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Published in: Metals and Materials International 6/2020

31-07-2019

AlNiCrFeMn Equiatomic High Entropy Alloy: A Further Insight in Its Microstructural Evolution, Mechanical and Surface Degradation Response

Authors: E. Ananiadis, K. Lentzaris, E. Georgatis, C. Mathiou, A. Poulia, A. E. Karantzalis

Published in: Metals and Materials International | Issue 6/2020

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Abstract

The microstructure and properties of an equiatomic AlCrFeMnNi high entropy alloy (HEA) in the as-cast condition are presented. The microstructure consists of two phases (NiAl-rich B2 and FeCr-rich A2) featuring various eutectic morphologies, ranging from regular to anomalous development. Solidification phenomena (undercooling and recalescense) are used in order to assess the various morphological features along with theories of anomalous eutectic growth. Sliding wear testing shows an oxidation-delamination mode of material removal along with some partial abrasive mode character. Modulus of elasticity and yield point are significantly high and elongation presents at a satisfying level, whereas fracture surface examination reveals the characteristics of a brittle fracture mode. High temperature oxidation tests show multiple oxidation phenomena of different kinetics, formed oxide phases and material deterioration phenomena.

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Literature
1.
go back to reference B.S. Murty, J.W. Yeh, S. Ranganathan, High-Entropy Alloys (Butterworth-Heinemann, Oxford, 2014) B.S. Murty, J.W. Yeh, S. Ranganathan, High-Entropy Alloys (Butterworth-Heinemann, Oxford, 2014)
2.
go back to reference J.W. Yeh, S.K. Chen, S.J. Lin, J.Y. Gan, T.S. Chin, T.T. Shun, C.H. Tsau, S.Y. Chang, Nanostructured high-entropy alloys with multiple principal elements: novel alloy design concepts and outcomes. Adv. Eng. Mater. 6, 299 (2004)CrossRef J.W. Yeh, S.K. Chen, S.J. Lin, J.Y. Gan, T.S. Chin, T.T. Shun, C.H. Tsau, S.Y. Chang, Nanostructured high-entropy alloys with multiple principal elements: novel alloy design concepts and outcomes. Adv. Eng. Mater. 6, 299 (2004)CrossRef
3.
go back to reference C.M. Lin, H.L. Tsai, H.Y. Bor, Effect of aging treatment on microstructure and properties of high-entropy Cu0.5CoCrFeNi alloy. Intermetallics 18, 1244 (2010)CrossRef C.M. Lin, H.L. Tsai, H.Y. Bor, Effect of aging treatment on microstructure and properties of high-entropy Cu0.5CoCrFeNi alloy. Intermetallics 18, 1244 (2010)CrossRef
4.
go back to reference S.T. Chen, W.Y. Tang, Y.F. Kuo, S.Y. Chen, C.H. Tsau, T.T. Shun, J.W. Yeh, Microstructure and properties of age-hardenable AlxCrFe1.5MnNi0.5 alloys. Mater. Sci. Eng. A 527, 5818 (2010)CrossRef S.T. Chen, W.Y. Tang, Y.F. Kuo, S.Y. Chen, C.H. Tsau, T.T. Shun, J.W. Yeh, Microstructure and properties of age-hardenable AlxCrFe1.5MnNi0.5 alloys. Mater. Sci. Eng. A 527, 5818 (2010)CrossRef
5.
go back to reference C.Y. Hsu, C.C. Juan, T.S. Sheu, S.K. Chen, J.W. Yeh, Effect of aluminum content on microstructure and mechanical properties of AlxCoCrFeMo0.5Ni high-entropy alloys. J. Met. 65, 1840 (2013) C.Y. Hsu, C.C. Juan, T.S. Sheu, S.K. Chen, J.W. Yeh, Effect of aluminum content on microstructure and mechanical properties of AlxCoCrFeMo0.5Ni high-entropy alloys. J. Met. 65, 1840 (2013)
6.
go back to reference C.Y. Hsu, T.S. Sheu, J.W. Yeh, S.K. Chen, Effect of iron content on wear behavior of AlCoCrFexMo0.5Ni high-entropy alloys. Wear 268, 653 (2010)CrossRef C.Y. Hsu, T.S. Sheu, J.W. Yeh, S.K. Chen, Effect of iron content on wear behavior of AlCoCrFexMo0.5Ni high-entropy alloys. Wear 268, 653 (2010)CrossRef
7.
go back to reference J.M. Wu, S.J. Lin, J.W. Yeh, S.K. Chen, Y.S. Huang, H.C. Chen, Adhesive wear behavior of AlxCoCrCuFeNi high-entropy alloys as a function of aluminum content. Wear 261, 513 (2006)CrossRef J.M. Wu, S.J. Lin, J.W. Yeh, S.K. Chen, Y.S. Huang, H.C. Chen, Adhesive wear behavior of AlxCoCrCuFeNi high-entropy alloys as a function of aluminum content. Wear 261, 513 (2006)CrossRef
8.
go back to reference M.H. Chuang, M.H. Tsai, W.R. Wang, S.J. Lin, J.W. Yeh, Microstructure and wear behavior of AlxCo1.5CrFeNi1.5Tiy high-entropy alloys. Acta Mater. 59, 6308 (2011)CrossRef M.H. Chuang, M.H. Tsai, W.R. Wang, S.J. Lin, J.W. Yeh, Microstructure and wear behavior of AlxCo1.5CrFeNi1.5Tiy high-entropy alloys. Acta Mater. 59, 6308 (2011)CrossRef
9.
