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Published in: Tribology Letters 1/2016

01-07-2016 | Original Paper

Accelerated Formation of Tribo-oxide Layer and Its Effect on Sliding Wear of a Titanium Alloy

Authors: Q. Y. Zhang, Y. Zhou, X. X. Li, L. Wang, X. H. Cui, S. Q. Wang

Published in: Tribology Letters | Issue 1/2016

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Abstract

Sliding wear tests of Ti–6Al–4V alloy against AISI 52100 steel were performed at room temperature. For the sake of improving the worse wear performance of the titanium alloy, an attempt of inducing the accelerated formation of protective tribo-oxide layers was made by artificially supplying nanoscale oxides of TiO2, Fe2O3 or their mixtures onto sliding tracks. Fe2O3 nanoparticles were noticed to have an advantage over TiO2 in the formation of sustainable tribo-oxide layers under higher load, which was ascribed to their rapid sintering rate and excellent load-carrying capability. The existence of Fe2O3 and Fe2O3-rich tribo-layers markedly reduced the wear rate of Ti–6Al–4V alloy under 10–50 N, whereas TiO2 and TiO2-rich nanoparticles as abrasives promoted wear in most cases. Clearly, TiO2 and Fe2O3 nano-oxides as main ingredients of tribo-layers presented the opposite function in the sliding wear of Ti–6Al–4V alloy. In the titanium alloy/steel sliding system, the wear-reducing function of tribo-layers was suggested to be attributed to the appearance of Fe2O3, not TiO2.

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Literature
1.
go back to reference Miller, P.D., Holladay, J.W.: Friction and wear properties of titanium. Wear 2, 133–140 (1958/1959) Miller, P.D., Holladay, J.W.: Friction and wear properties of titanium. Wear 2, 133–140 (1958/1959)
2.
go back to reference Budinski, K.G.: Tribological properties of titanium alloys. Wear 151, 203–217 (1991)CrossRef Budinski, K.G.: Tribological properties of titanium alloys. Wear 151, 203–217 (1991)CrossRef
3.
go back to reference Lebedeva, I.L., Presnyakova, G.N.: Adhesion wear mechanisms under dry friction of titanium alloys in vacuum. Wear 148, 203–210 (1991)CrossRef Lebedeva, I.L., Presnyakova, G.N.: Adhesion wear mechanisms under dry friction of titanium alloys in vacuum. Wear 148, 203–210 (1991)CrossRef
4.
go back to reference Long, M., Rack, H.J.: Friction and surface behavior of selected titanium alloys during reciprocating-sliding motion. Wear 249, 157–167 (2001)CrossRef Long, M., Rack, H.J.: Friction and surface behavior of selected titanium alloys during reciprocating-sliding motion. Wear 249, 157–167 (2001)CrossRef
5.
go back to reference Majumdar, P., Singh, S.B., Chakraborty, M.: Wear properties of Ti–13Zr–13Nb (wt. %) near β titanium alloy containing 0.5 wt. % boron in dry condition, Hank’s solution and bovine serum. Mater. Sci. Eng., C 30, 1065–1075 (2010)CrossRef Majumdar, P., Singh, S.B., Chakraborty, M.: Wear properties of Ti–13Zr–13Nb (wt. %) near β titanium alloy containing 0.5 wt. % boron in dry condition, Hank’s solution and bovine serum. Mater. Sci. Eng., C 30, 1065–1075 (2010)CrossRef
6.
go back to reference Lee, Y.S., Niinomi, M., Nakai, M., Naritab, K., Cho, K.: Predominant factor determining wear properties of β-type and (α + β)-type titanium alloys in metal-to-metal contact for biomedical applications. J. Mech. Behav. Biomed. Mater. 41, 208–220 (2015)CrossRef Lee, Y.S., Niinomi, M., Nakai, M., Naritab, K., Cho, K.: Predominant factor determining wear properties of β-type and (α + β)-type titanium alloys in metal-to-metal contact for biomedical applications. J. Mech. Behav. Biomed. Mater. 41, 208–220 (2015)CrossRef
7.
go back to reference Qiu, M., Zhang, Y.Z., Bao, S.G., Du, S.M., Yan, Z.W.: The relationships between tribological behaviour and heat-transfer capability of Ti6Al4V alloys. Wear 263, 653–657 (2007)CrossRef Qiu, M., Zhang, Y.Z., Bao, S.G., Du, S.M., Yan, Z.W.: The relationships between tribological behaviour and heat-transfer capability of Ti6Al4V alloys. Wear 263, 653–657 (2007)CrossRef
8.
