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Journal of Polymer Research
Published in: Journal of Polymer Research 12/2017

01-11-2017 | ORIGINAL PAPER

Bio-based mesoporous sponges of chitosan conjugated with amino acid-diketopiperazine through oil-in-water emulsions

Authors: Kenji Takada, Hongrong Yin, Tomoyuki Matsui, Mohammad Asif Ali, Tatsuo Kaneko

Published in: Journal of Polymer Research | Issue 12/2017

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Abstract

Fully bio-based chitosan derivative was synthesized using 3-benzyl-2,5-diketopiperazine-6-acetic acid (DKP) activated by 1-(3-dimethylaminopropyl)-3-ethylcarbodiimide hydrochloride and N-hydroxysuccinimide. From IR and 1H NMR spectra, the structure of the bioconjugated chitosan and the quantitative modification were confirmed. Oil-in-water (o/w) emulsion of the obtained product was presented with the various ratios of water and benzene solution. Continuously the obtained o/w emulsions were freeze-dried to produce the mesoporous sponge, depended on the ratio of the water and benzene. These amphiphilic properties were observed by the property of the pendant DKP moieties in chitosan. The pore size in the sponges was controlled in a range from 0.1 to 0.3 μm by changing the solvent ratios.
previous article Improvement of physical properties of poly(glycerol sebacate) by copolymerization with polyhydroxybutyrate-diols
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Metadata
Title
Bio-based mesoporous sponges of chitosan conjugated with amino acid-diketopiperazine through oil-in-water emulsions
Authors
Kenji Takada
Hongrong Yin
Tomoyuki Matsui
Mohammad Asif Ali
Tatsuo Kaneko
Publication date
01-11-2017
Publisher
Springer Netherlands
Published in
Journal of Polymer Research / Issue 12/2017
Print ISSN: 1022-9760
Electronic ISSN: 1572-8935
DOI
https://doi.org/10.1007/s10965-017-1372-7

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