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Journal of Materials Science
Published in: Journal of Materials Science 34/2020

08-09-2020 | Chemical routes to materials

A novel amorphous CoSx/NH2-MIL-125 composite for photocatalytic degradation of rhodamine B under visible light

Authors: Shengjun Liu, Qichao Zou, Yan Ma, Wen Sun, Yu Li, Jian Zhang, Cheng Zhang, Lifang He, Yudie Sun, Qian Chen, Bo Liu, Hexin Zhang, Kui Zhang

Published in: Journal of Materials Science | Issue 34/2020

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Abstract

Metal–organic frameworks (MOFs) are a new type of porous crystal materials that have been widely used in various fields. Owing to their adjustable porous structure, MOF photocatalysts with high catalytic activity have become a research hotspot. In this study, NH2-MIL-125/CoSx samples were investigated as a novel visible light-responsive catalyst for the removal of organic dye. The NH2-MIL-125/CoSx-20 composites showed the best photodegradation efficiency, where photodegradation of the rhodamine B reached 95.4% in 45 min. CoSx was able to effectively extend the wavelength absorption range of NH2-MIL-125 and effectively separate the photogenerated electrons and holes and that could lead to the improved photocatalytic performance of the composites. The reactive superoxide radical (·O2−) was identified as the main active species using reactive species capture experiments, and a reasonable photocatalytic mechanism was proposed. This paper is intended to guide the development of organic–inorganic hybrid materials for environmental remediation.
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Appendix
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Metadata
Title
A novel amorphous CoSx/NH2-MIL-125 composite for photocatalytic degradation of rhodamine B under visible light
Authors
Shengjun Liu
Qichao Zou
Yan Ma
Wen Sun
Yu Li
Jian Zhang
Cheng Zhang
Lifang He
Yudie Sun
Qian Chen
Bo Liu
Hexin Zhang
Kui Zhang
Publication date
08-09-2020
Publisher
Springer US
Published in
Journal of Materials Science / Issue 34/2020
Print ISSN: 0022-2461
Electronic ISSN: 1573-4803
DOI
https://doi.org/10.1007/s10853-020-05210-4

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