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Published in: Environmental Earth Sciences 2/2010

01-07-2010 | Original Article

Arsenic in geothermal sources at the north-central Andean region of Ecuador: concentrations and mechanisms of mobility

Authors: Luis Cumbal, Paulina Vallejo, Brigida Rodriguez, Dina Lopez

Published in: Environmental Earth Sciences | Issue 2/2010

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Abstract

The arsenic content of geothermal hot springs and their sediments in the north-central Andean region of Ecuador has been investigated. The area of study is located between parallels 1°11′N and 1°30′S and includes five provinces. The area is rich in geothermal surface manifestations that are mainly used for medicinal baths in recreational complexes. Unfortunately, water residuals without treatment are released from the recreational facilities to surrounding water bodies. The results indicate that total arsenic in geothermal waters in this region has a range of 2–969 µg As/L, and sediments contain arsenic ranging from 1.6 to 717.6 mg/kg. Chemical analyses of sediment samples show the presence of sulfur, iron, aluminum and calcium. A high concentration of natural organic matter was also found in some samples (20–29.5%); thus sorption and coprecipitation can be the main mechanisms of As immobilization on mineral phases and natural organic matter.

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Literature
go back to reference Baldock JW (1983) Geología del Ecuador: Boletín Explicativo del Mapa Geológico de la República del Ecuador. Dirección General de Geología y Minas, Quito Baldock JW (1983) Geología del Ecuador: Boletín Explicativo del Mapa Geológico de la República del Ecuador. Dirección General de Geología y Minas, Quito
go back to reference Baur WH, Onishi B-MH (1969) Arsenic. In: Wedepohl KH (ed) Handbook of geochemistry. Springer, Berlin, pp 33-A-1–33-0-5 Baur WH, Onishi B-MH (1969) Arsenic. In: Wedepohl KH (ed) Handbook of geochemistry. Springer, Berlin, pp 33-A-1–33-0-5
go back to reference Cherry JA, Shaikh DE, Tallman DE, Nicholson RV (1979) Arsenic species as an indicator of redox conditions in groundwater. J Hydrol 43:373–392CrossRef Cherry JA, Shaikh DE, Tallman DE, Nicholson RV (1979) Arsenic species as an indicator of redox conditions in groundwater. J Hydrol 43:373–392CrossRef
go back to reference Clifford D, Ceber L, Chow S (1983) As(III)/As(V) separation by chloride-form ion-exchange resins. In: Proceedings of the AWWA WQTC, Norfolk Clifford D, Ceber L, Chow S (1983) As(III)/As(V) separation by chloride-form ion-exchange resins. In: Proceedings of the AWWA WQTC, Norfolk
go back to reference Criaud A, Fouillac C (1989) The distribution of arsenic(III) and arsenic(V) in geothermal waters: examples from the Massif Central of France, the Island of Dominica in the Leeward Islands of the Caribbean, the Valles Caldera of New Mexico, USA, and southwest Bulgaria. Chem Geol 76:259–269CrossRef Criaud A, Fouillac C (1989) The distribution of arsenic(III) and arsenic(V) in geothermal waters: examples from the Massif Central of France, the Island of Dominica in the Leeward Islands of the Caribbean, the Valles Caldera of New Mexico, USA, and southwest Bulgaria. Chem Geol 76:259–269CrossRef
go back to reference Cumbal L, Bundschuh J, Aguirre V, Murgueitio E, Tipán I, Chavez C (2009) The origin of arsenic in waters and sediments from Papallacta Lake in Ecuador. In: Bundschuh J, Armienta MA, Birkle P, Bhattacharya P, Matschullat J, Mukherjee AB (eds) Natural arsenic in ground waters of Latin America—occurrence health impact and remediation. Taylor & Francis Group, London, pp 81–90 Cumbal L, Bundschuh J, Aguirre V, Murgueitio E, Tipán I, Chavez C (2009) The origin of arsenic in waters and sediments from Papallacta Lake in Ecuador. In: Bundschuh J, Armienta MA, Birkle P, Bhattacharya P, Matschullat J, Mukherjee AB (eds) Natural arsenic in ground waters of Latin America—occurrence health impact and remediation. Taylor & Francis Group, London, pp 81–90
go back to reference Dzomabak DA, Morel JJ (1990) Surface complexation modeling: hydrous ferric oxide. Wiley, New York Dzomabak DA, Morel JJ (1990) Surface complexation modeling: hydrous ferric oxide. Wiley, New York
go back to reference Eary LE, Schramke JA (1990) Rates of inorganic oxidation reactions involving dissolved oxygen. In: Melchior DC, Bassett RL (eds) Chemical modeling in aqueous systems II. Am Chem Soc Symp Series 416. Washington, pp 379–396 Eary LE, Schramke JA (1990) Rates of inorganic oxidation reactions involving dissolved oxygen. In: Melchior DC, Bassett RL (eds) Chemical modeling in aqueous systems II. Am Chem Soc Symp Series 416. Washington, pp 379–396
go back to reference Ficklin WH (1983) Separation of As(III) and As(V) in ground waters by ion exchange. Talanta 30:5–371CrossRef Ficklin WH (1983) Separation of As(III) and As(V) in ground waters by ion exchange. Talanta 30:5–371CrossRef
