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Journal of Materials Science

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01-03-2014

Chemical reactivity of mineral aggregates in aqueous solution: relationship with bitumen emulsion breaking

Authors: Layella Ziyani, Vincent Gaudefroy, Valéry Ferber, Dimitri Deneele, Ferhat Hammoum

Published in: Journal of Materials Science | Issue 6/2014

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Abstract

This paper reports a study on chemical reactivity of gneiss, diorite and limestone aggregates in aqueous solution. The originality of this study is that it extended to very short times (less than 1440 min). Rise in pH tests was implemented and dissolution kinetics was analysed. The results showed that calcium was the major element released by the aggregates. It has also been found that dissolution had an influence on the final morphology of aggregates. Polyamine emulsifier adsorption onto aggregates has been assessed using electrophoresis. Finally, the rise in pH and electrophoretic tests were compared to the breaking test traditionally performed to characterise bitumen emulsions. It was found that breaking values were controlled by both the surface area and the surface charge of the particles. Results may be correlated to polyamine adsorption on aggregates. Adsorption seemed to be efficient for gneiss and diorite: at pH 2, their charge turned from slightly negative to highly positive. At this pH value, limestone particles were dissolved and polyamine adsorption must be less efficient than with gneiss and diorite, for which the emulsion breaking was facilitated by the high attraction of particles for the emulsifier, due to their negative surface charge.

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Title: Chemical reactivity of mineral aggregates in aqueous solution: relationship with bitumen emulsion breaking
Authors: Layella Ziyani
Vincent Gaudefroy
Valéry Ferber
Dimitri Deneele
Ferhat Hammoum
Publication date: 01-03-2014
Publisher: Springer US
Published in: Journal of Materials Science / Issue 6/2014
Print ISSN: 0022-2461
Electronic ISSN: 1573-4803
DOI: https://doi.org/10.1007/s10853-013-7938-9

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