go back to reference C.Y. Hsu, J.W. Yeh, S.K. Chen, T.T. Shun, Wear resistance and high-temperature compression strength of FCC CuCoNiCrAl0.5Fe alloy with boron addition. Metall. Mater. Trans. A 35, 1465 (2004)CrossRef C.Y. Hsu, J.W. Yeh, S.K. Chen, T.T. Shun, Wear resistance and high-temperature compression strength of FCC CuCoNiCrAl0.5Fe alloy with boron addition. Metall. Mater. Trans. A 35, 1465 (2004)CrossRef
10.
go back to reference C.P. Lee, C.C. Chang, Y.Y. Chen, J.W. Yeh, H.C. Shih, Effect of the aluminium content AlxCrFe1.5MnNi0.5 high-entropy alloys on the corrosion behavior in aqueous environments. Corros. Sci. 50, 2053 (2008)CrossRef C.P. Lee, C.C. Chang, Y.Y. Chen, J.W. Yeh, H.C. Shih, Effect of the aluminium content AlxCrFe1.5MnNi0.5 high-entropy alloys on the corrosion behavior in aqueous environments. Corros. Sci. 50, 2053 (2008)CrossRef
11.
go back to reference P.K. Liaw, Z. Tang, L. Huang, W. He, Alloying and processing effects on the aqueous corrosion behavior of high-entropy alloys. MDPI-Entropy 16, 895 (2014)CrossRef P.K. Liaw, Z. Tang, L. Huang, W. He, Alloying and processing effects on the aqueous corrosion behavior of high-entropy alloys. MDPI-Entropy 16, 895 (2014)CrossRef
12.
go back to reference S. Frankel, Introduction to Metallurgically Influenced Corrosion, ASM Handbook, Corrosion Fundamentals, Testing, and Protection, vol. 13 (ASM International, Novelty, 2003), p. 257 S. Frankel, Introduction to Metallurgically Influenced Corrosion, ASM Handbook, Corrosion Fundamentals, Testing, and Protection, vol. 13 (ASM International, Novelty, 2003), p. 257
13.
go back to reference M.J. Yao, K.G. Pradeep, C.C. Tasan, D. Raabe, A novel, single phase, non- equiatomic FeMnNiCoCr high-entropy alloy with exceptional phase stability and tensile ductility. Scripta Mater. 72, 5 (2014)CrossRef M.J. Yao, K.G. Pradeep, C.C. Tasan, D. Raabe, A novel, single phase, non- equiatomic FeMnNiCoCr high-entropy alloy with exceptional phase stability and tensile ductility. Scripta Mater. 72, 5 (2014)CrossRef
14.
go back to reference M.S. Lucas, G.B. Wilks, L. Mauger, J.A. Munoz, O.N. Senkov, E. Michel, J. Horwath, S.L. Semiatin, M.B. Stone, D.L. Abernathy, E. Karapetrova, Absence of long-range chemical ordering in equimolar FeCoCrNi. Appl. Phys. Lett. 100, 251907 (2012)CrossRef M.S. Lucas, G.B. Wilks, L. Mauger, J.A. Munoz, O.N. Senkov, E. Michel, J. Horwath, S.L. Semiatin, M.B. Stone, D.L. Abernathy, E. Karapetrova, Absence of long-range chemical ordering in equimolar FeCoCrNi. Appl. Phys. Lett. 100, 251907 (2012)CrossRef
15.
go back to reference Y.F. Kao, T.D. Lee, S.K. Chen, Y.S. Chang, Electrochemical passive properties of AlxCoCrFeNi (x = 0, 0.25, 0.50, 1.00) alloys in sulfuric acids. Corros. Sci. 52, 1026 (2010)CrossRef Y.F. Kao, T.D. Lee, S.K. Chen, Y.S. Chang, Electrochemical passive properties of AlxCoCrFeNi (x = 0, 0.25, 0.50, 1.00) alloys in sulfuric acids. Corros. Sci. 52, 1026 (2010)CrossRef
16.
go back to reference K. Sieradzki, R. Newman, Percolation model for passivation in stainless steels. J. Electrochem. Soc. 133, 1979 (1986)CrossRef K. Sieradzki, R. Newman, Percolation model for passivation in stainless steels. J. Electrochem. Soc. 133, 1979 (1986)CrossRef
17.
go back to reference Y.L. Chou, Y.C. Wang, J.W. Yeh, H.C. Shih, Pitting corrosion of the high entropy alloy Co1.5CrFeNi1.5Ti0.5Mo0.1 in chloride-containing sulphate solutions. Corros. Sci. 52, 3481 (2010)CrossRef Y.L. Chou, Y.C. Wang, J.W. Yeh, H.C. Shih, Pitting corrosion of the high entropy alloy Co1.5CrFeNi1.5Ti0.5Mo0.1 in chloride-containing sulphate solutions. Corros. Sci. 52, 3481 (2010)CrossRef
18.
go back to reference Y. Zhang, T.T. Zuo, Z. Tang, M.C. Gao, K.A. Dahmen, P.K. Liaw, Z.P. Lu, Microstructures and properties of high-entropy alloys. Prog. Mater Sci. 61, 1 (2014)CrossRef Y. Zhang, T.T. Zuo, Z. Tang, M.C. Gao, K.A. Dahmen, P.K. Liaw, Z.P. Lu, Microstructures and properties of high-entropy alloys. Prog. Mater Sci. 61, 1 (2014)CrossRef
19.