go back to reference Molinari, A., Straffelini, G., Tesi, B., Bacci, T.: Dry sliding wear mechanisms of the Ti6Al4V alloy. Wear 208, 105–112 (1997)CrossRef Molinari, A., Straffelini, G., Tesi, B., Bacci, T.: Dry sliding wear mechanisms of the Ti6Al4V alloy. Wear 208, 105–112 (1997)CrossRef
9.
go back to reference Straffelini, G., Molinari, A.: Dry sliding wear of Ti–6Al–4V alloy as influenced by the counterface and sliding conditions. Wear 236, 328–338 (1999)CrossRef Straffelini, G., Molinari, A.: Dry sliding wear of Ti–6Al–4V alloy as influenced by the counterface and sliding conditions. Wear 236, 328–338 (1999)CrossRef
10.
go back to reference Sahoo, R., Jha, B.B., Sahoo, T.K.: Dry sliding wear behaviour of Ti–6Al–4V alloy consisting of bimodal microstructure. Trans. Indian Inst. Met. 67, 239–245 (2014)CrossRef Sahoo, R., Jha, B.B., Sahoo, T.K.: Dry sliding wear behaviour of Ti–6Al–4V alloy consisting of bimodal microstructure. Trans. Indian Inst. Met. 67, 239–245 (2014)CrossRef
11.
go back to reference Qiu, M., Zhang, Y.Z., Zhu, J., Yang, J.H.: Correlation between the characteristics of the thermo-mechanical mixed layer and wear behaviour of Ti–6Al–4V alloy. Tribol. Lett. 22, 227–231 (2006)CrossRef Qiu, M., Zhang, Y.Z., Zhu, J., Yang, J.H.: Correlation between the characteristics of the thermo-mechanical mixed layer and wear behaviour of Ti–6Al–4V alloy. Tribol. Lett. 22, 227–231 (2006)CrossRef
12.
go back to reference Qiu, M., Zhang, Y.Z., Yang, J.H., Zhu, J.: Microstructure and tribological characteristics of Ti–6Al–4V alloy against GCr15 under high speed and dry sliding. Mater. Sci. Eng., A 434, 71–75 (2006)CrossRef Qiu, M., Zhang, Y.Z., Yang, J.H., Zhu, J.: Microstructure and tribological characteristics of Ti–6Al–4V alloy against GCr15 under high speed and dry sliding. Mater. Sci. Eng., A 434, 71–75 (2006)CrossRef
13.
go back to reference Henry, P., Takadoum, J., Berçot, P.: Tribocorrosion of 316L stainless steel and TA6V4 alloy in H2SO4 media. Corros. Sci. 51, 1308–1314 (2009)CrossRef Henry, P., Takadoum, J., Berçot, P.: Tribocorrosion of 316L stainless steel and TA6V4 alloy in H2SO4 media. Corros. Sci. 51, 1308–1314 (2009)CrossRef
14.
go back to reference Henry, P., Takadoum, J., Berçot, P.: Depassivation of some metals by sliding friction. Corros. Sci. 53, 320–328 (2011)CrossRef Henry, P., Takadoum, J., Berçot, P.: Depassivation of some metals by sliding friction. Corros. Sci. 53, 320–328 (2011)CrossRef
15.
go back to reference Dong, H., Bell, T.: Enhanced wear resistance of titanium surfaces by a new thermal oxidation treatment. Wear 238, 131–137 (2000)CrossRef Dong, H., Bell, T.: Enhanced wear resistance of titanium surfaces by a new thermal oxidation treatment. Wear 238, 131–137 (2000)CrossRef
16.
go back to reference Zhou, Y., Zhang, Q.Y., Liu, J.Q., Cui, X.H., Mo, J.G., Wang, S.Q.: Wear characteristics of a thermally oxidized and vacuum diffusion heat treated coating on Ti–6Al–4V alloy. Wear 344–345, 9–21 (2015)CrossRef Zhou, Y., Zhang, Q.Y., Liu, J.Q., Cui, X.H., Mo, J.G., Wang, S.Q.: Wear characteristics of a thermally oxidized and vacuum diffusion heat treated coating on Ti–6Al–4V alloy. Wear 344–345, 9–21 (2015)CrossRef
17.
