res 70:39–49
Metadata
Title
A Mathematical Correlation of Compressive Strength Among Silica, Alumina and Calcia Present in Composite Red Mud and Iron Ore Tailingbricks
Authors
M. Beulah
Pranab Das
G. Gayathri
M. R. Sudhir
K. Sarath Chandra
P. Sasha Rai
Copyright Year
2021
Publisher
Springer Singapore
DOI
https://doi.org/10.1007/978-981-33-6969-6_29