go back to reference Y.F. Kao, T.J. Chen, S.K. Chen, J.W. Yeh, Microstructure and mechanical property of as-cast, -homogenized, and -deformed AlxCoCrFeNi (0 ≤ x ≤ 2) high- entropy alloys. J. Alloys Compd. 488, 57 (2009)CrossRef Y.F. Kao, T.J. Chen, S.K. Chen, J.W. Yeh, Microstructure and mechanical property of as-cast, -homogenized, and -deformed AlxCoCrFeNi (0 ≤ x ≤ 2) high- entropy alloys. J. Alloys Compd. 488, 57 (2009)CrossRef
20.
go back to reference G.R. Holcomb, J. Tylczak, C. Carney, Oxidation of CoCrFeMnNi high entropy alloys. JOM 67, 2326 (2015)CrossRef G.R. Holcomb, J. Tylczak, C. Carney, Oxidation of CoCrFeMnNi high entropy alloys. JOM 67, 2326 (2015)CrossRef
21.
go back to reference Y.K. Kim, Y.A. Joo, H.S. Kim, K.A. Lee, High temperature oxidation behavior of Cr-Mn-Fe-Co-Ni high entropy alloy. Intermetallics 98, 45 (2018)CrossRef Y.K. Kim, Y.A. Joo, H.S. Kim, K.A. Lee, High temperature oxidation behavior of Cr-Mn-Fe-Co-Ni high entropy alloy. Intermetallics 98, 45 (2018)CrossRef
22.
go back to reference W. Kai, C.C. Li, F.P. Cheng, K.P. Chu, R.T. Huang, L.W. Tsay, J.J. Kai, Air-oxidation of FeCoNiCr-based quinary high-entropy alloys at 700–900◦C. Corros. Sci. 121, 116 (2017)CrossRef W. Kai, C.C. Li, F.P. Cheng, K.P. Chu, R.T. Huang, L.W. Tsay, J.J. Kai, Air-oxidation of FeCoNiCr-based quinary high-entropy alloys at 700–900◦C. Corros. Sci. 121, 116 (2017)CrossRef
23.
go back to reference O.N. Senkov, S.V. Senkova, D.M. Dimiduk, C. Woodward, D.B. Miracle, Oxidation behaviour of a refractory NbCrMo0.5Ta0.5TiZr alloy. J. Mater. Sci. 47, 6522–6534 (2012)CrossRef O.N. Senkov, S.V. Senkova, D.M. Dimiduk, C. Woodward, D.B. Miracle, Oxidation behaviour of a refractory NbCrMo0.5Ta0.5TiZr alloy. J. Mater. Sci. 47, 6522–6534 (2012)CrossRef
24.
go back to reference C.M. Liu, H.M. Wang, S.Q. Zhang, H.B. Tang, A.L. Zhang, Microstructure and oxidation behaviour of new refractory high entropy alloys. J. Alloys Compd. 583, 162169 (2014) C.M. Liu, H.M. Wang, S.Q. Zhang, H.B. Tang, A.L. Zhang, Microstructure and oxidation behaviour of new refractory high entropy alloys. J. Alloys Compd. 583, 162169 (2014)
25.
go back to reference G. Zhu, Y. Liu, J. Ye, Early high-temperature oxidation behavior of Ti (C, N)- based cermets with multi-component AlCoCrFeNi high-entropy alloy binder. Int. J. Refract. Met. Hard Mater. 44, 3541 (2014) G. Zhu, Y. Liu, J. Ye, Early high-temperature oxidation behavior of Ti (C, N)- based cermets with multi-component AlCoCrFeNi high-entropy alloy binder. Int. J. Refract. Met. Hard Mater. 44, 3541 (2014)
26.
go back to reference Y. Zhang, High Entropy Materials-A Brief Introduction. 1st edn. (Springer, 2019), pp. 77–89 Y. Zhang, High Entropy Materials-A Brief Introduction. 1st edn. (Springer, 2019), pp. 77–89
28.
go back to reference M.C. Gao, J.-W. Yeh, P. K. Liaw, Y. Zhang, High-Entropy Alloys: Fundamentals and Applications. Springer International Publishing, Cham, ISBN 978-3-319-27013-5, 1, (2016) M.C. Gao, J.-W. Yeh, P. K. Liaw, Y. Zhang, High-Entropy Alloys: Fundamentals and Applications. Springer International Publishing, Cham, ISBN 978-3-319-27013-5, 1, (2016)
29.
go back to reference M.H. Tsai, J.W. Yeh, High-entropy alloys: a critical review. Mater. Res. Lett. 2, 107 (2014)CrossRef M.H. Tsai, J.W. Yeh, High-entropy alloys: a critical review. Mater. Res. Lett. 2, 107 (2014)CrossRef
30.
go back to reference Y. Zhang, X. Yang, P.K. Liaw, Alloy design and properties optimization of high-entropy alloys. JOM 64, 830 (2012)CrossRef Y. Zhang, X. Yang, P.K. Liaw, Alloy design and properties optimization of high-entropy alloys. JOM 64, 830 (2012)CrossRef
31.
go back to reference C.J. Tong, Y.L. Chen, S.K. Chen, J.W. Yeh, T.T. Shun, C.H. Tsau, S.J. Lin, S.Y. Chang, Microstructure characterization of AlxCoCrCu–FeNi high-entropy alloy system with multiprincipal elements. Metall. Mater. Trans. A 36, 881 (2005)CrossRef C.J. Tong, Y.L. Chen, S.K. Chen, J.W. Yeh, T.T. Shun, C.H. Tsau, S.J. Lin, S.Y. Chang, Microstructure characterization of AlxCoCrCu–FeNi high-entropy alloy system with multiprincipal elements. Metall. Mater. Trans. A 36, 881 (2005)CrossRef
32.