go back to reference Pawlak, W., Kubiak, K.J., Wendler, B.G., Mathia, T.G.: Wear resistant multilayer nanocomposite WC1-x/C coating on Ti–6Al–4V titanium alloy. Tribol. Int. 82, 400–406 (2015)CrossRef Pawlak, W., Kubiak, K.J., Wendler, B.G., Mathia, T.G.: Wear resistant multilayer nanocomposite WC1-x/C coating on Ti–6Al–4V titanium alloy. Tribol. Int. 82, 400–406 (2015)CrossRef
18.
go back to reference Ohidul Alam, Md., Haseeb, A.S.M.A.: Response of Ti–6Al–4V and Ti–24Al–11Nb alloys to dry sliding wear against hardened steel. Tribol. Int. 35, 357–362 (2002)CrossRef Ohidul Alam, Md., Haseeb, A.S.M.A.: Response of Ti–6Al–4V and Ti–24Al–11Nb alloys to dry sliding wear against hardened steel. Tribol. Int. 35, 357–362 (2002)CrossRef
19.
go back to reference Guo, S., Zheng, Q., Hou, X.L., Cheng, X.N., Zhao, X.Q.: Wear response of metastable b-type Ti–25Nb–2Mo–4Sn alloy for biomedical applications. Rare Met. 34, 564–568 (2015)CrossRef Guo, S., Zheng, Q., Hou, X.L., Cheng, X.N., Zhao, X.Q.: Wear response of metastable b-type Ti–25Nb–2Mo–4Sn alloy for biomedical applications. Rare Met. 34, 564–568 (2015)CrossRef
20.
go back to reference Chelliah, N., Kailas, S.V.: Synergy between tribo-oxidation and strain rate response on governing the dry sliding wear behavior of titanium. Wear 266, 704–712 (2009)CrossRef Chelliah, N., Kailas, S.V.: Synergy between tribo-oxidation and strain rate response on governing the dry sliding wear behavior of titanium. Wear 266, 704–712 (2009)CrossRef
21.
go back to reference Mao, Y.S., Wang, L., Chen, K.M., Wang, S.Q., Cui, X.H.: Tribo-layer and its role in dry sliding wear of Ti–6Al–4V alloy. Wear 297, 1032–1039 (2013)CrossRef Mao, Y.S., Wang, L., Chen, K.M., Wang, S.Q., Cui, X.H.: Tribo-layer and its role in dry sliding wear of Ti–6Al–4V alloy. Wear 297, 1032–1039 (2013)CrossRef
22.
go back to reference Wang, L., Zhang, Q.Y., Li, X.X., Cui, X.H., Wang, S.Q.: Severe-to-mild wear transition of titanium alloys as a function of temperature. Tribol. Lett. 53, 511–520 (2014)CrossRef Wang, L., Zhang, Q.Y., Li, X.X., Cui, X.H., Wang, S.Q.: Severe-to-mild wear transition of titanium alloys as a function of temperature. Tribol. Lett. 53, 511–520 (2014)CrossRef
23.
go back to reference Wang, L., Zhang, Q.Y., Li, X.X., Cui, X.H., Wang, S.Q.: Dry sliding wear behavior of Ti–6.5Al–3.5Mo–1.5Zr–0.3Si alloy. Metall. Mater. Trans. A 45, 2284–2296 (2014)CrossRef Wang, L., Zhang, Q.Y., Li, X.X., Cui, X.H., Wang, S.Q.: Dry sliding wear behavior of Ti–6.5Al–3.5Mo–1.5Zr–0.3Si alloy. Metall. Mater. Trans. A 45, 2284–2296 (2014)CrossRef
24.
go back to reference Chen, K.M., Zhou, Y., Li, X.X., Zhang, Q.Y., Wang, L., Wang, S.Q.: Investigation on wear characteristics of a titanium alloy/steel tribo-pair. Mater. Des. 65, 65–73 (2015)CrossRef Chen, K.M., Zhou, Y., Li, X.X., Zhang, Q.Y., Wang, L., Wang, S.Q.: Investigation on wear characteristics of a titanium alloy/steel tribo-pair. Mater. Des. 65, 65–73 (2015)CrossRef
25.
go back to reference Li, X.X., Zhou, Y., Li, Y.X., Ji, X.L., Wang, S.Q.: Dry sliding wear characteristics of Ti–6.5Al–3.5Mo–1.5Zr–0.3Si alloy at various sliding speeds. Metall. Mater. Trans. A 46A, 4360–4368 (2015)CrossRef Li, X.X., Zhou, Y., Li, Y.X., Ji, X.L., Wang, S.Q.: Dry sliding wear characteristics of Ti–6.5Al–3.5Mo–1.5Zr–0.3Si alloy at various sliding speeds. Metall. Mater. Trans. A 46A, 4360–4368 (2015)CrossRef
26.
