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2018 | OriginalPaper | Chapter

7. Alternative Uses for Biodiesel Byproduct: Glycerol as Source of Energy and High Valuable Chemicals

Authors : Cauê Alves Martins, Pablo Sebastián Fernández, Giuseppe Abíola Camara

Published in: Increased Biodiesel Efficiency

Publisher: Springer International Publishing

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Abstract

Glycerol was firstly faced as a residue, since it is massively produced from the transesterification of vegetable oils and animal fat, corresponding to roughly 10% of the total amount of biodiesel. The recent high availability of glycerol has decreased its price and increased the risks of environmentally inadequate disposal. Now, this small chain alcohol is faced as a powerful alternative for energy conversion and production of chemicals with commercial interest. Its three hydrated carbons make this organic a noticeable substrate to produce other carbonyl compounds and to be used to produce energy in electrochemical devices collectively known as direct alcohol fuel cells. The development in the electrocatalysis field opened up new strategies to convert glycerol into power and chemicals, by using fuel cells and electrolyzer reactors. In both systems, the efficiency of the process depends on several aspects, as the medium, applied potential, and mainly on the surface reaction taking place at the interface between solution and electrode. In this chapter, we discuss the use of glycerol in these electrochemical systems and illustrate some experimental results regarding fundamental and applied science. Namely, we describe some advances in the understanding of the glycerol electro-oxidation reaction interpreted by spectroscopy and chromatographic techniques. Novel nanomaterials currently applied to improve the catalysis of the reaction are also shown. Moreover, we comment some results regarding fuel cells, microfluidic fuel cells, and electrolyzers fed by glycerol and the perspectives and challenges of its use.

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previous chapter Recent Advances on Sample Preparation Procedures for Elemental Determination in Biodiesel

Alencar LM, Caneppele GL, Martins CA (2016) Fast and controlled decorating of metallic nanoparticles using wall-jet configuration. Electroanalysis 29:314–318. https://doi.org/10.1002/elan.201600472 CrossRef

Avramov-Ivić ML, Leger JM, Lamy C et al (1991a) The electro-oxidation of glycerol on the gold(100)-oriented single-crystal surface and poly crystalline surface in 0.1 M NaOH. J Electroanal Chem Interfacial Electrochem 308:309–317. https://doi.org/10.1016/0022-0728(91)85075-Z CrossRef

Avramov-Ivić ML, Leger JM, Lamy C et al (1991b) The electro-oxidation of glycerol on the gold(100)-oriented single-crystal surface and poly crystalline surface in 0.1 M NaOH. J Electroanal Chem Interfacial Electrochem 308:309–317. https://doi.org/10.1016/0022-0728(91)85075-Z CrossRef

Bagnato G, Iulianelli A, Sanna A, Basile A (2017) Glycerol production and transformation: a critical review with particular emphasis on glycerol reforming reaction for producing hydrogen in conventional and membrane reactors. Membranes 7:17. https://doi.org/10.3390/membranes7020017 CrossRef

Bambagioni V, Bevilacqua M, Bianchini C et al (2010) Self-sustainable production of hydrogen, chemicals, and energy from renewable alcohols by electrocatalysis. Chemsuschem 3:851–855. https://doi.org/10.1002/cssc.201000103 CrossRef

Babir F (2012) PEM fuel cells: theory and practice, 2nd edn.

Benipal N, Qi J, Gentile JC, Li W (2017a) Direct glycerol fuel cell with polytetrafluoroethylene (PTFE) thin film separator. Renew Energy 105:647–655. https://doi.org/10.1016/j.renene.2016.12.028 CrossRef

Benipal N, Qi J, Liu Q, Li W (2017b) Carbon nanotube supported PdAg nanoparticles for electrocatalytic oxidation of glycerol in anion exchange membrane fuel cells. Appl Catal B Environ 210:121–130. https://doi.org/10.1016/j.apcatb.2017.02.082 CrossRef

Bianchini C, Shen PK (2009) Palladium-based electrocatalysts for alcohol oxidation in half cells and in direct alcohol fuel cells. Chem Rev 109:4183–4206. https://doi.org/10.1021/cr9000995 CrossRef