go back to reference X. Wang, H. Xie, L. Jia, Z.L. Lu, Effect of Ti, Al and Cu addition on structural evolution and phase constitution of FeCoNi system equimolar alloys. Mater. Sci. Forum 724, 335 (2012)CrossRef X. Wang, H. Xie, L. Jia, Z.L. Lu, Effect of Ti, Al and Cu addition on structural evolution and phase constitution of FeCoNi system equimolar alloys. Mater. Sci. Forum 724, 335 (2012)CrossRef
33.
go back to reference S. Praveen, B.S. Murty, R.S. Kottada, Alloying behaviour in multi-component AlCoCrCuFe and NiCoCrCuFe high entropy alloys. Mater. Sci. Eng. A 534, 83 (2012)CrossRef S. Praveen, B.S. Murty, R.S. Kottada, Alloying behaviour in multi-component AlCoCrCuFe and NiCoCrCuFe high entropy alloys. Mater. Sci. Eng. A 534, 83 (2012)CrossRef
34.
go back to reference L. Liu, J.B. Zhu, C. Zhang, J.C. Li, Q. Jiang, Microstructure and the properties of FeCoCuNiSnx high entropy alloys. Mater. Sci. Eng. A 548, 64 (2012)CrossRef L. Liu, J.B. Zhu, C. Zhang, J.C. Li, Q. Jiang, Microstructure and the properties of FeCoCuNiSnx high entropy alloys. Mater. Sci. Eng. A 548, 64 (2012)CrossRef
35.
go back to reference C.J. Tong, M.R. Chen, S.K. Chen, J.W. Yeh, T.T. Shun, S.J. Lin, S.Y. Chang, Mechanical performance of the AlxCoCrCuFeNi high-entropy alloy system with multiprincipal elements. Metall. Mater. Trans. A 36, 1263 (2005)CrossRef C.J. Tong, M.R. Chen, S.K. Chen, J.W. Yeh, T.T. Shun, S.J. Lin, S.Y. Chang, Mechanical performance of the AlxCoCrCuFeNi high-entropy alloy system with multiprincipal elements. Metall. Mater. Trans. A 36, 1263 (2005)CrossRef
36.
go back to reference O.N. Senkov, G.B. Wilks, D.B. Miracle, C.P. Chuang, P.K. Liaw, Refractory high-entropy alloys. Intermetallics 18, 1758 (2010)CrossRef O.N. Senkov, G.B. Wilks, D.B. Miracle, C.P. Chuang, P.K. Liaw, Refractory high-entropy alloys. Intermetallics 18, 1758 (2010)CrossRef
37.
go back to reference O.N. Senkov, J.M. Scott, S.V. Senkova, D.B. Miracle, C.F. Woodward, Microstructure and room temperature properties of a high-entropy TaNbHfZrTi alloy. J. Alloys Compd. 509, 6043 (2011)CrossRef O.N. Senkov, J.M. Scott, S.V. Senkova, D.B. Miracle, C.F. Woodward, Microstructure and room temperature properties of a high-entropy TaNbHfZrTi alloy. J. Alloys Compd. 509, 6043 (2011)CrossRef
38.
go back to reference O.N. Senkov, S.V. Senkova, C. Woodward, D.B. Miracle, Low-density, refractory multi-principal element alloys of the Cr-Nb-Ti-V-Zr system: microstructure and phase analysis. Acta Mater. 61, 1545 (2013)CrossRef O.N. Senkov, S.V. Senkova, C. Woodward, D.B. Miracle, Low-density, refractory multi-principal element alloys of the Cr-Nb-Ti-V-Zr system: microstructure and phase analysis. Acta Mater. 61, 1545 (2013)CrossRef
39.
go back to reference Y. Zhang, T.T. Zuo, Z. Tang, M.C. Gao, K.A. Dahmen, P.K. Liaw, Z.P. Lu, Microstructure and properties of high-entropy alloys. Prog. Mater Sci. 61, 1 (2014)CrossRef Y. Zhang, T.T. Zuo, Z. Tang, M.C. Gao, K.A. Dahmen, P.K. Liaw, Z.P. Lu, Microstructure and properties of high-entropy alloys. Prog. Mater Sci. 61, 1 (2014)CrossRef
40.
go back to reference C.J. Tong, M.R. Chen, H.W. Yeh, S.J. Lin, S.K. Chen, T.T. Shun, S.Y. Chang, Mechanical performance of the AlxCoCrCuFeNi high-entropy alloy system with multiprincipal elements. Metall. Mater. Trans. A 36, 1263 (2005)CrossRef C.J. Tong, M.R. Chen, H.W. Yeh, S.J. Lin, S.K. Chen, T.T. Shun, S.Y. Chang, Mechanical performance of the AlxCoCrCuFeNi high-entropy alloy system with multiprincipal elements. Metall. Mater. Trans. A 36, 1263 (2005)CrossRef
41.
go back to reference C.C. Tung, J.W. Yeh, T.T. Shun, S.K. Chen, Y.S. Huang, H.C. Chen, On the elemental effect of AlCoCrCuFeNi high-entropy alloy system. Mater. Lett. 61, 1 (2007)CrossRef C.C. Tung, J.W. Yeh, T.T. Shun, S.K. Chen, Y.S. Huang, H.C. Chen, On the elemental effect of AlCoCrCuFeNi high-entropy alloy system. Mater. Lett. 61, 1 (2007)CrossRef
43.
go back to reference C.T. Sims, W.C. Hagel, The Superalloys (Wiley, New York, 1972) C.T. Sims, W.C. Hagel, The Superalloys (Wiley, New York, 1972)
44.
