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Topics in Catalysis

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01-06-2009 | Original Paper

Catalysis by Mesoporous Dendrimers

Authors: Mahendra P. Kapoor, Hiroya Kuroda, Masaaki Yanagi, Hironobu Nanbu, Lekh R. Juneja

Published in: Topics in Catalysis | Issue 6-7/2009

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Abstract

The present study reports the divergent synthesis, characterization and catalytic properties of different generation of triazine based aromatic amine dendritic mesoporous silicas derived via a stepwise functionalization of mesoporous silica substrates of different pore sizes with 2,4,6 tricholorotriazine and ethylene diamine. Mesoporous dendritic silicas up to second generation (2G) are grown in side the channels of mesoporous silica materials with 4 and 7 nm pore sizes. The catalytic properties of resulted dendritic materials in Knoevenagel condensation reaction were compared to the aliphatic polyamidoamine dendrimers that are also grown up to second generation (2G) inside the mesoporous channels. The reusability study of both aliphatic and aromatic dendritic mesoporous silica systems is also compared.

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Newkome GR, Moorefield CN, Vogtle F (2001) Dendrimers and dendrons: concepts, synthesis, applications. Wiley-VCH, WeinheimCrossRef

Tomila DA, Taylor AN, Goddard WA (1990) Angew Chem Int Ed Engl 29:138–175CrossRef

Vlatakis G, Andrson LI, Muller R, Mosbach K (1993) Nature 361:645–647CrossRef

Frechet JMJ (1994) Science 263:1710–1715CrossRef

Zeng F, Zimmerman SC (1997) Chem Rev 97:402–413CrossRef

Gorman C (1998) Adv Mater 10:295–309CrossRef

Newkome GR, He E, Moorefield CN (1999) Chem Rev 99:1689–1746CrossRef

Astruc D, Chardec F (2001) Chem Rev 101:2991–3024CrossRef

Zimmerman SC, Wendland MS, Rakow NA, Zharov I, Suslick KS (2002) Nature 418:399–403CrossRef

10.

Ooe M, Murata M, Mizugaki T, Ebitani K, Kaneda K (2004) J Am Chem Soc 126:1604–1605CrossRef

11.

Liu Y, Bruening ML, Bergbreiter DE, Crooks RM (1997) Angew Chem Int Ed Engl 36:2114–2116CrossRef

12.

Liu Y, Zhao M, Bergbreiter DE, Crooks RM (1997) J Am Chem Soc 119:8720–8721CrossRef

13.

Kresge CT, Leonowicz ME, Roth WJ, Vartuli JC, Beck JC (1992) Nature 359:710–712CrossRef

14.

Scott RWJ, Datye AK, Crooks RM (2003) J Am Chem Soc 125:3708–3709CrossRef

15.

Zhao M, Sun L, Crooks RM (1998) J Am Chem Soc 120:4877–4878CrossRef

16.

Bourque SC, Alper H, Manzer LE, Arya P (2000) J Am Chem Soc 122:956–957CrossRef

17.

Bourque SC, Maltais F, Xiao WJ, Tardif O, Alper H, Arya P, Manzer LE (1999) J Am Chem Soc 121:3035–3038CrossRef

18.

Antebi S, Arya P, Manzer LE, Alper H (2002) J Org Chem 67:6623–6624CrossRef

19.

Reynhardt JPK, Alper H (2003) J Org Chem 68:8353–8360CrossRef

20.

Reynhardt JPK, Yang Y, Sayari A, Alper H (2004) Chem Mater 16:4095–4102CrossRef

21.

Reynhardt JPK, Yang Y, Sayari A, Alper H (2005) Adv Funct Mater 15:1641–1646CrossRef

22.

Ottaviani MF, Turro NJ, Jockusch S, Tomila DA (2003) J Phy Chem 107:2046–2053CrossRef

23.

Kapoor MP, Kasama Y, Yokoyama T, Yanagi M, Inagaki S, Nanbu H, Juneja LR (2006) J Mater Chem 16:4714–4722CrossRef

24.

Diaz I, Garcia B, Alonso B, Casado CM, Moran M, Lasada J, Perez-Pariente J (2002) Chem Mater 15:1073–1079CrossRef

25.

Acosta EJ, Carr CS, Simanek EE, Shantz DF (2004) Adv Mater 16:985CrossRef

26.

Landskron K, Ozin GA (2004) Science 306:1529–1532CrossRef

27.

Inagaki S, Koiwai A, Suzuki N, Fukushima Y, Kuroda K (1996) Bull Chem Soc Jpn 69:1449–1457CrossRef

28.

Kruk M, Jaroneic M, Sayari A (1999) J Phys Chem B 103:4590–4598CrossRef

29.

Tsubokawa N, Ichioka H, Satoh T, Hayashi S, Fujiki K (1998) React Funct Polym 37:75–82CrossRef

30.

Knoevenagel E (1894) Chem Ber 27:2345–2347CrossRef

31.

Jones G (1967) Org React 15:204–206

32.

Rand L, Haidukewych D, Dolinski RJ (1966) J Org Chem 31:1272–1274CrossRef

33.

Muzart J (1982) Synthesis 60:1–3

34.

Richardhein W, Melvin J (1961) J Org Chem 26:4874CrossRef

35.

Texier-Boullet F, Foucaud A (1982) Tetrahedron Lett 23:4927–4928CrossRef

36.

Moison H, Texier-Boullet F, Foucaud A (1987) Tetrahedron 43:537–542CrossRef

37.

Angeletti E, Canepa C, Martinetti P, Venurello J (1989) Chem Soc Perkin Trans 1:105–107

38.

Subba Rao YV, Choudary BM (1991) Synth Commun 21:1163–1166CrossRef

39.

Corma A, Fornes V, Martin-Aranda RM, Rey F (1992) J Catal 134:58–65CrossRef

40.

Kloetsstra KR, van Bekkum H (1995) J Chem Soc Chem Commun 1005–1006

41.

Shin Y, Liu JL, Wang Q, Nie Z, Samuels WD, Fryxell GE, Esarhos GJ (2000) Angew Chem Int Ed 39:2702–2707CrossRef

42.

Macquarrie DJ, Jackson DB (1997) J Chem Soc Chem Commun 1781–1782

43.

Liu J, Shin Y, Nie Z, Chang JH, Wang LQ, Fryxell GE, Samuels WD, Esarhos GJ (2000) J Phys Chem B 104:8328–8339

44.

Macquarrie DJ (1996) J Chem Soc Chem Commun 1961–1962

45.

Lasperas M, Liorett T, Chaves L, Rodriguez I, Cauvel A, Brunel D (1997) Stud Surf Sci Catal 108:75–82CrossRef

46.

Choudary BM, Kantam ML, Sreekanth P, Bandopadhyay T, Figueras F, Tuel A (1999) J Mol Catal A: Chem 142:361–365

Title: Catalysis by Mesoporous Dendrimers
Authors: Mahendra P. Kapoor
Hiroya Kuroda
Masaaki Yanagi
Hironobu Nanbu
Lekh R. Juneja
Publication date: 01-06-2009
Publisher: Springer US
Published in: Topics in Catalysis / Issue 6-7/2009
Print ISSN: 1022-5528
Electronic ISSN: 1572-9028
DOI: https://doi.org/10.1007/s11244-009-9221-5

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