Bott-Neto JL, Garcia AC, Oliveira VL et al (2014) Au/C catalysts prepared by a green method towards C3 alcohol electrooxidation: a cyclic voltammetry and in situ FTIR spectroscopy study. J Electroanal Chem 735:57–62. https://doi.org/10.1016/j.jelechem.2014.10.010 CrossRef

Caneppele GL, Almeida TS, Zanata CR et al (2017) Exponential improving in the activity of Pt/C nanoparticles towards glycerol electrooxidation by Sb ad-atoms deposition. Appl Catal B Environ 200:114–120. https://doi.org/10.1016/j.apcatb.2016.06.072 CrossRef

Chen Q-S, Xu Z-N, Peng S-Y et al (2015) One-step electrochemical synthesis of preferentially oriented (111) Pd nanocrystals supported on graphene nanoplatelets for formic acid electrooxidation. J Power Sour 282:471–478. https://doi.org/10.1016/j.jpowsour.2015.02.042 CrossRef

Coutanceau C, Baranton S (2016) Electrochemical conversion of alcohols for hydrogen production: a short overview. Wiley Interdiscip Rev Energy Environ 5:388–400. https://doi.org/10.1002/wene.193 CrossRef

Da Silva RG, Aquino Neto S, Kokoh KB, De Andrade AR (2017) Electroconversion of glycerol in alkaline medium: from generation of energy to formation of value-added products. J Power Sources 351:174–182. https://doi.org/10.1016/j.jpowsour.2017.03.101 CrossRef

Dector A, Cuevas-Muñiz FM, Guerra-Balcázar M et al (2013) Glycerol oxidation in a microfluidic fuel cell using Pd/C and Pd/MWCNT anodes electrodes. Int J Hydrog Energy 38:12617–12622. https://doi.org/10.1016/j.ijhydene.2012.12.030 CrossRef

Ding J, Bu L, Guo S et al (2016) Morphology and phase controlled construction of Pt–Ni nanostructures for efficient electrocatalysis. Nano Lett. https://doi.org/10.1021/acs.nanolett.6b00471

Falase A, Main M, Garcia K et al (2012) Electrooxidation of ethylene glycol and glycerol by platinum-based binary and ternary nano-structured catalysts. Electrochim Acta 66:295–301. https://doi.org/10.1016/j.electacta.2012.01.096 CrossRef

Fang Y, Wang W, Wo X et al (2014) Plasmonic imaging of electrochemical oxidation of single nanoparticles. J Am Chem Soc 136:12584–12587. https://doi.org/10.1021/ja507097y CrossRef

Fashedemi OO, Miller HA, Marchionni A et al (2015) Electro-oxidation of ethylene glycol and glycerol at palladium-decorated FeCo@Fe core–shell nanocatalysts for alkaline direct alcohol fuel cells: functionalized MWCNT supports and impact on product selectivity. J Mater Chem A 3:7145–7156. https://doi.org/10.1039/C5TA00076A CrossRef

Fernández PS, Fernandes Gomes J, Angelucci CA et al (2015a) Establishing a link between well-ordered Pt(100) surfaces and real systems: how do random superficial defects influence the electro-oxidation of glycerol? ACS Catal 5:4227–4236. https://doi.org/10.1021/acscatal.5b00451 CrossRef

Fernández PS, Martins CA, Angelucci CA et al (2015b) Evidence for independent glycerol electrooxidation behavior on different ordered domains of polycrystalline platinum. ChemElectroChem 2:263–268. https://doi.org/10.1002/celc.201402291 CrossRef

Fernández PS, Martins CA, Martins ME, Camara GA (2013) Electrooxidation of glycerol on platinum nanoparticles: deciphering how the position of each carbon affects the oxidation pathways. Electrochim Acta 112:686–691. https://doi.org/10.1016/j.electacta.2013.09.032 CrossRef

Fernández PS, Martins ME, Camara GA (2012a) New insights about the electro-oxidation of glycerol on platinum nanoparticles supported on multi-walled carbon nanotubes. Electrochim Acta 66:180–187. https://doi.org/10.1016/j.electacta.2012.01.069 CrossRef

Fernández PS, Martins ME, Martins CA, Camara GA (2012b) The electro-oxidation of isotopically labeled glycerol on platinum: New information on C–C bond cleavage and CO2 production. Electrochem Commun 15:14–17. https://doi.org/10.1016/j.elecom.2011.11.013 CrossRef