go back to reference D.A. Shifler, High-Temperature Gaseous Corrosion Testing, Corrosion: Fundamentals, Testing, and Protection, ASM Handbook, vol. 13 (Novelty, ASM International, 2003), p. 650 D.A. Shifler, High-Temperature Gaseous Corrosion Testing, Corrosion: Fundamentals, Testing, and Protection, ASM Handbook, vol. 13 (Novelty, ASM International, 2003), p. 650
45.
go back to reference D. Caplan, M. Cohen, Effect of cold working on the oxidation of iron from 400–650°C. Corros. Sci. 6, 321 (1966)CrossRef D. Caplan, M. Cohen, Effect of cold working on the oxidation of iron from 400–650°C. Corros. Sci. 6, 321 (1966)CrossRef
46.
go back to reference J.M. Francis, W.H. Whitlow, The effect of yttrium on the high temperature oxidation of resistance of some Fe-Cr base alloys in carbon dioxide. Corros. Sci. 5, 701 (1965)CrossRef J.M. Francis, W.H. Whitlow, The effect of yttrium on the high temperature oxidation of resistance of some Fe-Cr base alloys in carbon dioxide. Corros. Sci. 5, 701 (1965)CrossRef
47.
go back to reference D. Caplan, A. Harvey, M. Cohen, The effect of surface preparation on oxide films on Cr and Fe–Cr alloys. J. Electrochem. Soc. 108, 134 (1961)CrossRef D. Caplan, A. Harvey, M. Cohen, The effect of surface preparation on oxide films on Cr and Fe–Cr alloys. J. Electrochem. Soc. 108, 134 (1961)CrossRef
48.
go back to reference D. Caplan, M. Cohen, Scaling of Fe-26Cr alloys at 870°–1200°C. J. Electrochem. Soc. 112, 471 (1965)CrossRef D. Caplan, M. Cohen, Scaling of Fe-26Cr alloys at 870°–1200°C. J. Electrochem. Soc. 112, 471 (1965)CrossRef
49.
go back to reference J.R. Davis, Stainless Steels, ASM Speciality Handbook (ASM, Materials Park, 1994) J.R. Davis, Stainless Steels, ASM Speciality Handbook (ASM, Materials Park, 1994)
50.
go back to reference F. Meng, J. Qiu, I. Baker, The effects of chromium on the microstructure and tensile behavior of Fe30Ni20Mn35Al15. Mater. Sci. Eng. A 586, 45 (2013)CrossRef F. Meng, J. Qiu, I. Baker, The effects of chromium on the microstructure and tensile behavior of Fe30Ni20Mn35Al15. Mater. Sci. Eng. A 586, 45 (2013)CrossRef
52.
go back to reference Α. Τakeuchi, A. Inoue, Classification of bulk metallic glasses by atomic size difference, heat of mixing and period of constituent elements and its applications to characterization of the main alloying element. Mater. Trans. 46, 2817 (2005)CrossRef Α. Τakeuchi, A. Inoue, Classification of bulk metallic glasses by atomic size difference, heat of mixing and period of constituent elements and its applications to characterization of the main alloying element. Mater. Trans. 46, 2817 (2005)CrossRef
53.
go back to reference S. Guo, C.T. Liu, Phase stability in high entropy alloys: formation solid solution phase or amorphous phase. Prog. Nat. Sci. Mater. Int. 21, 433 (2011)CrossRef S. Guo, C.T. Liu, Phase stability in high entropy alloys: formation solid solution phase or amorphous phase. Prog. Nat. Sci. Mater. Int. 21, 433 (2011)CrossRef
54.
go back to reference S. Guo, C. Ng, J. Lu et al., Effect of valence electron concentration on stability of fcc or bcc phase in high entropy alloys. J. Appl. Phys. 109, 103505 (2011)CrossRef S. Guo, C. Ng, J. Lu et al., Effect of valence electron concentration on stability of fcc or bcc phase in high entropy alloys. J. Appl. Phys. 109, 103505 (2011)CrossRef
55.
go back to reference D.J.M. King, S.C. Middleburgh, A.G. McGregor, M.B. Cortie, Predicting the formation and stability of single phase high-entropy alloys. Acta Mater. 104, 172 (2016)CrossRef D.J.M. King, S.C. Middleburgh, A.G. McGregor, M.B. Cortie, Predicting the formation and stability of single phase high-entropy alloys. Acta Mater. 104, 172 (2016)CrossRef
56.
go back to reference A. Poulia, E. Georgatis, C. Mathiou, A.E. Karantzalis, Phase segregation discussion in a Hf25Zr30Ti20Nb15V10 high entropy alloy: the effect of the high melting point element. Mater. Chem. Phys. 210, 251 (2018)CrossRef A. Poulia, E. Georgatis, C. Mathiou, A.E. Karantzalis, Phase segregation discussion in a Hf25Zr30Ti20Nb15V10 high entropy alloy: the effect of the high melting point element. Mater. Chem. Phys. 210, 251 (2018)CrossRef
57.
go back to reference S. Sheikh, H. Mao, S. Guo, Predicting solid solubility in CoCrFeNiMx (M = 4d transition metal) hight-entropy alloys. J. Appl. Phys. 121, 194903 (2018)CrossRef S. Sheikh, H. Mao, S. Guo, Predicting solid solubility in CoCrFeNiMx (M = 4d transition metal) hight-entropy alloys. J. Appl. Phys. 121, 194903 (2018)CrossRef
58.
go back to reference E. Pickering, N.G. Jones, High-entropy alloys: a critical assessment of their founding principles and future prospects. Int. Mater. Rev. 61, 183 (2016)CrossRef E. Pickering, N.G. Jones, High-entropy alloys: a critical assessment of their founding principles and future prospects. Int. Mater. Rev. 61, 183 (2016)CrossRef
59.
