Skip to main content
Top

2023 | OriginalPaper | Chapter

A Modified Thermodynamic Software to Control the Composition of Inclusions During Calcium Treatment Process

Authors : Weijian Wang, Lifeng Zhang

Published in: Materials Processing Fundamentals 2023

Publisher: Springer Nature Switzerland

Activate our intelligent search to find suitable subject content or patents.

search-config
loading …

Abstract

Based on the minimum Gibbs free energy method, a modified thermodynamic model was established to predict the composition of inclusions during the calcium treatment process. Three types of phase were contained in the steel-inclusion system, including the molten steel phase, the liquid inclusions phase, and the solid inclusions phase. The Wanger model was applied to calculated activities of elements in the molten steel. Reported interaction parameters were evaluated and used to improve the accuracy of thermodynamic calculation results. The coexistence theory was applied to calculate activities of Al2O3 and CaO in liquid inclusions. According to the thermodynamic calculations, the effect of T.Ca content in the molten steel on the transformation of inclusions was discussed. Combining the established thermodynamic model and a calcium yield prediction model, a software for precise control of calcium treatment process was also developed.

Dont have a licence yet? Then find out more about our products and how to get one now:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Springer Professional "Wirtschaft"

Online-Abonnement

Mit Springer Professional "Wirtschaft" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 340 Zeitschriften

aus folgenden Fachgebieten:

  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Versicherung + Risiko




Jetzt Wissensvorsprung sichern!