go back to reference Li, X.X., Zhou, Y., Ji, X.L., Li, Y.X., Wang, S.Q.: Effects of sliding velocity on tribo-oxides and wear behavior of Ti–6Al–4V alloy. Tribol. Int. 91, 228–234 (2015)CrossRef Li, X.X., Zhou, Y., Ji, X.L., Li, Y.X., Wang, S.Q.: Effects of sliding velocity on tribo-oxides and wear behavior of Ti–6Al–4V alloy. Tribol. Int. 91, 228–234 (2015)CrossRef
27.
go back to reference Zhang, Q.Y., Zhou, Y., Wang, L., Cui, X.H., Wang, S.Q.: Investigation on tribo-layers and their function of a titanium alloy during dry sliding. Tribol. Int. 94, 541–549 (2016)CrossRef Zhang, Q.Y., Zhou, Y., Wang, L., Cui, X.H., Wang, S.Q.: Investigation on tribo-layers and their function of a titanium alloy during dry sliding. Tribol. Int. 94, 541–549 (2016)CrossRef
28.
go back to reference Farokhzadeh, K., Edrisy, A.: Transition between mild and severe wear in titanium alloys. Tribol. Int. 94, 98–111 (2016)CrossRef Farokhzadeh, K., Edrisy, A.: Transition between mild and severe wear in titanium alloys. Tribol. Int. 94, 98–111 (2016)CrossRef
29.
30.
go back to reference Stott, F.H.: High-temperature sliding wear of metals. Tribol. Int. 35, 489–495 (2002)CrossRef Stott, F.H.: High-temperature sliding wear of metals. Tribol. Int. 35, 489–495 (2002)CrossRef
31.
go back to reference Iwabuchi, A., Kubosawa, H., Hori, K.: The dependence of the transition from severe to mild wear on load and surface roughness when the oxide particles are supplied before sliding. Wear 139, 319–333 (1990)CrossRef Iwabuchi, A., Kubosawa, H., Hori, K.: The dependence of the transition from severe to mild wear on load and surface roughness when the oxide particles are supplied before sliding. Wear 139, 319–333 (1990)CrossRef
32.
go back to reference Iwabuchi, A., Hori, K., Kubosawa, H.: The effect of oxide particles supplied at the interface before sliding on the severe–mild wear transition. Wear 128, 123–137 (1988)CrossRef Iwabuchi, A., Hori, K., Kubosawa, H.: The effect of oxide particles supplied at the interface before sliding on the severe–mild wear transition. Wear 128, 123–137 (1988)CrossRef
33.
go back to reference Ludema, K.C.: Third bodies in wear models. In: Dowson, D. (ed.) Wear Particles, pp. 155–160. Elsevier, Amsterdam (1992) Ludema, K.C.: Third bodies in wear models. In: Dowson, D. (ed.) Wear Particles, pp. 155–160. Elsevier, Amsterdam (1992)
34.
go back to reference Leheup, E.R., Pendlebury, R.E.: Unlubricated reciprocating wear of stainless steel with an interfacial air flow. Wear 142, 351–372 (1991)CrossRef Leheup, E.R., Pendlebury, R.E.: Unlubricated reciprocating wear of stainless steel with an interfacial air flow. Wear 142, 351–372 (1991)CrossRef
35.
go back to reference Hiratsuka, K., Muramoto, K.: Role of wear particles in severe–mild wear transition. Wear 259, 467–476 (2005)CrossRef Hiratsuka, K., Muramoto, K.: Role of wear particles in severe–mild wear transition. Wear 259, 467–476 (2005)CrossRef
36.
go back to reference German, R.M.: Powder Metallurgy Science. MPIF, Princeton (1984) German, R.M.: Powder Metallurgy Science. MPIF, Princeton (1984)
37.
go back to reference Kato, H., Komai, K.: Tribofilm formation and mild wear by tribo-sintering of nanometer-sized oxide particles on rubbing steel surfaces. Wear 262, 36–41 (2007)CrossRef Kato, H., Komai, K.: Tribofilm formation and mild wear by tribo-sintering of nanometer-sized oxide particles on rubbing steel surfaces. Wear 262, 36–41 (2007)CrossRef
38.