go back to reference S. Guo, C. Ng, C.T. Liu, Sunflower-like solidification microstructure in a near-eutectic high-entropy alloy. Mater. Res. Lett. 1, 228 (2013)CrossRef S. Guo, C. Ng, C.T. Liu, Sunflower-like solidification microstructure in a near-eutectic high-entropy alloy. Mater. Res. Lett. 1, 228 (2013)CrossRef
60.
go back to reference A. Munitz, L. Meshi, M.J. Kaufman, Heat treatments’ effects on the microstructure and mechanical properties of an equiatomic Al–Cr–Fe–Mn–Ni high entropy alloy. Mater. Sci. Eng. A 689, 384 (2017)CrossRef A. Munitz, L. Meshi, M.J. Kaufman, Heat treatments’ effects on the microstructure and mechanical properties of an equiatomic Al–Cr–Fe–Mn–Ni high entropy alloy. Mater. Sci. Eng. A 689, 384 (2017)CrossRef
61.
go back to reference T.Z. Kattamis, M.C. Flemings, Structure of undercooled Ni–Sn eutectic. Met. Trans. 1, 1449 (1970)CrossRef T.Z. Kattamis, M.C. Flemings, Structure of undercooled Ni–Sn eutectic. Met. Trans. 1, 1449 (1970)CrossRef
62.
go back to reference B.L. Jones, Growth mechanisms in undercooled eutectics. Metall. Trans. 2, 2950 (1971)CrossRef B.L. Jones, Growth mechanisms in undercooled eutectics. Metall. Trans. 2, 2950 (1971)CrossRef
63.
go back to reference B. Wei, D.M. Herlach, B. Feuerbacher, F. Sommer, Dendritic and eutectic solidification of undercooled Co–Sb alloys. Acta Metall. Mater. 41, 1801 (1993)CrossRef B. Wei, D.M. Herlach, B. Feuerbacher, F. Sommer, Dendritic and eutectic solidification of undercooled Co–Sb alloys. Acta Metall. Mater. 41, 1801 (1993)CrossRef
64.
go back to reference M. Li, K. Kuribayashi, Free solidification of undercooled eutectics. Mater. Trans. 47, 2889 (2016)CrossRef M. Li, K. Kuribayashi, Free solidification of undercooled eutectics. Mater. Trans. 47, 2889 (2016)CrossRef
65.
go back to reference X.X. Wei, X. Lin, W. Xu, Q.S. Huang, M. Ferry, J.F. Li, Y.H. Zhou, Remelting- induced anomalous eutectic formation during solidification of deeply undercooled eutectic alloy melts. Acta Mater. 95, 44 (2015)CrossRef X.X. Wei, X. Lin, W. Xu, Q.S. Huang, M. Ferry, J.F. Li, Y.H. Zhou, Remelting- induced anomalous eutectic formation during solidification of deeply undercooled eutectic alloy melts. Acta Mater. 95, 44 (2015)CrossRef
66.
go back to reference C. Yang, J. Gao, Y.K. Zhang, M. Kolbe, D.M. Herlach, New evidence for the dual origin of anomalous eutectic structures in undercooled Ni-Sn alloys: in situ observations and EBSD characterization. Acta Mater. 59, 3915 (2011)CrossRef C. Yang, J. Gao, Y.K. Zhang, M. Kolbe, D.M. Herlach, New evidence for the dual origin of anomalous eutectic structures in undercooled Ni-Sn alloys: in situ observations and EBSD characterization. Acta Mater. 59, 3915 (2011)CrossRef
67.
go back to reference X. Lin, Y.Q. Cao, Z.T. Wang, J. Cao, L.L. Wang, W.D. Huang, Regular eutectic and anomalous eutectic growth behavior in laser remelting of Ni–30 wt%Sn alloys. Acta Mater. 126, 210 (2017)CrossRef X. Lin, Y.Q. Cao, Z.T. Wang, J. Cao, L.L. Wang, W.D. Huang, Regular eutectic and anomalous eutectic growth behavior in laser remelting of Ni–30 wt%Sn alloys. Acta Mater. 126, 210 (2017)CrossRef
68.
go back to reference L. Liu, X.X. Wei, Q.S. Huang, J.F. Li, X.H. Cheng, Y.H. Zhou, Anomalous eutectic formation in the solidification of undercooled Co–Sn alloys. J. Cryst. Growth 358, 20 (2012)CrossRef L. Liu, X.X. Wei, Q.S. Huang, J.F. Li, X.H. Cheng, Y.H. Zhou, Anomalous eutectic formation in the solidification of undercooled Co–Sn alloys. J. Cryst. Growth 358, 20 (2012)CrossRef
69.
go back to reference Y. Cao, X. Lin, Z. Wang, L. Wang, M. Song, H. Yang, W. Huang, Three- dimensional reconstruction of anomalous eutectic in laser remelted Ni–30 wt% Sn alloy. Sci. Technol. Adv. Mater. 16, 065007 (2016)CrossRef Y. Cao, X. Lin, Z. Wang, L. Wang, M. Song, H. Yang, W. Huang, Three- dimensional reconstruction of anomalous eutectic in laser remelted Ni–30 wt% Sn alloy. Sci. Technol. Adv. Mater. 16, 065007 (2016)CrossRef
70.
go back to reference C.R. Clopet, R.F. Cochrane, A.M. Mullis, The origin of anomalous eutectic structures in undercooled Ag–Cu alloy. Acta Mater. 61, 6894 (2013)CrossRef C.R. Clopet, R.F. Cochrane, A.M. Mullis, The origin of anomalous eutectic structures in undercooled Ag–Cu alloy. Acta Mater. 61, 6894 (2013)CrossRef
71.