Fernández PS, Tereshchuk P, Angelucci CA et al (2016) How do random superficial defects influence the electro-oxidation of glycerol on Pt(111) surfaces? Phys Chem Chem Phys. https://doi.org/10.1039/C6CP04768H

Figueiredo MC, Sorsa O, Arán-Ais RM et al (2015) Trimetallic catalyst based on PtRu modified by irreversible adsorption of Sb for direct ethanol fuel cells. J Catal 329:69–77. https://doi.org/10.1016/j.jcat.2015.04.032 CrossRef

Fontes EH, da Silva SG, Spinacé EV, et al (2016) In Situ ATR-FTIR studies of ethanol electro-oxidation in alkaline medium on PtRh/C electrocatalyst prepared by an alcohol reduction process. Electrocatalysis 1–8. https://doi.org/10.1007/s12678-016-0308-z

Garcia AC, Birdja YY, Tremiliosi-Filho G, Koper MTM (2017) Glycerol electro-oxidation on bismuth-modified platinum single crystals. J Catal 346:117–124. https://doi.org/10.1016/j.jcat.2016.12.013 CrossRef

Garcia AC, Kolb MJ, van Nierop y Sanchez C, et al (2016) Strong impact of platinum surface structure on primary and secondary alcohol oxidation during electro-oxidation of glycerol. ACS Catal 6:4491–4500. https://doi.org/10.1021/acscatal.6b00709

Gomes JF, de Paula FBC, Gasparotto LHS, Tremiliosi-Filho G (2012) The influence of the Pt crystalline surface orientation on the glycerol electro-oxidation in acidic media. Electrochim Acta 76:88–93. https://doi.org/10.1016/j.electacta.2012.04.144 CrossRef

Gomes JF, Garcia AC, Gasparotto LHS et al (2014) Influence of silver on the glycerol electro-oxidation over AuAg/C catalysts in alkaline medium: a cyclic voltammetry and in situ FTIR spectroscopy study. Electrochim Acta 144:361–368. https://doi.org/10.1016/j.electacta.2014.08.035 CrossRef

Gomes JF, Martins CA, Giz MJ et al (2013) Insights into the adsorption and electro-oxidation of glycerol: self-inhibition and concentration effects. J Catal 301:154–161. https://doi.org/10.1016/j.jcat.2013.02.007 CrossRef

González-Cobos J, Baranton S, Coutanceau C (2016) Development of bismuth-modified PtPd nanocatalysts for the electrochemical reforming of polyols into hydrogen and value-added chemicals. Chem ElectroChem 3:1694–1704. https://doi.org/10.1002/celc.201600147

Goulet M-A, Kjeang E (2014) Co-laminar flow cells for electrochemical energy conversion. J Power Sources 260:186–196. https://doi.org/10.1016/j.jpowsour.2014.03.009 CrossRef

Gupta M, Kumar N (2012) Scope and opportunities of using glycerol as an energy source. Renew Sustain Energy Rev 16:4551–4556. https://doi.org/10.1016/j.rser.2012.04.001 CrossRef

Hamann CH, Hamnett A, Vielstich W (2007) Electrocatalysis and reaction mechanisms. In Electrochemistry, 2nd edn. Wiley, Weinheim

Holade Y, Morais C, Servat K et al (2013) Toward the electrochemical valorization of glycerol: fourier transform infrared spectroscopic and chromatographic studies. ACS Catal 3:2403–2411. https://doi.org/10.1021/cs400559d CrossRef

Horn EJ, Rosen BR, Baran PS (2016) Synthetic organic electrochemistry: an enabling and innately sustainable method. ACS Cent Sci 2:302–308. https://doi.org/10.1021/acscentsci.6b00091 CrossRef

Huang L, Sun J-Y, Cao S-H et al (2016) Combined EC-NMR and in situ FTIR spectroscopic studies of glycerol electrooxidation on Pt/C, PtRu/C, and PtRh/C. ACS Catal 6:7686–7695. https://doi.org/10.1021/acscatal.6b02097 CrossRef

Hutchings GJ (2008) Nanocrystalline gold and gold palladium alloy catalysts for chemical synthesis. Chem Commun 1148–1164. https://doi.org/10.1039/b712305c

