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Journal of Materials Science
Published in: Journal of Materials Science 19/2018

30-04-2018 | Mechanochemical Synthesis

BaF-benzenedicarboxylate: the first mechanochemical synthesis of a new coordination polymer with a direct Ba–F bond

Authors: S. Breitfeld, G. Scholz, F. Emmerling, E. Kemnitz

Published in: Journal of Materials Science | Issue 19/2018

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Abstract

A new barium coordination polymer, BaF-benzenedicarboxylate (BaF(p-BDC)0.5), with fluorine directly coordinated to the metal cation, was prepared by mechanochemical synthesis routes. Phase-pure BaF-benzenedicarboxylate was synthesized by milling starting either from barium hydroxide or from barium acetate as sources for barium cations. In both cases, the second reactant was 1,4-benzenedicarboxylic acid (H2(p-BDC)). Ammonium fluoride was used as fluorinating agent directly at milling. This is the first mechanochemical synthesis of coordination polymers where fluorine is directly coordinated to the metal cation. Following the second possibility, barium acetate fluoride (Ba(OAc)F) is formed as intermediate product after milling, and the new coordination polymer is accessible only after washing with water and dimethyl sulfoxide. The new compound BaF(p-BDC)0.5 was characterized by X-ray powder diffraction, FTIR-, and 19F, 1H-13C CP MAS NMR spectroscopies, DTA-TG, and elemental analysis.
previous article F anion dynamics in cation-mixed nanocrystalline LaF3: SrF2
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Appendix
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Metadata
Title
BaF-benzenedicarboxylate: the first mechanochemical synthesis of a new coordination polymer with a direct Ba–F bond
Authors
S. Breitfeld
G. Scholz
F. Emmerling
E. Kemnitz
Publication date
30-04-2018
Publisher
Springer US
Published in
Journal of Materials Science / Issue 19/2018
Print ISSN: 0022-2461
Electronic ISSN: 1573-4803
DOI
https://doi.org/10.1007/s10853-018-2331-3

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Preface

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