go back to reference B. Tang, D.A. Cogswell, G. Xu, S. Milenkovic, Y. Cui, Formation mechanism of eutectic microstructure in NiAl–Cr composites. Phys. Chem. Chem. Phys. 18, 19773 (2016)CrossRef B. Tang, D.A. Cogswell, G. Xu, S. Milenkovic, Y. Cui, Formation mechanism of eutectic microstructure in NiAl–Cr composites. Phys. Chem. Chem. Phys. 18, 19773 (2016)CrossRef
72.
go back to reference R. Goetzinger, M. Barth, D.M. Herlach, Mechanism of formation of the anomalous eutectic structure in rapidly solidified Ni–Si, Co–Sb and Ni–Al–Ti alloys. Acta Mater. 46, 1647 (1998)CrossRef R. Goetzinger, M. Barth, D.M. Herlach, Mechanism of formation of the anomalous eutectic structure in rapidly solidified Ni–Si, Co–Sb and Ni–Al–Ti alloys. Acta Mater. 46, 1647 (1998)CrossRef
73.
go back to reference A. Karma, Model of grain refinement in solidification of undercooled melts. Int. J. Non-Equilib. Process. 1, 201 (1998) A. Karma, Model of grain refinement in solidification of undercooled melts. Int. J. Non-Equilib. Process. 1, 201 (1998)
74.
go back to reference I.V. Kragelsky, M.N. Dobychin, V.S. Kompalov, Friction and Wear Calculation Methods (Pergamon, Oxford, 1982) I.V. Kragelsky, M.N. Dobychin, V.S. Kompalov, Friction and Wear Calculation Methods (Pergamon, Oxford, 1982)
75.
go back to reference D.H. Buckley, Surface Effects in Adhesion, Friction, Wear and Lubrication (Elsevier, Amsterdam, 1981) D.H. Buckley, Surface Effects in Adhesion, Friction, Wear and Lubrication (Elsevier, Amsterdam, 1981)
76.
go back to reference O.N. Senkov, G.B. Wilks, J.M. Scott, D.B. Miracle, Mechanical properties of Nb25Mo25Ta25W25 and V20Nb20Mo20Ta20W20 refractory high-entropy alloys. Intermetallics 19, 698 (2011)CrossRef O.N. Senkov, G.B. Wilks, J.M. Scott, D.B. Miracle, Mechanical properties of Nb25Mo25Ta25W25 and V20Nb20Mo20Ta20W20 refractory high-entropy alloys. Intermetallics 19, 698 (2011)CrossRef
77.
go back to reference U. Roy, H. Roy, H. Daoud, U. Glatzel, K. Ray, Fracture toughness and fracture micromechanism in a cast AlCoCrCuFeNi high entropy alloy system. Mater. Lett. 132, 186 (2014)CrossRef U. Roy, H. Roy, H. Daoud, U. Glatzel, K. Ray, Fracture toughness and fracture micromechanism in a cast AlCoCrCuFeNi high entropy alloy system. Mater. Lett. 132, 186 (2014)CrossRef
78.
go back to reference J. Joseph, N. Stanford, P. Hodgson, D.M. Fabijanic, Tension/compression asymmetry in additive manufactured face centered cubic high entropy alloy. Scr. Mater. 129, 30 (2017)CrossRef J. Joseph, N. Stanford, P. Hodgson, D.M. Fabijanic, Tension/compression asymmetry in additive manufactured face centered cubic high entropy alloy. Scr. Mater. 129, 30 (2017)CrossRef
79.
go back to reference D.H. Xiao, P.F. Zhou, W.Q. Wu, H.Y. Diao, M.C. Gao, M. Song, P.K. Liaw, Microstructure, mechanical and corrosion behaviors of AlCoCuFeNi-(Cr, Ti) high entropy alloys. Mater. Des. 116, 438 (2017)CrossRef D.H. Xiao, P.F. Zhou, W.Q. Wu, H.Y. Diao, M.C. Gao, M. Song, P.K. Liaw, Microstructure, mechanical and corrosion behaviors of AlCoCuFeNi-(Cr, Ti) high entropy alloys. Mater. Des. 116, 438 (2017)CrossRef
80.
go back to reference J.H. Chen, R. Cao, Micromechanism of Cleavage Fracture of Metals (Butterworth-Heinemann, Oxford, 2015) J.H. Chen, R. Cao, Micromechanism of Cleavage Fracture of Metals (Butterworth-Heinemann, Oxford, 2015)
81.
go back to reference I.A. Kvernes, P. Kofstad, The oxidation behavior of some Ni–Cr–Al alloys at high temperatures. Metall. Trans. 3, 1511 (1972)CrossRef I.A. Kvernes, P. Kofstad, The oxidation behavior of some Ni–Cr–Al alloys at high temperatures. Metall. Trans. 3, 1511 (1972)CrossRef
82.
go back to reference W. Kai, W.L. Jang, R.T. Huang, C.C. Lee, H.H. Hsieh, C.F. Du, Air oxidation of FeCoNi-base equi-molar alloys at 800–1000°C. Oxid. Met. 63, 169 (2004)CrossRef W. Kai, W.L. Jang, R.T. Huang, C.C. Lee, H.H. Hsieh, C.F. Du, Air oxidation of FeCoNi-base equi-molar alloys at 800–1000°C. Oxid. Met. 63, 169 (2004)CrossRef
83.