Ilie A, Simoes M, Baranton S et al (2011) Influence of operational parameters and of catalytic materials on electrical performance of direct glycerol solid alkaline membrane fuel cells. J Power Sour 196:4965–4971. https://doi.org/10.1016/j.jpowsour.2011.02.003 CrossRef

Independent Review Panel Summary Report (2009) Current (2009) State-of-the-art hydrogen production cost estimate using water electrolysis

Iwasita T, Nart FC (1997) In situ infrared spectroscopy at electrochemical interfaces. Prog Surf Sci 55:271–340. https://doi.org/10.1016/S0079-6816(97)00032-4 CrossRef

Jin M, Zhang H, Xie Z, Xia Y (2011) Palladium concave nanocubes with high-index facets and their enhanced catalytic properties. Angew Chem Int Ed 50:7850–7854. https://doi.org/10.1002/anie.201103002 CrossRef

Kishida H, Jin F, Zhou Z et al (2005) Conversion of glycerin into lactic acid by alkaline hydrothermal reaction. Chem Lett 34:1560–1561. https://doi.org/10.1246/cl.2005.1560 CrossRef

Kjeang E (2014) Microfluidic fuel cells and batteries, spring briefs

Kongjao S, Damronglerd S, Hunsom M (2011) Electrochemical reforming of an acidic aqueous glycerol solution on Pt electrodes. J Appl Electrochem 41:215–222. https://doi.org/10.1007/s10800-010-0226-3 CrossRef

Kwon Y, Hersbach TJP, Koper MTM (2014) Electro-oxidation of glycerol on platinum modified by adatoms: activity and selectivity effects. Top Catal 57:1272–1276. https://doi.org/10.1007/s11244-014-0292-6 CrossRef

Kwon Y, Koper MTM (2010) Combining voltammetry with HPLC: application to electro-oxidation of glycerol. Anal Chem 82:5420–5424. https://doi.org/10.1021/ac101058t CrossRef

Lam CH, Bloomfield AJ, Anastas PT (2017) A switchable route to valuable commodity chemicals from glycerol via electrocatalytic oxidation with an earth abundant metal oxidation catalyst. Green Chem 19:1958–1968. https://doi.org/10.1039/C7GC00371D CrossRef

Lertthahan P, Yongprapat S, Therdthianwong A, Therdthianwong S (2017) Pt-modified Au/C catalysts for direct glycerol electro-oxidation in an alkaline medium. Int J Hydrog Energy 42:9202–9209. https://doi.org/10.1016/j.ijhydene.2016.05.120 CrossRef

Lima da Silva A, Müller IL (2010) Operation of solid oxide fuel cells on glycerol fuel: a thermodynamic analysis using the Gibbs free energy minimization approach. J Power Sour 195:5637–5644. https://doi.org/10.1016/j.jpowsour.2010.03.066 CrossRef

Marchionni A, Bevilacqua M, Bianchini C et al (2013) Electrooxidation of ethylene glycol and glycerol on Pd–(Ni–Zn)/C anodes in direct alcohol fuel cells. Chemsuschem 6:518–528. https://doi.org/10.1002/cssc.201200866 CrossRef

Marshall AT, Haverkamp RG (2008) Production of hydrogen by the electrochemical reforming of glycerol–water solutions in a PEM electrolysis cell. Int J Hydrog Energy 33:4649–4654. https://doi.org/10.1016/j.ijhydene.2008.05.029 CrossRef

Martins CA, Fernández PS, de Lima F et al (2014a) Remarkable electrochemical stability of one-step synthesized Pd nanoparticles supported on graphene and multi-walled carbon nanotubes. Nano Energy 9:142–151. https://doi.org/10.1016/j.nanoen.2014.07.009 CrossRef

Martins CA, Fernández PS, Troiani HE et al (2014b) Ethanol versus glycerol: understanding the lack of correlation between the oxidation currents and the production of CO₂ on Pt nanoparticles. J Electroanal Chem 717–718:231–236. https://doi.org/10.1016/j.jelechem.2014.01.027 CrossRef

Martins CA, Giz MJ, Camara GA (2011) Generation of carbon dioxide from glycerol: evidences of massive production on polycrystalline platinum. Electrochim Acta 56:4549–4553. https://doi.org/10.1016/j.electacta.2011.02.076 CrossRef