Literature
1.
go back to reference Choudhary SK, Ghosh A (2008) Thermodynamic evaluation of formation of oxide—sulfide duplex inclusions in steel. ISIJ Int 48(11):1552–1559CrossRef Choudhary SK, Ghosh A (2008) Thermodynamic evaluation of formation of oxide—sulfide duplex inclusions in steel. ISIJ Int 48(11):1552–1559CrossRef
2.
go back to reference Zhang L, Thomas BG, Associate R (2002) Alumina inclusion behavior during steel deoxidation. In: 7th European electric steelmaking conference, Venice, Italy, pp 77–86 Zhang L, Thomas BG, Associate R (2002) Alumina inclusion behavior during steel deoxidation. In: 7th European electric steelmaking conference, Venice, Italy, pp 77–86
3.
go back to reference Zhang L, Thomas BG (2006) State of the art in the control of inclusions during steel ingot casting. Metall and Mater Trans B 37(5):733–761CrossRef Zhang L, Thomas BG (2006) State of the art in the control of inclusions during steel ingot casting. Metall and Mater Trans B 37(5):733–761CrossRef
4.
go back to reference Wang QY, Bathias C, Kawagoishi N, Chen Q (2002) Effect of inclusion on subsurface crack initiation and gigacycle fatigue strength. Int J Fatigue 24(12):1269–1274CrossRef Wang QY, Bathias C, Kawagoishi N, Chen Q (2002) Effect of inclusion on subsurface crack initiation and gigacycle fatigue strength. Int J Fatigue 24(12):1269–1274CrossRef
5.
go back to reference Larsson M, Melander A, Nordgren A (1993) Effect of inclusions on fatigue behaviour of hardened spring steel. Mater Sci Technol 9(3):235–245CrossRef Larsson M, Melander A, Nordgren A (1993) Effect of inclusions on fatigue behaviour of hardened spring steel. Mater Sci Technol 9(3):235–245CrossRef
6.
go back to reference Lamut J, Falkus J, Jurjevec B, Knap M (2012) Influence of inclusions modification on nozzle clogging. Arch Metall Mater 57(1):319–324CrossRef Lamut J, Falkus J, Jurjevec B, Knap M (2012) Influence of inclusions modification on nozzle clogging. Arch Metall Mater 57(1):319–324CrossRef
7.
go back to reference Ren Q, Yang W, Cheng L, Hu Z, Zhang L (2020) Effect of calcium treatment on magnetic properties of non-oriented electrical steels. J Magnetism and Magnetic Mater 494 Ren Q, Yang W, Cheng L, Hu Z, Zhang L (2020) Effect of calcium treatment on magnetic properties of non-oriented electrical steels. J Magnetism and Magnetic Mater 494
8.
go back to reference Li M, Liu Y, Zhang L (2019) Effect of reoxidation on inclusions in steel during calcium treatment. Metallurgical Res Technol 116(2):206–214CrossRef Li M, Liu Y, Zhang L (2019) Effect of reoxidation on inclusions in steel during calcium treatment. Metallurgical Res Technol 116(2):206–214CrossRef
9.
go back to reference Zhang L, Liu Y, Zhang Y, Yang W, Chen W (2018) Transient evolution of nonmetallic inclusions during calcium treatment of molten steel. Metall and Mater Trans B 49(4):1841–1859CrossRef Zhang L, Liu Y, Zhang Y, Yang W, Chen W (2018) Transient evolution of nonmetallic inclusions during calcium treatment of molten steel. Metall and Mater Trans B 49(4):1841–1859CrossRef
10.
go back to reference Liu Y, Zhang L (2018) Relationship between dissolved calcium and total calcium in Al-killed steels after calcium treatment. Metall and Mater Trans B 49(4):1624–1631CrossRef Liu Y, Zhang L (2018) Relationship between dissolved calcium and total calcium in Al-killed steels after calcium treatment. Metall and Mater Trans B 49(4):1624–1631CrossRef
11.
go back to reference Yang W, Zhang L, Wang X, Ren Y, Liu X, Shan Q (2013) Characteristics of inclusions in low carbon al-killed steel during ladle furnace refining and calcium treatment. ISIJ Int 53(8):1401–1410CrossRef Yang W, Zhang L, Wang X, Ren Y, Liu X, Shan Q (2013) Characteristics of inclusions in low carbon al-killed steel during ladle furnace refining and calcium treatment. ISIJ Int 53(8):1401–1410CrossRef
12.
go back to reference Zhang L (2019) Non-metallic inclusions in steels: fundamentals (in Chinese). Metallurgical Industry Press, Beijing Zhang L (2019) Non-metallic inclusions in steels: fundamentals (in Chinese). Metallurgical Industry Press, Beijing
13.
go back to reference Zhang L (2019) Non-metallic inclusions in steels: industrial practice (in Chinese). Metallurgical Industry Press, Beijing Zhang L (2019) Non-metallic inclusions in steels: industrial practice (in Chinese). Metallurgical Industry Press, Beijing
14.
go back to reference Wang W, Zhang L, Ren Y, Luo Y, Sun X, Yang W (2021) Prediction of calcium yield during calcium treatment process performed in steelmaking using neural network. Metall and Mater Trans B 53(1):1–7CrossRef Wang W, Zhang L, Ren Y, Luo Y, Sun X, Yang W (2021) Prediction of calcium yield during calcium treatment process performed in steelmaking using neural network. Metall and Mater Trans B 53(1):1–7CrossRef
15.
go back to reference Wang W, Luo Y, Sun X, Zhang L (2019) Study on effect of calcium treatment on inclusions evolution mechanism and Ca yield. In: Ladle refining 2019 annual meeting proceedings. Suzhou, China, pp 416−420 Wang W, Luo Y, Sun X, Zhang L (2019) Study on effect of calcium treatment on inclusions evolution mechanism and Ca yield. In: Ladle refining 2019 annual meeting proceedings. Suzhou, China, pp 416−420
16.
go back to reference Sun X, Wang W, Luo Y, Zhang J, Ren Y, Zhang L (2019) Evolution of inclusions in high-sulfur and low-oxygen steels after calcium treatment. In: AISTech 2019-proceedings of the iron and steel technology conference Pittsburgh, Pa., USA, pp 1233–1247 Sun X, Wang W, Luo Y, Zhang J, Ren Y, Zhang L (2019) Evolution of inclusions in high-sulfur and low-oxygen steels after calcium treatment. In: AISTech 2019-proceedings of the iron and steel technology conference Pittsburgh, Pa., USA, pp 1233–1247
17.
go back to reference Suito H, Inoue R (1996) Thermodynamics on control of inclusions composition in ultra-clean steels. ISIJ Int 36(3):528–536CrossRef Suito H, Inoue R (1996) Thermodynamics on control of inclusions composition in ultra-clean steels. ISIJ Int 36(3):528–536CrossRef
18.
go back to reference Wan Y, Chen W, Zhang S (2014) Thermodynamic analysis and experimental research of 50W600 non-oriented silicon steel after calcium treatment. Shanghai Metals 36(1):37–41 Wan Y, Chen W, Zhang S (2014) Thermodynamic analysis and experimental research of 50W600 non-oriented silicon steel after calcium treatment. Shanghai Metals 36(1):37–41
Metadata
Title
A Modified Thermodynamic Software to Control the Composition of Inclusions During Calcium Treatment Process
Authors
Weijian Wang
Lifeng Zhang
Copyright Year
2023
DOI
https://doi.org/10.1007/978-3-031-22657-1_12

Premium Partners