go back to reference U. Krupp, H.J. Christ, Selective oxidation and internal nitridation during high-temperature exposure of single-crystalline nickel-base superalloys. Metall. Mater. Trans. A 31, 47 (2000)CrossRef U. Krupp, H.J. Christ, Selective oxidation and internal nitridation during high-temperature exposure of single-crystalline nickel-base superalloys. Metall. Mater. Trans. A 31, 47 (2000)CrossRef
84.
go back to reference F.H. Stott, F.I. Wei, C.A. Enahoro, The influence of manganese on the High-temperature oxidation of iron-chromium alloys. Mater. Corros. 40, 198 (1989)CrossRef F.H. Stott, F.I. Wei, C.A. Enahoro, The influence of manganese on the High-temperature oxidation of iron-chromium alloys. Mater. Corros. 40, 198 (1989)CrossRef
85.
go back to reference T. Ericsson, A study of the Cr-depleted surface layers formed on four Cr-Ni steels during oxidation in steam at 600 °C and 800 °C. Oxid. Met. 2, 401 (1970)CrossRef T. Ericsson, A study of the Cr-depleted surface layers formed on four Cr-Ni steels during oxidation in steam at 600 °C and 800 °C. Oxid. Met. 2, 401 (1970)CrossRef
86.
go back to reference R.J. Hussey, M. Cohen, The oxidation of Fe in the temperature range 450–550°C—II. The pressure range 10−3–760 torr. Corros. Sci. 11, 713 (1971)CrossRef R.J. Hussey, M. Cohen, The oxidation of Fe in the temperature range 450–550°C—II. The pressure range 10−3–760 torr. Corros. Sci. 11, 713 (1971)CrossRef
87.
go back to reference G. Granaud, R.A. Rapp, Thickness of the oxide layers formed during the oxidation of iron. Oxid. Met. 11, 193 (1977)CrossRef G. Granaud, R.A. Rapp, Thickness of the oxide layers formed during the oxidation of iron. Oxid. Met. 11, 193 (1977)CrossRef
88.
go back to reference J.E. Castle, P.L. Surman, Self-diffusion of oxygen in magnetite. Techniques for sampling and isootopic analysis of micro quantities of water. J. Phys. Chem. 71, 4255 (1967)CrossRef J.E. Castle, P.L. Surman, Self-diffusion of oxygen in magnetite. Techniques for sampling and isootopic analysis of micro quantities of water. J. Phys. Chem. 71, 4255 (1967)CrossRef
89.
go back to reference L. Himmel, R.T. Mehl, C.E. Birchenall, Self-diffusion of iron in iron oxides and the wagner theory of oxidation. J. Met. 5, 827 (1953) L. Himmel, R.T. Mehl, C.E. Birchenall, Self-diffusion of iron in iron oxides and the wagner theory of oxidation. J. Met. 5, 827 (1953)
90.
go back to reference S.C. Tsai, A.M. Huntz, C. Dolin, Growth mechanism of Cr2O3 scales: oxygen and chromium diffusion, oxidation kinetics and effect of yttrium. Mater. Sci. Eng. A 212, 6 (1996)CrossRef S.C. Tsai, A.M. Huntz, C. Dolin, Growth mechanism of Cr2O3 scales: oxygen and chromium diffusion, oxidation kinetics and effect of yttrium. Mater. Sci. Eng. A 212, 6 (1996)CrossRef
91.
go back to reference A.M. Huntz, Parabolic laws during high temperature oxidation: relations with the grain size and thickness of the oxide. J. Mater. Sci. Lett. 18, 1981 (1999)CrossRef A.M. Huntz, Parabolic laws during high temperature oxidation: relations with the grain size and thickness of the oxide. J. Mater. Sci. Lett. 18, 1981 (1999)CrossRef
92.
go back to reference A.F. Smith, The diffusion of chromium in type 316 stainless steel. Met. Sci. 9, 375 (1975)CrossRef A.F. Smith, The diffusion of chromium in type 316 stainless steel. Met. Sci. 9, 375 (1975)CrossRef
93.
go back to reference R.Y. Chen, W.Y.D. Yuen, Review of the high-temperature oxidation of iron and carbon steels in air or oxygen. Oxid. Met. 59, 433 (2003)CrossRef R.Y. Chen, W.Y.D. Yuen, Review of the high-temperature oxidation of iron and carbon steels in air or oxygen. Oxid. Met. 59, 433 (2003)CrossRef
94.
go back to reference P. Kofstad, Oxidation of metals: determination of activation energies. Acta Chem. Scand. 12, 701 (1958)CrossRef P. Kofstad, Oxidation of metals: determination of activation energies. Acta Chem. Scand. 12, 701 (1958)CrossRef
95.
go back to reference Z. Liu, W. Gao, H. Gong, Anisothermal oxidation of micro-crystalline Ni–20Cr–5Al alloy coating at 850–1280°C. Scr. Mater. 38, 1057 (1998)CrossRef Z. Liu, W. Gao, H. Gong, Anisothermal oxidation of micro-crystalline Ni–20Cr–5Al alloy coating at 850–1280°C. Scr. Mater. 38, 1057 (1998)CrossRef
Metadata
Title
AlNiCrFeMn Equiatomic High Entropy Alloy: A Further Insight in Its Microstructural Evolution, Mechanical and Surface Degradation Response
Authors
E. Ananiadis
K. Lentzaris
E. Georgatis
C. Mathiou
A. Poulia
A. E. Karantzalis
Publication date
31-07-2019
Publisher
The Korean Institute of Metals and Materials
Published in
Metals and Materials International / Issue 6/2020
Print ISSN: 1598-9623
Electronic ISSN: 2005-4149
DOI
https://doi.org/10.1007/s12540-019-00401-4

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