Matsuoka K, Iriyama Y, Abe T et al (2005) Alkaline direct alcohol fuel cells using an anion exchange membrane. J Power Sources 150:27–31. https://doi.org/10.1016/j.jpowsour.2005.02.020 CrossRef

Maya-Cornejo J, Guerra-Balcázar M, Arjona N et al (2016) Electrooxidation of crude glycerol as waste from biodiesel in a nanofluidic fuel cell using Cu@Pd/C and Cu@Pt/C. Fuel 183:195–205. https://doi.org/10.1016/j.fuel.2016.06.075 CrossRef

Mello GAB, Fernández PS, Martins ME, Camara GA (2017) Glycerol electrooxidation on platinum-tin electrodeposited films: inducing changes in surface composition by cyclic voltammetry. Electrocatalysis 8:1–10. https://doi.org/10.1007/s12678-016-0332-z CrossRef

Monzó J, Malewski Y, Vidal-Iglesias FJ et al (2015) Electrochemical oxidation of small organic molecules on Au nanoparticles with preferential surface orientation. Chem ElectroChem 2:958–962. https://doi.org/10.1002/celc.201500084

Oliveira M (2016) Revista Fapesp, Ed. 245

Park JY, Zhang Y, Grass M et al (2008) Tuning of catalytic CO oxidation by changing composition of Rh–Pt bimetallic nanoparticles. Nano Lett 8:673–677. https://doi.org/10.1021/nl073195i CrossRef

Pilatowsky I, Romero RJ, Isaza CA, et al (2011) Cogeneration fuel cell-sorption air conditioning systems. Springer Science & Business Media

Qi J, Xin L, Zhang Z et al (2013) Surface dealloyed PtCo nanoparticles supported on carbon nanotube: facile synthesis and promising application for anion exchange membrane direct crude glycerol fuel cell. Green Chem 15:1133–1137. https://doi.org/10.1039/C3GC36955B CrossRef

Roquet L, Belgsir EM, Léger J-M, Lamy C (1994a) Kinetics and mechanisms of the electrocatalytic oxidation of glycerol as investigated by chromatographic analysis of the reaction products: Potential and pH effects. Electrochim Acta 39:2387–2394. https://doi.org/10.1016/0013-4686(94)E0190-Y CrossRef

Roquet L, Belgsir EM, Léger J-M, Lamy C (1994b) Kinetics and mechanisms of the electrocatalytic oxidation of glycerol as investigated by chromatographic analysis of the reaction products: Potential and pH effects. Electrochim Acta 39:2387–2394. https://doi.org/10.1016/0013-4686(94)E0190-Y CrossRef

Sau TK, Rogach AL (2010) Nonspherical noble metal nanoparticles: colloid-chemical synthesis and morphology control. Adv Mater 22:1781–1804. https://doi.org/10.1002/adma.200901271 CrossRef

Shan X, Díez-Pérez I, Wang L et al (2012) Imaging the electrocatalytic activity of single nanoparticles. Nat Nanotechnol 7:668–672. https://doi.org/10.1038/nnano.2012.134 CrossRef

Simões M, Baranton S, Coutanceau C (2011) Enhancement of catalytic properties for glycerol electrooxidation on Pt and Pd nanoparticles induced by Bi surface modification. Appl Catal B Environ 110:40–49. https://doi.org/10.1016/j.apcatb.2011.08.020 CrossRef

Simões M, Baranton S, Coutanceau C (2012) Electrochemical valorisation of glycerol. Chemsuschem 5:2106–2124. https://doi.org/10.1002/cssc.201200335 CrossRef

Soares LA, Morais C, Napporn TW et al (2016) Beneficial effects of rhodium and tin oxide on carbon supported platinum catalysts for ethanol electrooxidation. J Power Sour 315:47–55. https://doi.org/10.1016/j.jpowsour.2016.03.013 CrossRef

Solla-Gullón J, Vidal-Iglesias FJ, Herrero E, Feliu JM, Aldaz A (2013) Polymer electrolyte fuel cells: science, applications, and challenges. In: Franco AA. Pan Stanford

Song C (2002) Fuel processing for low-temperature and high-temperature fuel cells. Catal Today 77:17–49. https://doi.org/10.1016/S0920-5861(02)00231-6 CrossRef

Thia L, Xie M, Liu Z et al (2016) Copper-modified gold nanoparticles as highly selective catalysts for glycerol electro-oxidation in alkaline solution. ChemCatChem 8:3272–3278. https://doi.org/10.1002/cctc.201600725 CrossRef