go back to reference Brown, A.M., Ashby, M.F.: Correlations for diffusion constants. Acta Metall. 28, 1085–1101 (1980)CrossRef Brown, A.M., Ashby, M.F.: Correlations for diffusion constants. Acta Metall. 28, 1085–1101 (1980)CrossRef
39.
go back to reference Archard, J.F.: The temperature of rubbing surfaces. Wear 2, 438–455 (1958–1959) Archard, J.F.: The temperature of rubbing surfaces. Wear 2, 438–455 (1958–1959)
40.
go back to reference Kayaba, T., Iwabuchi, A.: Effect of the hardness of hardened steels and the action of oxides on fretting wear. Wear 66, 27–41 (1981)CrossRef Kayaba, T., Iwabuchi, A.: Effect of the hardness of hardened steels and the action of oxides on fretting wear. Wear 66, 27–41 (1981)CrossRef
41.
go back to reference Straffelini, G., Trabucco, D., Molinari, A.: Oxidative wear of heat-treated steels. Wear 250, 485–491 (2001)CrossRef Straffelini, G., Trabucco, D., Molinari, A.: Oxidative wear of heat-treated steels. Wear 250, 485–491 (2001)CrossRef
42.
go back to reference Colombia, Ch., Berthier, Y., Floquet, A., Vincent, L., Godot, M.: Fretting: load carrying capacity of wear debris. J. Tribol.-Trans. ASME 106, 194–201 (1984)CrossRef Colombia, Ch., Berthier, Y., Floquet, A., Vincent, L., Godot, M.: Fretting: load carrying capacity of wear debris. J. Tribol.-Trans. ASME 106, 194–201 (1984)CrossRef
43.
go back to reference Kato, H.: Severe–mild wear transition by supply of oxide particles on sliding surface. Wear 255, 426–429 (2003)CrossRef Kato, H.: Severe–mild wear transition by supply of oxide particles on sliding surface. Wear 255, 426–429 (2003)CrossRef
44.
go back to reference Kato, H.: Effects of supply of fine oxide particles onto rubbing steel surfaces on severe–mild wear transition and oxide film formation. Tribol. Int. 41, 735–742 (2008)CrossRef Kato, H.: Effects of supply of fine oxide particles onto rubbing steel surfaces on severe–mild wear transition and oxide film formation. Tribol. Int. 41, 735–742 (2008)CrossRef
45.
go back to reference Hahn, H., Logas, J., Averback, R.S.: Sintering characteristics of nanocrystalline TiO2. J. Mater. Res. 5, 609–614 (1990)CrossRef Hahn, H., Logas, J., Averback, R.S.: Sintering characteristics of nanocrystalline TiO2. J. Mater. Res. 5, 609–614 (1990)CrossRef
46.
go back to reference Iwabuchi, A.: The role of oxide particles in the fretting wear of mild steel. Wear 151, 301–311 (1991)CrossRef Iwabuchi, A.: The role of oxide particles in the fretting wear of mild steel. Wear 151, 301–311 (1991)CrossRef
47.
go back to reference Varenberg, M., Halperin, G., Etsion, I.: Different aspects of the role of wear debris in fretting wear. Wear 252, 902–910 (2002)CrossRef Varenberg, M., Halperin, G., Etsion, I.: Different aspects of the role of wear debris in fretting wear. Wear 252, 902–910 (2002)CrossRef
48.
go back to reference Everitt, N.M., Ding, J., Bandak, G., Shipway, P.H., Leen, S.B., Williams, E.J.: Characterisation of fretting-induced wear debris for Ti–6Al–4V. Wear 267, 283–291 (2009)CrossRef Everitt, N.M., Ding, J., Bandak, G., Shipway, P.H., Leen, S.B., Williams, E.J.: Characterisation of fretting-induced wear debris for Ti–6Al–4V. Wear 267, 283–291 (2009)CrossRef
Metadata
Title
Accelerated Formation of Tribo-oxide Layer and Its Effect on Sliding Wear of a Titanium Alloy
Authors
Q. Y. Zhang
Y. Zhou
X. X. Li
L. Wang
X. H. Cui
S. Q. Wang
Publication date
01-07-2016
Publisher
Springer US
Published in
Tribology Letters / Issue 1/2016
Print ISSN: 1023-8883
Electronic ISSN: 1573-2711
DOI
https://doi.org/10.1007/s11249-016-0694-7

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