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Journal of Materials Science
Published in: Journal of Materials Science 11/2018

28-02-2018 | Energy materials

A new sodium ferrous orthophosphate Na x Fe4(PO4)3 as anode materials for sodium-ion batteries

Authors: Hui Zhang, Yanming Zhao, Mingming Wen, Youzhong Dong, Qinghua Fan, Quan Kuang, Huatao Liu, Xin Lian

Published in: Journal of Materials Science | Issue 11/2018

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Abstract

A new sodium ferrous orthophosphate Na x Fe4(PO4)3 (1.1 ≤ x ≤ 1.2) with P21/n symmetry has been successfully synthesized via a solid-state reaction for the first time. The structure consists of FeO5 pyramids, FeO6 octahedron, and PO4 tetrahedra which form large six-sided tunnels along \( \vec{b} \) direction and three- or four-sided tunnels running along \( \vec{a} \) direction. When evaluated as the anode materials for sodium-ion batteries, the first discharge and charge capacities of 553 and 264 mAh g−1 for Na1.1Fe4(PO4)3/C and 583 and 315 mAh g−1 for Na1.2Fe4(PO4)3/C, respectively, can be obtained at 10 mA g−1 current density. Compared to the Na1.1Fe4(PO4)3/C, Na1.2Fe4(PO4)3/C exhibits a better cycling performance, where the charge capacity of about 100 mAh g−1 can still be maintained after 15 cycles. The electrode kinetics are investigated further by the electrochemical impedance spectroscopy.
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Metadata
Title
A new sodium ferrous orthophosphate Na x Fe4(PO4)3 as anode materials for sodium-ion batteries
Authors
Hui Zhang
Yanming Zhao
Mingming Wen
Youzhong Dong
Qinghua Fan
Quan Kuang
Huatao Liu
Xin Lian
Publication date
28-02-2018
Publisher
Springer US
Published in
Journal of Materials Science / Issue 11/2018
Print ISSN: 0022-2461
Electronic ISSN: 1573-4803
DOI
https://doi.org/10.1007/s10853-018-2128-4

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