Vidal-Iglesias FJ, Solla-Gullón J, Herrero E et al (2010) Pd adatom decorated (100) preferentially oriented Pt nanoparticles for formic acid electrooxidation. Angew Chem Int Ed 49:6998–7001. https://doi.org/10.1002/anie.201002501 CrossRef

Wang Y, Chen KS, Mishler J et al (2011) A review of polymer electrolyte membrane fuel cells: technology, applications, and needs on fundamental research. Appl Energy 88:981–1007. https://doi.org/10.1016/j.apenergy.2010.09.030 CrossRef

Wang Z, Xin L, Zhao X et al (2014) Carbon supported Ag nanoparticles with different particle size as cathode catalysts for anion exchange membrane direct glycerol fuel cells. Renew Energy 62:556–562. https://doi.org/10.1016/j.renene.2013.08.005 CrossRef

Wang Y, Leung DYC, Xuan J, Wang H (2016) A review on unitized regenerative fuel cell technologies, part B: unitized regenerative alkaline fuel cell, solid oxide fuel cell, and microfluidic fuel cell. Renew Sustain Energy Rev. https://doi.org/10.1016/j.rser.2016.11.054

Won JY, Sohn HJ, Song RH, Woo SI (2009) Glycerol as a bioderived sustainable fuel for solid-oxide fuel cells with internal reforming. Chemsuschem 2:1028–1031. https://doi.org/10.1002/cssc.200900170 CrossRef

Xin L, Zhang Z, Wang Z, Li W (2012) Simultaneous generation of mesoxalic acid and electricity from glycerol on a gold anode catalyst in anion-exchange membrane fuel cells. ChemCatChem 4:1105–1114. https://doi.org/10.1002/cctc.201200017 CrossRef

Yu Y, Gao Y, Hu K et al (2015) Electrochemistry and electrocatalysis at single gold nanoparticles attached to carbon nanoelectrodes. ChemElectroChem 2:58–63. https://doi.org/10.1002/celc.201402312 CrossRef

Yuksel A, Koga H, Sasaki M, Goto M (2010) Hydrothermal electrolysis of glycerol using a continuous flow reactor. Ind Eng Chem Res 49:1520–1525. https://doi.org/10.1021/ie9016418 CrossRef

Zalineeva A, Baranton S, Coutanceau C (2013) Bi-modified palladium nanocubes for glycerol electrooxidation. Electrochem Commun 34:335–338. https://doi.org/10.1016/j.elecom.2013.07.022 CrossRef

Zanata CR, Fernández PS, Troiani HE et al (2016) Rh-decorated PtIrOx nanoparticles for glycerol electrooxidation: Searching for a stable and active catalyst. Appl Catal B Environ 181:445–455. https://doi.org/10.1016/j.apcatb.2015.08.021 CrossRef

Zhang J, Liang Y, Li N et al (2012a) A remarkable activity of glycerol electrooxidation on gold in alkaline medium. Electrochim Acta 59:156–159. https://doi.org/10.1016/j.electacta.2011.10.048 CrossRef

Zhang Z, Xin L, Li W (2012b) Supported gold nanoparticles as anode catalyst for anion-exchange membrane-direct glycerol fuel cell (AEM-DGFC). Int J Hydrog Energy 37:9393–9401. https://doi.org/10.1016/j.ijhydene.2012.03.019 CrossRef

Zhang Z, Xin L, Li W (2012c) Electrocatalytic oxidation of glycerol on Pt/C in anion-exchange membrane fuel cell: cogeneration of electricity and valuable chemicals. Appl Catal B Environ 119:40–48. https://doi.org/10.1016/j.apcatb.2012.02.009 CrossRef

Title: Alternative Uses for Biodiesel Byproduct: Glycerol as Source of Energy and High Valuable Chemicals
Authors: Cauê Alves Martins
Pablo Sebastián Fernández
Giuseppe Abíola Camara
Publisher: Springer International Publishing
Book: Increased Biodiesel Efficiency
Print ISBN: 978-3-319-73551-1

Electronic ISBN: 978-3-319-73552-8

Copyright Year: 2018
DOI: https://doi.org/10.1007/978-3-319-73552-8_7