go back to reference Greenberg AE, Clesceri LS, Eaton AD (1998) Standard methods for the examination of water and wastewater, 20th edn. American Public Health Association, Washington Greenberg AE, Clesceri LS, Eaton AD (1998) Standard methods for the examination of water and wastewater, 20th edn. American Public Health Association, Washington
go back to reference Instituto Ecuatoriano de Estadística y Censo (2001) VI Censo de Población y V de Vivienda Instituto Ecuatoriano de Estadística y Censo (2001) VI Censo de Población y V de Vivienda
go back to reference Kim M-J, Nriagu J, Haack S (2000) Carbonate ions and arsenic dissolution by groundwater. Environ Sci Technol 34:3094–3100CrossRef Kim M-J, Nriagu J, Haack S (2000) Carbonate ions and arsenic dissolution by groundwater. Environ Sci Technol 34:3094–3100CrossRef
go back to reference Kopriva A, Zeman J, Sracek O (2005) High arsenic concentrations in mining waters at Kank, Czech Republic. In: Bundschuh J, Bhattacharya P, Chandrasekharam J (eds) Natural arsenic in groundwater: occurrence remediation and management. Taylor & Francis Group, London, pp 49–55 Kopriva A, Zeman J, Sracek O (2005) High arsenic concentrations in mining waters at Kank, Czech Republic. In: Bundschuh J, Bhattacharya P, Chandrasekharam J (eds) Natural arsenic in groundwater: occurrence remediation and management. Taylor & Francis Group, London, pp 49–55
go back to reference Manning BA, Fendorf SE, Goldberg S (1998) Surface structures and stability of As(III) on goethite: spectroscopic evidence of inner-sphere complexes. Environ Sci Technol 32:2383–2388CrossRef Manning BA, Fendorf SE, Goldberg S (1998) Surface structures and stability of As(III) on goethite: spectroscopic evidence of inner-sphere complexes. Environ Sci Technol 32:2383–2388CrossRef
go back to reference Nordstrom DK, McCleskey RB, Ball JW (2001) Processes governing arsenic geochemistry in the thermal waters of Yellowstone National Park. In: USGS workshop on arsenic in the environment, Denver Nordstrom DK, McCleskey RB, Ball JW (2001) Processes governing arsenic geochemistry in the thermal waters of Yellowstone National Park. In: USGS workshop on arsenic in the environment, Denver
go back to reference Pierce ML, Moore CB (1982) Adsorption of As(III) and As(V) on amorphous iron hydroxide. Water Res 16(7):1247–1253CrossRef Pierce ML, Moore CB (1982) Adsorption of As(III) and As(V) on amorphous iron hydroxide. Water Res 16(7):1247–1253CrossRef
go back to reference Romero L, Alonso H, Campano P, Fanfani L, Cidub R, Dadea C, Keegan T, Thornton I, Farago M (2003) Arsenic enrichment in waters and sediments of the Rio Loa (Second Region, Chile). Appl Geochem 18:1399–1416CrossRef Romero L, Alonso H, Campano P, Fanfani L, Cidub R, Dadea C, Keegan T, Thornton I, Farago M (2003) Arsenic enrichment in waters and sediments of the Rio Loa (Second Region, Chile). Appl Geochem 18:1399–1416CrossRef
go back to reference Sahai N, Lee YJ, Xu H, Ciardelli M, Gaillard J-F (2007) Role of Fe(II) and phosphate in arsenic uptake by coprecipitation. Geochim Cosmochim Acta 71(24):e39–e46 Sahai N, Lee YJ, Xu H, Ciardelli M, Gaillard J-F (2007) Role of Fe(II) and phosphate in arsenic uptake by coprecipitation. Geochim Cosmochim Acta 71(24):e39–e46
go back to reference Smedley PL, Kinniburgh DG (2002) A review of the source, behaviour and distribution of arsenic in natural waters. Appl Geochem 17:517–568CrossRef Smedley PL, Kinniburgh DG (2002) A review of the source, behaviour and distribution of arsenic in natural waters. Appl Geochem 17:517–568CrossRef
go back to reference Wang S, Mulligan CN (2006a) Natural attenuation processes for remediation of arsenic contaminated soils and groundwater. J Hazard Mater 138(3):459–470CrossRef Wang S, Mulligan CN (2006a) Natural attenuation processes for remediation of arsenic contaminated soils and groundwater. J Hazard Mater 138(3):459–470CrossRef
go back to reference Wang S, Mulligan CN (2006b) Effect of natural organic matter on arsenic release from soils and sediments into groundwater. J Environ Geochem Health 28(3):197–214CrossRef Wang S, Mulligan CN (2006b) Effect of natural organic matter on arsenic release from soils and sediments into groundwater. J Environ Geochem Health 28(3):197–214CrossRef
go back to reference Welch AH, Westjohn DB, Helsel DR, Wanty RB (2000) Arsenic in ground water of the United States: occurrence and geochemistry. Ground Water 38:589–604CrossRef Welch AH, Westjohn DB, Helsel DR, Wanty RB (2000) Arsenic in ground water of the United States: occurrence and geochemistry. Ground Water 38:589–604CrossRef
Metadata
Title
Arsenic in geothermal sources at the north-central Andean region of Ecuador: concentrations and mechanisms of mobility
Authors
Luis Cumbal
Paulina Vallejo
Brigida Rodriguez
Dina Lopez
Publication date
01-07-2010
Publisher
Springer-Verlag
Published in
Environmental Earth Sciences / Issue 2/2010
Print ISSN: 1866-6280
Electronic ISSN: 1866-6299
DOI
https://doi.org/10.1007/s12665-009-0343-7

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